改性氧化石墨烯复合环氧丙烯酸酯电磁屏蔽涂层的制备及其性能研究

金海航, 辛华, 焦岚姣, 安秋凤*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 116 -123.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 116-123. DOI: 10.19817/j.cnki.issn1006-3536.2025.12.048
新材料与新技术

改性氧化石墨烯复合环氧丙烯酸酯电磁屏蔽涂层的制备及其性能研究

    金海航, 辛华, 焦岚姣, 安秋凤*
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Preparation and properties of modified graphene oxide composite epoxy acrylate electromagnetic shielding coating

  • Jin Haihang, Xin Hua, Jiao Lanjiao, An Qiufeng
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摘要

通过硅烷偶联剂KH-550与水合肼(N2H4·H2O)对氧化石墨烯(GO)进行改性,得到氨基功能化的还原氧化石墨烯(RKGO)。将RKGO引入经自由基聚合得到的环氧基丙烯酸树脂(EPAA)体系,构筑氨基功能化还原氧化石墨烯/环氧丙烯酸树脂(RKGO/EPAA)电磁屏蔽复合涂层。通过红外、拉曼等手段进行表征测试,并对复合涂层机械性能及电磁屏蔽性能进行探究。结果表明:构筑得到的电磁屏蔽复合涂层整体机械性能优异,硬度为1H,附着力为0级。当RKGO添加量达到20%时,涂层的体积电阻率为10.2Ω·cm,电磁屏蔽效能达到21.66dB,超过商用需求20dB的标准,涂层表现出优异的电磁屏蔽效能,在电磁屏蔽复合材料领域中具有应用前景。

Abstract

Amino-functionalized reduced graphene oxide (RKGO) was obtained by modifying graphene oxide (GO) with silane coupling agent KH-550 and hydrazine hydrate(N2H4·H2O).RKGO was introduced into the epoxy acrylic resin (EPAA) system obtained by free radical polymerization to construct an amino-functionalized reduced graphene oxide/epoxy acrylic resin (RKGO/EPAA) electromagnetic shielding composite coating.Characterization tests were carried out by infrared and Raman spectroscopy,and the mechanical properties and electromagnetic shielding properties of the composite coatings were investigated.The results showed that the electromagnetic shielding composite coating had excellent overall mechanical properties,with a hardness of 1H and an adhesion grade of 0.When the addition amount of RKGO reached 20%,the volume resistivity of the coating was 10.2Ω·cm,and the electromagnetic shielding effectiveness reached 21.66dB,which exceeded the standard of 20dB of commercial demand.The coating exhibited excellent electromagnetic shielding effectiveness,showing promising application prospects in the field of electromagnetic shielding composite materials.

关键词

改性氧化石墨烯 / 环氧丙烯酸树脂 / 复合涂层 / 电磁屏蔽

Key words

modified graphene oxide / epoxy acrylic resin / composite coating / electromagnetic shielding

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改性氧化石墨烯复合环氧丙烯酸酯电磁屏蔽涂层的制备及其性能研究[J]. 化工新型材料, 2025, 53(12): 116-123 DOI:10.19817/j.cnki.issn1006-3536.2025.12.048

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基金资助

陕西省科技创新团队项目(2024RS-CXTD-46)

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