具有稳定超疏水性能的高效油水分离膜的制备及性能研究

考鸿铭1, 李龙云2, 许功豪1, 徐向鹏1,3, 周景淼1, 于鑫然1, 张肖1, 梁山1, 陈京1*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 157 -162.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 157-162. DOI: 10.19817/j.cnki.issn1006-3536.2025.12.043
科学研究

具有稳定超疏水性能的高效油水分离膜的制备及性能研究

    考鸿铭1, 李龙云2, 许功豪1, 徐向鹏1,3, 周景淼1, 于鑫然1, 张肖1, 梁山1, 陈京1*
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Preparation and performance of highly efficient oil-water separation membranes with stable superhydrophobic properties

  • Kao Hongming1, Li Longyun2, Xu Gonghao1, Xu Xiangpeng1,3, Zhou Jingmiao1, Yu Xinran1, Zhang Xiao1, Liang Shan1, Chen Jing1
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摘要

超疏水/超亲油材料通常涉及复杂的制备过程。为解决这一问题,受贻贝粘蛋白的启发,引入聚多巴胺(PDA)作为粘合剂,将SiO2包裹起来并将超疏水表面牢固地粘合到纤维素滤膜(FM)上。利用扫描电子显微镜、能量色散光谱和X射线光电子能谱分别研究了改性纤维素滤膜的形貌和成分。通过测量水接触角和油接触角确定了改性纤维素滤膜的润湿性。结果表明:水接触角为155.9°,油接触角为0°,表明改性纤维素滤膜具有超疏水/超亲油性。改性纤维素滤膜还具有化学稳定性、抗污性和自洁性。改性纤维素滤膜对CCl4的首次分离效率和通量分别高达99.96%和7876L/(m2·h)。它还可用于连续油水分离,50次循环后分离效率仍可达99.77%。其优异的性能使改性纤维素滤膜在含油废水处理等方面具有良好的应用前景。

Abstract

Superhydrophobic/superoleophilic materials often involve complex preparation processes.To solve this problem,inspired by mussel foot protein,polydopamine (PDA) was introduced as a binder to encapsulate silica (SiO2) and firmly bond the superhydrophobic surface to a cellulose filter membrane (FM).The morphology and composition of the modified cellulose filter membrane were investigated using scanning electron microscopy,energy dispersive spectroscopy and X-ray photoelectron spectroscopy.The wettability of the modified cellulose filter membrane was determined by measuring the water contact angle and oil contact angle.The water contact angle was 155.9° and the oil contact angle was 0°,indicating that the modified cellulose filter membrane was superhydrophobic/superoleophilic.The modified cellulose filter membrane also demonstrated chemical stability,anti-fouling capacity and self-cleaning properties.The first separation efficiency and flux of modified cellulose membrane for CCl4 reached 99.96% and 7876L/(m2·h),respectively.It could also be used for continuous oil-water separation,and the separation efficiency could still maintain 99.77% even after 50 cycles.Its excellent performance makes the modified cellulose filtration membrane have a good application prospect for the treatment of oily wastewater in harsh environments.

关键词

纤维素滤膜 / 超疏水性 / 超亲油性 / 油水分离

Key words

filter membrane / superhydrophobic / superoleophilic / oil-water separation

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具有稳定超疏水性能的高效油水分离膜的制备及性能研究[J]. 化工新型材料, 2025, 53(12): 157-162 DOI:10.19817/j.cnki.issn1006-3536.2025.12.043

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