用于放射性碘捕获的多孔有机聚合物的研究进展

仪安立, 郭彩林, 孙寒雪, 李安*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 53 -57.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 53-57. DOI: 10.19817/j.cnki.issn1006-3536.2025.12.039
综述与专论

用于放射性碘捕获的多孔有机聚合物的研究进展

    仪安立, 郭彩林, 孙寒雪, 李安*
作者信息 +

Research progress on porous organic polymers for radioactive iodine capture

  • Yi Anli, Guo Cailin, Sun Hanxue, Li An
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文章历史 +
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摘要

核能是清洁能源的代表,但伴随而来的核废料问题一直是全球各国面临的重大挑战。核废料中含有的放射性核素如 129I、131I等通常以单质和碘化物形态存在,对人类健康和生态环境有着极大的危害,如何高效捕获、回收放射性碘素具有重要的现实意义。多孔有机聚合物(POPs)是一类由强共价键连接而成的新型多孔材料,具有高比表面积、孔隙可调节、结构可控、热化学稳定性、分子设计的多功能性以及合成后可修饰等优点,是碘捕获领域极具潜力的吸附材料。重点梳理了以共轭微孔聚合物为代表的POPs材料在放射性碘素吸附、回收、捕获机理等方面的研究进展,同时提出了POPs材料在碘吸附领域面临的问题。

Abstract

Nuclear energy represents clean energy,but the accompanying problem of nuclear waste has always been a major global challenge.Radionuclides such as 129I and 131I contained in nuclear waste usually exist in the form of elements and iodides,which are extremely hazardous to human health and the ecological environment.It is of great practical significance how to efficiently capture and recycle radioactive iodine.Porous organic polymers (POPs) are a new class of porous materials connected by strong covalent bonds.They have the advantages of high specific surface area,adjustable pore size,controllable structure,thermochemical stability,multifunctionality in molecular design,and modification capability after synthesis,making them highly potential adsorbent materials in the field of iodine capture.The research progress of POPs materials represented by conjugated microporous polymers in the adsorption,recovery and capture mechanism of radioactive iodine was highlighted,and the problems faced by POPs materials in the field of iodine adsorption were also put forward.

关键词

多孔有机聚合物 / 碘捕获 / 吸附机理 / 富电子基团

Key words

porous organic polymers / iodine trapping / adsorption mechanism / electron-rich groups

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用于放射性碘捕获的多孔有机聚合物的研究进展[J]. 化工新型材料, 2025, 53(12): 53-57 DOI:10.19817/j.cnki.issn1006-3536.2025.12.039

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基金资助

兰州市青年科技人才创新项目(2024-QN-14);兰州市创新创业人才项目(2022-RC-11)

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