木质素多孔碳材料制备及其在超级电容器电极中的应用

黄睿, 庄军平*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 13 -18.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 13-18. DOI: 10.19817/j.cnki.issn1006-3536.2025.12.023
综述与专论

木质素多孔碳材料制备及其在超级电容器电极中的应用

    黄睿, 庄军平*
作者信息 +

Preparation of lignin-based porous carbon materials and their application in supercapacitor electrodes

  • Huang Rui, Zhuang Junping
Author information +
文章历史 +
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摘要

木质素作为存有量巨大的天然可再生碳基多酚类聚合物,具有成本低、易收集、含碳量高和官能团丰富等特点,经处理后可转变为高附加值的功能性材料。其中,木质素基碳材料凭借孔隙结构丰富、比表面积大、化学性质稳定和潜在的导电性等优势,被认为是制备超级电容器电活性材料的优选前体,对减少资源浪费和环境污染具有重大意义。主要综述了应用于超级电容器的木质素衍生碳材料的制备及研究进展,对木质素的基本电化学性质进行简介,并结合研究现状对木质素基超级电容器材料的发展前景进行展望。

Abstract

As a natural abundant renewable carbon-based polyphenol polymer,lignin has the characteristics of low cost,easy collection,high carbon content and rich functional groups,and can be transformed into high value-added functional materials after treatment.Among them,lignin-based carbon materials are considered to be the preferred precursors for the preparation of electroactive materials for supercapacitors due to the strengths of rich pore structure,large specific surface area,stable chemical properties and potential conductivity,which are of great significance for reducing resource waste and environmental pollution.The preparation and application of lignin-derived carbon materials for supercapacitor were mainly reviewed,the fundamental electrochemical properties of lignin were briefly introduced,and the development prospects of lignin-based supercapacitor materials were prospected combined with the research hotspots.

关键词

木质素 / 碳材料 / 超级电容器 / 电极

Key words

lignin / carbon materials / supercapacitors / electrode

引用本文

引用格式 ▾
木质素多孔碳材料制备及其在超级电容器电极中的应用[J]. 化工新型材料, 2025, 53(12): 13-18 DOI:10.19817/j.cnki.issn1006-3536.2025.12.023

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参考文献

[1] Tong Y,Yang J,Li J,et al.Lignin-derived electrode materials for supercapacitor applications:progress and perspectives[J].Journal of Materials Chemistry A,2023,11(3):1061-1082.
[2] 徐慧民,李莉娟,欧阳新华,等.木质素基超级电容器电极材料研究进展[J].中国造纸学报,2021,36(1):80-87.
[3] Jyothibasu J P,Wang R H,Tien Y C,et al.Lignin-derived quinone redox moieties for bio-based supercapacitors[J].Polymers,2022,14(15):3106.
[4] 徐斌,刘建国,张兴华,等.基于木质纤维素的生物基材料[J].化学进展,2024,36(5):709-723.
[5] 龙垠荧,杨健,管敏,等.木质素基材料在混合型超级电容器电极材料中的研究进展[J].化工进展,2022,41(9):4855-4865.
[6] 刘伟,王庆,徐伟卓,等.木质素分子在储能器件中的应用研究进展[J].林业工程学报,2024,9(1):1-20.
[7] Zhu J,Yan C,Zhang X,et al.A sustainable platform of lignin:from bioresources to materials and their applications in rechargeable batteries and supercapacitors[J].Progress in Energy and Combustion Science,2020,76:100788.
[8] Yi Y,Zhuang J,Liu C,et al.Emerging lignin-based materials in electrochemical energy systems[J].Energies,2022,15(24):9450.
[9] Park H W,Ahn H J,Roh K C.Recent advances in preparation and supercapacitor applications of lignin-derived porous carbon:a review[J].Journal of Electrochemical Science and Technology,2024,15(1):111-131.
[10] Zhong W,Su W,Li P,et al.Preparation and research progress of lignin-based supercapacitor electrode materials[J].International Journal of Biological Macromolecules,2023,259:128942.
[11] Wu Y,Cao J P,Hao Z Q,et al.One-step preparation of alkaline lignin-based activated carbons with different activating agents for electric double layer capacitor[J].International Journal of Electrochemical Science,2017,12(8):7227-7239.
[12] Pavlenko V,Żółtowska S,Haruna A B,et al.A comprehensive review of template-assisted porous carbons:modern preparation methods and advanced applications[J].Materials Science and Engineering:R:Reports,2022,149:100682.
[13] Liu J,Mei X W,Peng F.Lignin derived porous carbon with favorable mesoporous contributions for highly efficient ionic liquid-based supercapacitors[J].Chinese Chemical Letters,2023,34(10):108187.
[14] Li H,Zhao Y,Liu S,et al.Hierarchical porous carbon monolith derived from lignin for high areal capacitance supercapacitors[J].Microporous and Mesoporous Materials,2020,297:109960.
[15] Zhang X,Jian W,Zhao L,et al.Direct carbonization of sodium lignosulfonate through self-template strategies for the synthesis of porous carbons toward supercapacitor applications[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,636:128191.
[16] Liu H,Xu T,Liu K,et al.Lignin-based electrodes for energy storage application[J].Industrial Crops and Products,2021,165:113425.
[17] Cao Q,Zhu H,Xu J,et al.Research progress in the preparation of lignin-based carbon nanofibers for supercapacitors using electrospinning technology:a review[J].International Journal of Biological Macromolecules,2024,273:133037.
[18] Zhu M,Liu H,Cao Q,et al.Electrospun lignin-based carbon nanofibers as supercapacitor electrodes[J].ACS Sustainable Chemistry & Engineering,2020,8(34):12831-12841.
[19] Xu Y,Chen S,Zhu M,et al.Novel silicon-contained lignin-based carbon fibers derived from bamboo pulping black liquor with improved electrochemical performance for supercapacitors[J].Journal of Applied Polymer Science,2021,138(44):51321.
[20] Liu C,Lei T,Li Y,et al.Dissolution of alkali lignin in ionic liquid to fabricate nitrogen-doped carbon microspheres for electrochemical supercapacitors[J].Journal of Electroanalytical Chemistry,2023,951:117921.
[21] Yang J,Xiong F,Wang H,et al.Facile and scalable construction of nitrogen-doped lignin-based carbon nanospheres for high-performance supercapacitors[J].Fuel,2023,343:128007.
[22] Wang B,Zhang X,Zhou J,et al.Controllable synthesis of Fe3C-reinforced petal-like lignin microspheres with boosted electrochemical performance and its application in high performance supercapacitors[J].International Journal of Biological Macromolecules,2023,251:126325.
[23] Wang B,Xu J,Lu F,et al.Efficient utilization of lignin heterogeneity:employing a simple approach to modulate the structure-effect relationship of lignin microspheres for its high-quality applications in supercapacitors[J].Industrial Crops and Products,2024,221:119360.
[24] Liang Y,Zhou Y,Liu X,et al.Synthesis of ultra-thin graphene-like nanosheets from lignin based on evaporation induced self-assembly for supercapacitors[J].International Journal of Biological Macromolecules,2023,230:123247.
[25] Chen X,Ma J,Sun X,et al.SiC and N,S-doped carbon nanosheets and lignin-enhanced organohydrogel for low-temperature tolerant solid-state supercapacitors[J].International Journal of Biological Macromolecules,2024,258:128759.
[26] Ding Z,Mei X,Wang X.All-lignin converted graphene quantum dot/graphene nanosheet hetero-junction for high-rate and boosted specific capacitance supercapacitors[J].Nanoscale Advances,2021,3(9):2529-2537.
[27] Taer E,Yanti N,Mustika W S,et al.Porous activated carbon monolith with nanosheet/nanofiber structure derived from the green stem of cassava for supercapacitor application[J].International Journal of Energy Research,2020,44(13):10192-10205.
[28] Sun Z,Fang S,Hu Y H.3D graphene materials:from understanding to design and synthesis control[J].Chemical Reviews,2020,120(18):10336-10453.
[29] Zhou B,Li J,Liu W,et al.Functional-group modification of kraft lignin for enhanced supercapacitors[J].Chem Sus Chem,2020,13(10):2628-2633.
[30] Jiang C,Wang Z,Li J,et al.RGO-templated lignin-derived porous carbon materials for renewable high-performance supercapacitors[J].Electrochimica Acta,2020,353:136482.
[31] Fu F,Wang H,Yang D,et al.Lamellar hierarchical lignin-derived porous carbon activating the capacitive property of polyaniline for high-performance supercapacitors[J].Journal of Colloid and Interface Science,2022,617:694-703.
[32] Ehsani A,Moftakhar M K.Lignin-derived carbon as a high efficient active material for enhancing pseudocapacitance performance of p-type conductive polymer[J].Journal of Energy Storage,2021,35:102291.
[33] Makgopa K,Bello A,Raju K,et al.Emerging nanostructured materials for energy and environmental science[M].Cham:Springer International Publishing,2019:247-303.
[34] He G,Guo G,Zhou Z,et al.A lignin carbon/bismuth oxide electrode material prepared by electrostatic self-assembly with good stability in supercapacitors[J].Materials Science and Engineering:B,2023,291:116297.
[35] Panith P,Butnoi P,Intasanta V.The hybrid structure of nanoflower-like CoxMnyNizO4 nanoparticles embedded biomass-lignin carbon nanofibers as free-standing and binder-free electrodes for high performance supercapacitors[J].Journal of Alloys and Compounds,2022,918:165659.
[36] Xu J,Zhou X,Chen M.Pore structure improvement of lignin composite carbon aerogels by introducing manganese ion and its application in supercapacitors[J].Materials Research Express,2019,6(6):065036.
[37] Liu H,Chen H,Shi K,et al.Lignin-derived porous carbon for zinc-ion hybrid capacitor[J].Industrial Crops and Products,2022,187:115519.
[38] Li J,Yang J,Wang P,et al.NiCo2S4 combined 3D hierarchical porous carbon derived from lignin for high-performance supercapacitors[J].International Journal of Biological Macromolecules,2023,232:123344.
[39] Weng X,Jiang Y,Zeng Q,et al.Preparation of manganese/nitrogen-sulfur carbon electrodes from black liquor of bamboo pulp for supercapacitors[J].Journal of Alloys and Compounds,2024,1002:175333.

基金资助

国家重点研发计划项目(2022YFC2805104)

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