三聚氰胺泡沫基复合相变材料的制备与性能研究

赵旭升, 苏成松, 姜柯蕊, 蔡以兵*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 110 -115.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (12) : 110-115. DOI: 10.19817/j.cnki.issn1006-3536.2025.12.019
新材料与新技术

三聚氰胺泡沫基复合相变材料的制备与性能研究

    赵旭升, 苏成松, 姜柯蕊, 蔡以兵*
作者信息 +

Preparation and properties of melamine foam-based composite phase change materials

  • Zhao Xusheng, Su Chengsong, Jiang Kerui, Cai Yibing
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摘要

三聚氰胺泡沫(MF)是封装固-液相变材料的理想材料。通过聚二甲基硅氧烷(PDMS)将二硫化钼(MoS2)纳米颗粒粘附在MF骨架上,将其碳化后吸附聚乙二醇-6000(PEG-6000),制成复合相变材料CMFP-X MoS2@PEG。通过扫描电子显微镜、傅里叶变换红外光谱、X射线衍射仪、差示扫描量热仪等对CMFP-X MoS2@PEG的组成、形貌、储能密度和热循环稳定性进行分析,采用热红外成像仪和温度测量仪对CMFP-X MoS2@PEG导热性能和光热转换性能进行测试。结果表明,MoS2纳米颗粒均匀分布在泡沫骨架上,CMFP-X MoS2@PEG具有高储能密度、优异的防泄漏性和超过90%的光热转换效率,在太阳能收集和热疗领域具有潜在应用。

Abstract

Melamine foam (MF) is an ideal material for encapsulating solid-liquid phase change materials.Molybdenum disulfide (MoS2) nanoparticles were adhered to the MF framework using polydimethylsiloxane (PDMS),followed by carbonization and adsorption of polyethylene glycol-6000 (PEG-6000) to form composite phase change materials (CMFP-X MoS2@PEG).The composition,morphology,energy storage density,and thermal cycling stability of CMFP-X MoS2@PEG were analyzed using scanning electron microscopy (SEM),Fourier-transform infrared spectroscopy (FT-IR),X-ray diffraction (XRD),and differential scanning calorimetry (DSC).The thermal conductivity and photothermal conversion performance of the samples were tested using thermal infrared imaging and temperature measurement instruments.The results showed that MoS2 nanoparticles were uniformly distributed on the foam framework.CMFP-X MoS2@PEG exhibited high energy storage density,excellent leak-proof performance,and photothermal conversion efficiency exceeding 90%,indicating potential applications in solar energy collection and thermal therapy fields.

关键词

三聚氰胺泡沫 / MoS2纳米颗粒 / 聚乙二醇 / 相变材料 / 光热转换

Key words

melamine foam / MoS2 nanoparticles / polyethylene glycol / phase change material / photothermal conversion

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三聚氰胺泡沫基复合相变材料的制备与性能研究[J]. 化工新型材料, 2025, 53(12): 110-115 DOI:10.19817/j.cnki.issn1006-3536.2025.12.019

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基金资助

国家自然科学基金(22478161);装备预研教育部联合基金(8091B022202);江苏省基础研究计划(BK20242082)

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