碳材料因性能优异而被广泛应用于能源储存与转换领域,其中生物质炭材料因具有结构和性能可调、良好的环境效益和经济价值而备受关注。近年来生物质活性炭在制备工艺和功能化设计方面取得了较大的进展。综述了生物质活性炭在有机相变材料封装和海水淡化等储能领域及光热转换领域的应用研究进展,并展望了生物质活性炭未来的发展方向。
Carbon materials are widely used in the field of energy storage and conversion due to their excellent performance.Among them,biomass carbon materials have attracted much attention due to their adjustable structure and performance,good environmental benefits and economic value.In recent years,great progress has been made in the preparation process and functional design of biomass activated carbon.The application progress of biomass activated carbon in the fields of energy storage and photothermal conversion,such as encapsulation of organic phase change materials and desalination of seawater,was reviewed.The future development directions of biomass activated carbon were prospected.
[1] Zhu R,Yu Q F,Li M,et al.Analysis of factors influencing pore structure development of agricultural and forestry waste-derived activated carbon for adsorption application in gas and liquid phases:a review[J].Journal of Environmental Chemical Engineering,2021,9(5):105905.
[2] Jiang L L,Sheng L Z,Fan Z J.Biomass-derived carbon materials with structural diversities and their applications in energy storage[J].Science China Materials,2018,61(2):133-158.
[3] Wang Y L,Zhang M C,Shen X Y,et al.Biomass-derived carbon materials:controllable preparation and versatile applications[J].Small,2021,17(40):2008079.
[4] Sekar M,Mathimani T,Alagumalai A,et al.A review on the pyrolysis of algal biomass for biochar and bio-oil-bottlenecks and scope[J].Fuel,2021,283(1):119190.
[5] Kevin M D W,Pradhan R,Dutta A.Catalytic hydrothermal carbonization treatment of biomass for enhanced activated carbon:a review[J].Waste and Biomass Valorization,2021,12(12):2171-2186.
[6] Ahmad A A,Marwan A R,Shareef N,et al.Production of activated carbon derived from agricultural by-products via microwave-induced chemical activation:a review[J].Carbon Letters,2021,31:957-971.
[7] 冯利利,侯玉星,余润翔,等.多孔碳基定形相变储热材料的研究进展[J].煤炭学报,2022,47(9):3328-3338.
[8] 梁西妹,费华,蒋达华,等.生物质多孔高导热碳基复合相变材料热性能的研究进展[J].化工新型材料,2023,51(8):1-6.
[9] Huang J T,Wu B Y,Lyu S,et al.Improving the thermal energy storage capability of diatom-based biomass/polyethylene glycol composites phase change materials by artificial culture methods[J].Solar Energy Materials and Solar Cells,2021,219(1):110797.
[10] Tan B T,Huang Z H,Yin Z Y,et al.Preparation and thermal properties of shape-stabilized composite phase change materials based on polyethylene glycol and porous carbon prepared from potato[J].RSC Adv,2016,6(19):15821-15830.
[11] 李绍伟,傅彬彬,李静.碳化柚子皮基复合相变材料的制备及性能[J].复合材料学报,2022,39(6):2885-2893.
[12] Xie Y H,Li W J,Huang H W,et al.Bio-based radish@PDA/PEG sandwich composite with high efficiency solar thermal energy storage[J].ACS Sustainable Chem Eng,2020,22(8):8448-8457.
[13] Hu X P,Huang H W,Hu Y B,et al.Novel bio-based compo-site phase change materials with reduced graphene oxide-functionalized spent coffee grounds for efficient solar-to-thermal energy storage[J].Solar Energy Materials and Solar Cells,2021,219(1):110790.
[14] Li Y Q,Huang X B,Li Y,et al.Shape-stabilized phase change materials supported by eggplantsderived porous carbon for efficient solar-to-thermal energy conversion and storage[J].Sustainable Energy Fuels,2020,4(4):1764-1772.
[15] 李亚琼,李洋,席作帅,等.茄子衍生多孔碳负载聚乙二醇相变复合材料[J].工程科学学报,2020,42(1):106-112.
[16] Zhang C G,Hu X W,Xiao S K,et al.Enhanced thermal performance of phase-change material supported by nano-Ag coated eggplant-based biological porous carbon[J].Journal of Energy Storage,2021,43(11):103174.
[17] Jens U H,Fabian H,Jörg W,et al.Impregnation of wood with a paraffinic phase change material for increasing heat capacity[J].Wood Material Science & Engineering,2023,18(1):19-28.
[18] 陈子禾,赵呈志,冒文莉,等.定向生物质多孔碳复合相变材料的制备及其热性能研究[J].化工学报,2022,73(4):1817-1825.
[19] 王冲威,张天赐,金听祥,等.生物基多孔炭复合相变材料的制备及性能研究[J].化工新型材料,2024,52(9):80-83;88.
[20] 徐琬茹,洪宇翔,杜娟,等.甘蔗渣多孔碳基复合相变材料的制备及其性能研究[J].广西科技大学学报,2025,36(3):107-115.
[21] Li S Q,Wang H,Gao X,et al.Design of corn straw/paraffin wax shape-stabilized phase change materials with excellent thermal buffering performance[J].Journal of Energy Storage,2023,57(1):106217.
[22] Xiong T,Yong S O,Pavani D D,et al.Preparation and thermal conductivity enhancement of a paraffin wax-based composite phase change material doped with garlic stem biochar micro-particles[J].Science of the Total Environment,2022,827(27):154341.
[23] Ji Z,Abdaikarim S Y H,Li Huimin,et al.Waste pomelo peels-derived ultralow density 3D-porous carbon aerogels:mechanisms of “Soft-rigid” structural formation and solar-thermal energy storage conversion[J].Solar Energy Materials and Solar Cells,2023,259(11):112453.
[24] Sheng N,Nomura T,Zhu C,et al.Cotton-derived carbon sponge as support for form-stabilized composite phase change materials with enhanced thermal conductivity[J].Solar Energy Materials and Solar Cells,2019,192(4):8-15.
[25] 李洁,张佳,江晓明,等.石蜡基新型导热型复合相变材料的制备及性能研究[J].材料导报,2023,37(S1):572-575.
[26] 户晶荣,李欣聪.改性碳气凝胶/石蜡复合相变储热材料的研究[J].无机盐工业,2024,56(5):58-63.
[27] 禹兴海,唐海慰,李艳安,等.一种光、电驱动的生物碳/硬脂酸复合相变材料的制备及其性能[J].化工进展,2022,41(11):5936-5945.
[28] Mehrali M,Latibari S T,Rosen M A,et al.From rice husk to high performance shape stabilized phase change materials for thermal energy storage[J].RSC Adv,2016,6(51):45595-45604.
[29] Gökhan H,Ahmet S,Turgay K,et al.Walnut shell derived bio-carbon/methyl palmitate as novel composite phase change material with enhanced thermal energy storage properties[J].Journal of Energy Storage,2021,35(3):102288.
[30] Wang C J,Liang W D,Yang Y Y,et al.Biomass carbon aerogels based shape-stable phase change composites with high light-to-thermal efficiency for energy storage[J].Renewable Energy,2020,153:182-192.
[31] He Q,Fei H,Zhou J H,et al.Utilization of carbonized water hyacinth for effective encapsulation and thermal conductivity enhancement of phase change energy storage materials[J].Construction and Building Materials,2023,372(1):130841.
[32] Liu H,Qian Z Q,Wang Q W,et al.Development of renewable biomass-derived carbonaceous aerogel/mannitol phase-change composites for high thermal energy-release efficiency and shape stabilizati[J].ACS Applied Energy Materials,2021,4(2):1714-1730.
[33] Zhang Q,Zhang Y S,Shen Y,et al.Improving seawater desalination efficiency by solar driven interfacial evaporation based on biochar evaporator of nannochloropsis oculata residue[J].Journal of Environmental Chemical Engineering,2021,9(4):105787.
[34] Karen W M J,Wang Z P,Li Y H,et al.Low-cost and sustainable carbonized sawdust based solar absorber for solar vapor generation towards seawater desalination[J].Waste and Biomass Valorization,2023,14(10):3071-3080.
[35] Ma N,Fu Q,Hong Y X,et al.Processing natural wood into an efficient and durable solar steam generation device[J].ACS Appl Mater Interfaces,2020,12(15):18165-18173.
[36] Fang S,Lyu X Y,Tong T,et al.Turning dead leaves into an active multifunctional material as evaporator,photocatalyst,and bioplastic[J].Nature Communications,2023,14:1203.
[37] Guo H X,Li T J,Ai S,et al.Evaporator fabricated with accessible photothermal material derived from waste fallen leaves for highly efficient desalination[J].Applied Surface Science,2023,619:156728.
[38] Zhang C F,Yuan B H,Liang Y,et al.Solar vapor generator:a natural all-in-one 3D system derived from cattail[J].Solar Energy Materials and Solar Cells,2021,227(9):111127.
[39] Sun Y,Zhao Z B,Zhao G Y,et al.High performance carbo-nized corncob-based 3D solar vapor steam generator enhanced by environmental energy[J].Carbon,2021,179(9):337-347.
[40] Feng J,Bai B,Yang L,et al.Low-cost and facile hydrophilic amplification of raw corn straws for the applications of highly efficient interfacial solar steam generation[J].Materials Chemistry and Physics,2021,271(15):124904.
[41] Zeng L,Deng D X,Zhu L Y,et al.Biomass photothermal structures with carbonized durian for efficient solar-driven water evaporation[J].Energy,2023,273:127170.
[42] Phan T T,Nguyen T H,Nguyen T A H,et al.Durable,scalable and affordable iron(Ⅲ) based coconut husk photothermal material for highly efficient solar steam generation[J].Desalination,2021,518(22):115280.
[43] Wang X C,Zhang L J,Zheng D,et al.A polyelectrolyte hydrogel coated loofah sponge evaporator based on donnan effect for highly efficient solar-driven desalination[J].Chemical Engineering Journal,2023,462:142265.
[44] Guo M X,Wu J B,Zhao H Y,et al.Carbonized loofah and MOF-801 of synergistic effect for efficient solar steam generation[J].Int J Energy Res,2021,45(1):10599-10608.
[45] Kumar R,Tripathi P,Ongar B,et al.Experimental study on double effect solar distiller using bioactivity nanoparticles with analysis of thermo-economic and enviro-economical[J].Case Studies in Thermal Engineering,2023,47:103045.
[46] Yang J Y,Suo X D,Chen X R,et al.Water-light induced self-blacking system constituted by quinoa cellulose and graphene oxide for high performance of salt-rejecting solar desalination[J].Advanced Sustainable Systems,2022,6(1):2100350.
[47] Wu J,Yang X Y,Jia X H,et al.Full biomass-derived multifunctional aerogel for solar-driven interfacial evaporation[J].Chemical Engineering Journal,2023,471:144684.
[48] Shafaee M,Goharshadi E K,Ghafurian M M,et al.A highly efficient and sustainable photoabsorber in solar-driven seawater desalination and wastewater purification[J].RSC Advances,2023,13:17935.
[49] Zhai S M,Li M,Peng H Y,et al.Cost-effective resource utilization for waste biomass:a simple preparation method of photothermal biochar cakes (BCs) toward dye wastewater treatment with solar energy[J].Environmental Research,2021,194(3):110720.
[50] Duan H Y,Wang M X,Zhang Z W,et al.Biomass-derived photothermal carbon aerogel for efficient solar-driven seawater desalination[J].Journal of Environmental Chemical Engineering,2023,11(2):109295.
基金资助
四川省自然科学基金(2025ZNSFSC0375);工业固态废弃物土木工程综合开发利用四川省高校重点实验室项目(SC-FQWLY-2022-Y-08);攀枝花学院2024年双创项目(SC202413)
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