全氟弹性体(PFE)因具有优异的耐化学性和耐温性而备受关注。综述了PFE的结构组成、制备工艺和应用领域;阐述了聚合单体类型及对PFE性能的影响;总结了PFE在半导体、航空航天、石油开采、低温极端环境等多个领域的应用现状。基于PFE的研究现状,对PFE的未来发展方向和改进措施进行了展望。
Perfluoroelastomer (PFE) has garnered significant attention due to its exceptional chemical resistance and heat resistance performance.The paper reviewed the construction,preparation and application of PFE.The types of polymeric monomers and their effects on PFE properties were described.The application status of PFE in many fields such as semiconductor,aerospace,petroleum exploitation and low-temperature extreme environments was summarized.Based on the research status,the paper discussed the future development directions and improvement measures of PFE.
[1] 邢华艳,刘波,郭澎湃,等.国产全氟醚橡胶的开发与应用[J].有机氟工业,2023(1):20-23.
[2] 王珍,刘金岭,陆明.不同交联结构全氟醚橡胶的硫化动力学[J].弹性体,2022,32(5):1-6.
[3] 李伟.特种含氟弹性体复合材料的制备与性能研究[D].北京:北京化工大学,2024.
[4] 高燕,向宇.全氟醚橡胶及其制品在密封行业的应用[J].汽车零部件,2015(6):59-63.
[5] 冯洪福,苏有学,孙超超,等.耐高温全氟醚橡胶复合材料研究进展与展望[J].高分子材料科学与工程,2023,39(7):185-190.
[6] 张世鑫,魏海东,储民.氧化石墨烯在半导体加工用O形圈全氟醚橡胶材料中的应用[J].橡胶工业,2022,69(4):279-283.
[7] 薛丹伟,唐京,陈志锋.全氟醚橡胶简介[J].有机氟工业,2023(2):34-40.
[8] 张建新,李斌,兰军,等.各种单体对耐低温氟醚橡胶性能的影响[J].化工新型材料,2011,39(1):122-125.
[9] 张勤来.含有不同硫化点单体的全氟弹性体[J].有机氟工业,2002(4):55-59.
[10] 杨晓勇.中国特种氟橡胶研究进展[J].高分子通报,2014(5):10-14.
[11] Shimizu T,Inagaki S.Development of a novel cross-linking agent with excellent resistance to high-temperature vapour[J].Sealing Technology,2017,5:7-11.
[12] Easton M P,Fournier E W,Genova S,et al.Effects of nitrogen tetroxide exposure on dupont kalrez-1045[J].Polymer,1993,34(7):1401-1409.
[13] 曾波,汪仲权,陈立义,等.4-溴-3,3,4,4-四氟丁烯对全氟醚橡胶性能的影响研究[J].有机氟工业,2017(4):5-7,17.
[14] 张亨.全氟醚橡胶的性能研究进展[J].橡塑技术与装备,2015,41(3):29-34.
[15] 张亨.全氟醚橡胶的性能、生产和应用[J].有机氟工业,2013(3):38-40.
[16] Zhuo W,Wang Q,Li G,et al.Detection of the destruction mechanism of perfluorinated elastomer network under thermo-oxidative aging conditions[J].Chinese Journal of Polymer Science,2022,40(5):504.
[17] 田志扬,陶春建.炭黑与氧化锌对于全氟醚橡胶性能的影响[J].化工生产与技术,2023,29(2):1-2,21,61.
[18] 江畹兰.新型硫化剂ДИПИА-65对全氟醚橡胶Неофтон-Н性能的影响[J].世界橡胶工业,2017,44(2):10-14.
[19] 史勇,董超峰.全氟醚橡胶配方设计及混炼工艺性研究[J].生物化工,2021,7(2):55-56,60.
[20] 王楠.全氟弹性体应用进展(上)[J].橡塑技术与装备,2017,43(9):21-24.
[21] 田志扬.集成电路设备用全氟醚橡胶密封件的国产化[J].化工生产与技术,2023,29(1):13-15,8.
[22] Heller M,Legare J,Wang S H,et al.Thermal stability and sealing performance of perfluoroelastomer seals as a function of crosslinking chemistry[J].Journal of Vacuum Science & Technology A-Vacuum Surfaces and Films,1999,17(4):2119-2124.
[23] Legare J,Wang S,Vigliotti,Michele et,al.Contamination consider-ations for perfluoroelastomer seals used in deposition processes[C].IEEE/SEMI Advanced Semiconductor Manufacturing Conferenc,2008.
[24] Wang S,Legare J.Perfluoroelastomer and fluoroelastomer seals for semiconductor wafer processing equipment[J].Journal of Fluorine Chemistry,2003,122:113-119.
[25] Reger T,Reich G.Science of sealing:advanced materials for high-temperature applications[C].31st Annual Semi Advanced Semiconductor Manufacturing Conference,2020.
[26] 张世鑫,魏海东,储民.氧化石墨烯在半导体加工用O形圈全氟醚橡胶材料中的应用[J].橡胶工业,2022,69(4):279-283.
[27] 孟庆文,余国军,黄军,等.含氟聚合物在半导体行业中的应用[J].化工生产与技术,2022,28(4):17-19,29,8.
[28] 罗生乔,窦若岸,赖碧红.全氟弹性体密封件在半导体工业中的选择和应用[J].有机氟工业,2022(4):58-64.
[29] 铃木雄太,福士达夫.防粘全氟弹性体制品及其制备方法:美国,CN116829325A[P].2023-09-29.
[30] 李振环,孔建,杨家义,等.全氟醚橡胶制品的应用及案例失效分析1[J].液压气动与密封,2012,32(1):48-51.
[31] 王婧,韩秀峰,廉一龙,等.含氟橡胶的研究进展及在航空发动机中的应用[J].合成橡胶工业,2021,44(2):150-157.
[32] 董雅卓,冀克俭,侯倩倩,等.氟醚橡胶研究及应用进展[J].合成橡胶工业,2021,44(3):240-244.
[33] 冯洪福,苏有学,孙超超,等.耐高温全氟醚橡胶复合材料研究进展与展望[J].高分子材料科学与工程,2023,39(7):185-190.
[34] 朱永康.FKM和FFKM交联方法及其对密封件使用温度上限的影响[J].有机氟工业,2022(1):59-64.
[35] Davis L.Trelleborg engineers FFKM material to meet demanding EOR requirements[J].Sealing Technology,2017,11:2.
[36] 贺秋云,韩雄,曾小军.高温高压井下测试工具橡胶密封材料的优选[J].钻采工艺,2019,42(4):36-39,8.
[37] 李恩军,苟文亮,李耿,等.一种高强高模全氟醚橡胶材料及其制备方法与应用:中国,202010664376.8[P].2020-11-13.
[38] 蒋召平,王通,李海涛等.海上耐高温深水式井下安全阀的设计与试验[J].石油机械,2019,47(8):74-78.
[39] 谢忠麟,马晓,吴淑华.高性能特种弹性体的拓展(四)——氟橡胶(2)[J].橡胶工业,2022,69(2):149-159.
[40] Arrigoni S,Merli F.New perfluoroelastomer for sealing at low temperatures[J].Sealing Technology,2021,2010(9):9-13.
[41] Apostolo M,Triulzi F,Tortelli V,et al.Fluoroelastomers:America,US2006002552[P].2005-07-28.
PDF
