A major factor contributing to global climate change and environmental degradation is the continuous increase in the concentration of carbon dioxide (CO2) in the atmosphere.This phenomenon not only intensifies the greenhouse effect but also poses a threat to the balance of the ecosystem and human health.To address this issue,scientists are actively exploring porous materials that can efficiently adsorb and transform CO2.Porous organic polymers (POPs),with their large specific surface areas,tunable pore structures,and excellent physicochemical properties,have become a research hotspot.POPs can serve not only as adsorbents for CO2 but also as catalysts to promote the conversion of CO2 into useful chemicals.This paper comprehensively reviewed the research progress of POPs in the fields of CO2 adsorption and catalysis,analyzed the key factors influencing CO2 adsorption and conversion,and also highlighted the existing challenges in this filed.
[1] Liu Z,Guan D B,Wei W,et al.Reduced carbon emission estimates from fossil fuel combustion and cement production in China[J].Nature,2015,524(7565):335-338.
[2] Davis J S,Caldeira K,Matthews H D.Future CO2 emissions and climate change from existing energy infrastructure[J].Science,2010,329(5997):1330-1333.
[3] Moreno D,Bang A,Nielsen S,et al.Strategic management of CO2:a scalable model for CCS in decarbonised societies[J].Journal of Environmental Management,2024,368:122175.
[4] 张帅.CO2捕集封存技术的应用与安全发展研究[J].当代化工研究,2022,5(20):93-95.
[5] Singh G,Lee J,Karakoti A,et al.Emerging trends in porous materials for CO2 capture and conversion[J].Chemical Society Reviews,2020,49(13):4360-4404.
[6] Song K S,Fritz P W,Coskun A.Porous organic polymers for CO2 capture,separation and conversion[J].Chemical Society Reviews,2022,51(23):9831-9852.
[7] Kaur P,Hupp J T,Nguyen S T.Porous organic polymers in catalysis:opportunities and challenges[J].ACS Catalysis,2011,1(7):819-835.
[8] 陈亚举,任清刚,周贤太,等.多孔有机聚合物催化二氧化碳合成环状碳酸酯研究进展[J].化工进展,2021,40(7):3564-3583.
[9] Wang S T,Li H T,Huang H A,et al.Porous organic polymers as a platform for sensing applications[J].Chemical Society Reviews,2022,51(6):2031-2080.
[10] Tian J,Lin F R,Yu S B,et al.Water-dispersible and soluble porous organic polymers for biomedical applications[J].Aggregate,2022,3(5):187.
[11] Kim J H,Kang D W,Yun H,et al.Post-synthetic modifications in porous organic polymers for biomedical and related applications[J].Chemical Society Reviews,2022,51(1):43-56.
[12] Taheri N,Dinari M,Asgari M.Recent applications of porous organic polymers prepared via Friedel-Crafts reaction under the catalysis of AlCl3:a review[J].ACS Applied Polymer Materials,2022,4(9):6288-6302.
[13] Bhanja P,Chatterjee S,Bhaumik A.Triazine-based porous organic polymer with good CO2 gas adsorption properties and an efficient organocatalyst for the one-pot multicomponent condensation reaction[J].ChemCatChem,2016,8(19):3089-3098.
[14] Bhunia M K,Das S K,Pachfule P,et al.Nitrogen-rich porous covalent imine network (CIN) material as an efficient cataly-tic support for C—C coupling reactions[J].Dalton Trans,2012,41(4):1304-1311.
[15] Esteban N,Ferrer M L,Ania C O,et al.Porous organic polymers containing active metal centers for suzuki-miyaura he-terocoupling reactions[J].ACS Applied Materials & Interfaces,2020,12(51):56974-56986.
[16] Chen Q,Luo M,Hammershøj P,et al.Microporous polycarbazole with high specific surface area for gas storage and separation[J].Journal of the American Chemical Society,2012,134(14):6084-6087.
[17] Tan L X,Tan B E.Hypercrosslinked porous polymer materials:design,synthesis,and applications[J].Chemical Society Reviews,2017,46(11):3322-3356.
[18] Xu Y H,Jin S B,Xu H,et al.Conjugated microporous polymers:design,synthesis and application[J].Chemical Society Reviews,2013,42(20):8012-8031.
[19] Mckeown N B,Budd P M.Polymers of intrinsic microporosity (PIMs):organic materials for membrane separations,heterogeneous catalysis and hydrogen storage[J].Chem Soc Rev,2006,35(8):675-683.
[20] Tian Y Y,Zhu G S.Porous aromatic frameworks (PAFs)[J].Chemical Reviews,2020,120(16):8934-8986.
[21] CôTé A P,Benin A I,Ockwig N W,et al.Porous,crystalline,covalent organic frameworks[J].Science,2005,310(5751):1166-1170.
[22] Kuhn P,Antonietti M,Thomas A.Porous,covalent triazine-based frameworks prepared by ionothermal synthesis[J].Angewandte Chemie International Edition,2008,47(18):3450-3453.
[23] Ben T,Ren H,Ma S Q,et al.Targeted synthesis of a porous aromatic framework with high stability and exceptionally high surface area[J].Angewandte Chemie International Edition,2009,48(50):9457-9460.
[24] Yuan D Q,Lu W G,Zhao D,et al.Highly stable porous polymer networks with exceptionally high gas-uptake capacities[J].Advanced Materials,2011,23(32):3723-3725.
[25] Martin C F,Stöckel E,Clowes R,et al.Hypercrosslinked organic polymer networks as potential adsorbents for pre-combustion CO2 capture[J].Journal of Materials Chemistry,2011,21(14):5475-5483.
[26] Zou L F,Sun Y J,Che S,et al.Porous organic polymers for post-combustion carbon capture[J].Advanced Materials,2017,29(37):1700229.
[27] Yan J,Tan Y,Wei L L,et al.Friedel-Crafts synthesis of carbazole-based hierarchical nanoporous organic polymers for adsorption of ethane,carbon dioxide,and methane[J].Industrial & Engineering Chemistry Research,2022,61(36):13453-13460.
[28] Yuan R R,Zhang M Y,Sun H.Design and construction of an azo-functionalized POP for reversibly stimuli-responsive CO2 adsorption[J].Polymers,2023,15(7):1709.
[29] Huang K,Liu F J,Dai S.Solvothermal synthesis of hierarchically nanoporous organic polymers with tunable nitrogen functionality for highly selective capture of CO2[J].Journal of Materials Chemistry A,2016,4(34):13063-13070.
[30] Zhu X,Tian C C,Veith G M,et al.In Situ doping strategy for the preparation of conjugated triazine frameworks displaying efficient CO2 capture performance[J].Journal of the American Chemical Society,2016,138(36):11497-11500.
[31] Liu M Q,Shao L S,Huang J H,et al.O-containing hyper-cross-linked polymers and porous carbons for CO2 capture[J].Microporous and Mesoporous Materials,2018,264:104-111.
[32] Liao C,Liang Z,Liu B,et al.Phenylamino-,phenoxy-,and benzenesulfenyl-Linked covalent triazine frameworks for CO2 capture[J].ACS Applied Nano Materials,2020,3(3):2889-2898.
[33] Fu Y,Wang Z Q,Li S Z,et al.Functionalized covalent triazine frameworks for effective CO2 and SO2 removal[J].ACS Applied Materials & Interfaces,2018,10(42):36002-36009.
[34] Jing X F,Zou D L,Cui P,et al.Facile synthesis of cost-effective porous aromatic materials with enhanced carbon dioxide uptake[J].Journal of Materials Chemistry A,2013,1(44):13926-13931.
[35] Yuan R R,Ren H,Yan Z J,et al.Robust tri(4-ethynylphenyl)amine-based porous aromatic frameworks for carbon dioxide capture[J].Polymer Chemistry,2014,5(7):2266-2272.
[36] Hei Z H,Huang M H,Luo Y J,et al.A well-defined nitro-functionalized aromatic framework (NO2-PAF-1) with high CO2 adsorption:synthesis via the copper-mediated Ullmann homo-coupling polymerization of a nitro-containing monomer[J].Polymer Chemistry,2016,7(4):770-774.
[37] Cui Y,Xu Z,Li H Y,et al.Synthesis of a pyrazole-based microporous organic polymer for high-performance CO2 capture and alkyne carboxylation[J].ACS Applied Polymer Materials,2020,2(11):4512-4520.
[38] Dai Z F,Sun Q,Liu X L,et al.A hierarchical bipyridine-constructed framework for highly efficient carbon dioxide capture and catalytic conversion[J].ChemSusChem,2016,10(6):1186-1192.
[39] Dai Z F,Sun Q,Liu X L,et al.Metalated porous porphyrin polymers as efficient heterogeneous catalysts for cycloaddition of epoxides with CO2 under ambient conditions[J].Journal of Catalysis,2016,338:202-209.
[40] Wang W,Li C,Yan L,et al.Ionic liquid/Zn-PPh3 integrated porous organic polymers featuring multifunctional sites:highly active heterogeneous catalyst for cooperative conversion of CO2 to cyclic carbonates[J].ACS Catalysis,2016,6:6091-6100.
[41] Sun Q,Jin Y Y,Aguila B,et al.Porous ionic polymers as a robust and efficient platform for capture and chemical fixation of atmospheric CO2[J].ChemSusChem,2016,10(6):1160-1165.
[42] Chen Y J,Luo R C,Xu Q H,et al.State-of-the-art aluminum porphyrin-based heterogeneous catalysts for the chemical fi-xation of CO2 into cyclic carbonates at ambient conditions[J].ChemCatChem,2017,9(5):767-773.
基金资助
内蒙古自治区高等学校科学研究项目(NJZZ23063);内蒙古高校基本科研项目(2024YXXS050)
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