共价有机框架(COFs)的可功能化、高比表面积和可调节的孔径使其具有了各种各样的应用。环糊精起到的包合作用使其在医药业、食品业、药物分析上都有广泛的使用。将上述两种物质合成的材料即环糊精修饰共价有机框架(CD-COFs)进行总结概括,综述了CD-COFs的合成制备方法,包括“Click”反应、席夫碱反应、中和反应等。CD-COFs作为一种多功能的多孔材料,在气体吸附、药物传递、荧光传感和分离分析等领域得到了独特的探索和应用。
The functionalization,high specific surface area and adjustable pore size of covalent organic frameworks (COFs) make them have a variety of applications.Cyclodextrin has been widely used in the pharmaceutical industry,food industry and drug analysis due to its inclusion function.In this paper,the materials synthesized from the above two substances,namely cyclodextrin-modified covalent organic frameworks (CD-COFs),were summarized.The synthesis methods of CD-COFs,including “Click” reaction,Schiff base reaction and neutralization reaction,were reviewed.As a multifunctional porous material,CD-COFs were uniquely explored and applied in the fields of gas adsorption,drug delivery,fluorescence sensing and separation analysis.
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基金资助
北京市自然科学基金项目(2242005);北京石油化工学院致远科研基金项目(2024004);国家级大学生创新创业训练计划项目(2023310325)
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