Nowadays,the problem of water resource pollution is becoming more serious,and the removal of organic dye pollutants in freshwater is facing a major challenge.γ-Al2O3,as a new type of pore material,can be widely used in the fields of adsorption,catalysis,medicine and new energy,but the cost of preparing and application of γ-Al2O3 material remains high due to the low recovery of powder γ-Al2O3 material in practical applications.Spherical mesoporous γ-Al2O3 materials with high purity,good sphericity,high compressive strength,tunable pore structure and high dye-removal ability were prepared by sol-gel and oil-ammonia column forming methods without adding any additives using aluminum isopropoxide as the source of organic aluminum.At the same time,we explored the effect of the acid addition method on the material's pore structure and other physical and chemical properties.We selected Congo red (CR) dye to test the adsorption properties of the prepared spherical γ-Al2O3.According to the test results,the removal of CR dye solution by the prepared material was close to 100%,and the adsorption of CR by the sample was maintained above 97% after five cyclic adsorption tests.This facile and delicate way for the preparation of spherical mesoporous γ-Al2O3 materials has potential value to be widely used in wastewater purification,industrial catalysis,material production and medicine.
[1] Lu X,Wu P,Chi C,et al.A recyclable elastic foam composite with spatially separated adsorption sites for simultaneous capture of multiple contaminants in complex wastewater[J].Separation and Purification Technology,2025,354(8):129551.
[2] Eunmi I,Jun H S,In D K,et al.Bimodally-porous alumina with tunable mesopore and macropore for efficient organic adsorbents[J].Chemical Engineering Journal,2021,416:129147.
[3] Jiawei Y,Xinshuang G,Haifeng G,et al.Scalable preparation of sub-millimeter double-shelled Al2O3 hollow spheres and their rapid separation from wastewater after adsorption of congo red[J].ACS Omega,2022,7(42):37629-37639.
[4] Yang Zhenhao,Liu Guihua,Qi Tiangui,et al.Influence of NH4BF4 on the alumina phase transition and morphology[J].Materials Letters,2023,345:134474.
[5] Svarovskaya N,Glazkova E,Bakina O,et al.Hierarchical alumina:from pure phase to nanocomposites[J].Recent Patents on Nanotechnology,2020,14:92-101.
[6] Fedorov A,Gulyaeva Y.Strength statistics for porous alumina[J].Powder Technology,2019,343:783-791.
[7] Abdollahi M,Atashi H,Tabrizi F F.Parametric investigation of γ-alumina granule preparation via the oil-drop route[J].Advanced Powder Technology,2017,28(5):1356-1371.
[8] Khanbolouk F,Akia M,Arandiyan H,et al.Utilization of spray-dried nanoporous gamma alumina support in biodiesel production from waste cooking oil[J].Journal of Nanostructure in Chemistry,2017,7(2):191-200.
[9] Mo Y,Li C,Li H,et al.Innovative construction of macroporous-mesoporous structured spherical alumina and its hydrothermal stability[J].Particuology,2024,90:429-435.
[10] Xie Yadian,Gao Lanxing,Xue Miaoxuan,et al.The morphologically controlled synthesis and application of mesoporous alumina spheres[J].Molecules(Basel,Switzerland),2023,28(15):5622.
[11] Gaweγ B,Ye G.Hierarchical γ-alumina monoliths with macro and meso porosity prepared by using cross-linked dextran gel beads as the template[J].Materials Letters,2013,95:86-88.
[12] Cao Lei,Qian Rong,Zhang Yuanyuan,et al.Surface modification of PtSn/Al2O3 catalyst by organic acid chelation and its effect on propane dehydrogenation performance[J].Journal of Physics and Chemistry of Solids,2023,178:111331.
[13] Dabbagh Hossein A,Majd Mahdieh Mozaffari,Bahrami Fahimeh,et al.Effect of vitamin C template on morphology and structure of alumina:emerging application in enantiomer separation[J].Chemical Papers,2019,73:1931-1943.
[14] Rafiz Kishen,Murali Dheeraj Ram Lingam,Lin Jerry Y S.Suppressing lithium dendrite growth on lithium-ion/metal batteries by a tortuously porous γ-alumina separator[J].Electrochimica Acta,2022,421:140478.
[15] Panigrahi Subhasmita,Priyadarshini Sushree S,Mishra Pravat Manjari,et al.Algal biomass-silver nanoparticle composite as a heterogenous catalyst for the reduction of congo red[J].Water Air Soil Pollution,2024,235:209.
[16] Al-Salihi Sara,Jasim Ahmed M,Fidalgo Maria M,et al.Removal of congo red dyes from aqueous solutions by porous γ-alumina nanoshells[J].Chemosphere,2022,286(2):131769.
[17] Tian J,Tian P,Pang H,et al.Fabrication synthesis of porous Al2O3 hollow microspheres and its superior adsorption performance for organic dye[J].Microporous and Mesoporous Materials,2016,223:27-34.
[18] Li Zhonglin,Wang Ding,Lv Fengcheng,et al.Synthesis and characterization of high-purity mesoporous alumina with excellent adsorption capacity for congo red[J].Materials,2022,15(3):970.
[19] Islam Aminul,Taufiq-Yap Yun Hin,Ravindra Pogaku,et al.Biodiesel synthesis over millimetric γ-Al2O3/KI catalyst[J].Energy,2015,89:1-9.
[20] Xi Xiaojing,Li Juan,Chen Huajun,et al.The fabrication of mesoporous η-Al2O3 nanofiber with tunable pore size by template-induced strategy[J].Materials Today Communication,2023,36:106743.
[21] Cui X,Tang S,Zhou H.Mesoporous alumina materials synthesized in different gel templates[J].Materials Letters,2013,98:116-119.
[22] Tang W,Yuan Y,Hu G,et al.Ammonium salt-assisted preparation of porous high-purity γ-Al2O3 with a high specific surface area[J].Ceramics International,2024,50(5):7255-7265.
[23] Liu Tianyu,Zhang Jie,Ouyang Peiwen,et al.The relation between nanotube diameter,length and surface area and pore volume of multi-walled spiral halloysite nanotubes:a theoretical study[J].Applied Clay Science,2021,215:106303.
[24] Zhao S,Wen Y,Du C,et al.Introduction of vacancy capture mechanism into defective alumina microspheres for enhanced adsorption of organic dyes[J].Chemical Engineering Journal,2020,402:126180.
[25] Wang L,Wang A.Adsorption properties of congo red from aqueous solution onto surfactant-modified montmorillonite[J].Journal of Hazardous Materials,2008,160(1):173-180.