酸的加入方式对球形γ-Al2O3结构及刚果红吸附性能的影响

程宇清, 唐益旺, 王红霞, 辛秀兰*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (10) : 231 -237.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (10) : 231-237. DOI: 10.19817/j.cnki.issn1006-3536.2025.10.036
科学研究

酸的加入方式对球形γ-Al2O3结构及刚果红吸附性能的影响

    程宇清, 唐益旺, 王红霞, 辛秀兰*
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Effect of the mode of acid addition on the structure of spherical γ-Al2O3 and its adsorption properties for Congo red

  • Cheng Yuqing, Tang Yiwang, Wang Hongxia, Xin Xiulan
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摘要

当下水资源污染问题日益严重,淡水中有机染料污染物的去除面临重大挑战。γ-Al2O3作为一种新型孔材料可被广泛应用于吸附、催化、医药及新能源领域,但由于粉末γ-Al2O3材料在实际应用时的回收率较低,因此γ-Al2O3材料的制备及应用成本始终偏高。以异丙醇铝作为有机铝源,在不加入任何助剂的条件下通过溶胶-凝胶法和油-氨柱成型法制备出了纯度高、球形度好、抗压强度大、孔结构可调且具有较高染料去除能力的球形介孔γ-Al2O3材料。同时,探究了酸加入方式对材料孔结构等物化性质的影响。选取刚果红(CR)染料对制备出的球形γ-Al2O3进行吸附性能测试。结果表明:球形γ-Al2O3对CR染料溶液的去除率接近100%,在进行5次循环吸附试验后,对CR的吸附率仍维持在97%以上。这一简便、精细制备球形介孔γ-Al2O3材料的途径具有被广泛应用于废水净化、工业催化、材料生产及医药领域的潜在价值。

Abstract

Nowadays,the problem of water resource pollution is becoming more serious,and the removal of organic dye pollutants in freshwater is facing a major challenge.γ-Al2O3,as a new type of pore material,can be widely used in the fields of adsorption,catalysis,medicine and new energy,but the cost of preparing and application of γ-Al2O3 material remains high due to the low recovery of powder γ-Al2O3 material in practical applications.Spherical mesoporous γ-Al2O3 materials with high purity,good sphericity,high compressive strength,tunable pore structure and high dye-removal ability were prepared by sol-gel and oil-ammonia column forming methods without adding any additives using aluminum isopropoxide as the source of organic aluminum.At the same time,we explored the effect of the acid addition method on the material's pore structure and other physical and chemical properties.We selected Congo red (CR) dye to test the adsorption properties of the prepared spherical γ-Al2O3.According to the test results,the removal of CR dye solution by the prepared material was close to 100%,and the adsorption of CR by the sample was maintained above 97% after five cyclic adsorption tests.This facile and delicate way for the preparation of spherical mesoporous γ-Al2O3 materials has potential value to be widely used in wastewater purification,industrial catalysis,material production and medicine.

关键词

介孔氧化铝 / 溶胶-凝胶法 / 刚果红 / 吸附 / 拟薄水铝石

Key words

mesoporous alumina / sol-gel method / Congo red / adsorption / boehmite

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酸的加入方式对球形γ-Al2O3结构及刚果红吸附性能的影响[J]. 化工新型材料, 2025, 53(10): 231-237 DOI:10.19817/j.cnki.issn1006-3536.2025.10.036

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