MXene作为一种创新的二维材料,具备诸多显著特性,如出色的电子迁移能力、多样的层状结构、较大的比表面积、显著的亲水性、丰富的表面活性位点以及优异的化学稳定性,使其在环境修复方面展现出巨大的应用潜力。简述了MXene及其复合材料的制备工艺,介绍了MXene基复合材料对水中重金属、染料、放射性物质以及抗生素等的处理研究进展,总结了MXene复合材料在水处理应用中的优缺点,指出了其应用的局限性和前景。
As an innovative two-dimensional material,MXene has many remarkable properties,such as excellent electron mobility,diverse layered structures,large specific surface area,significant hydrophilicity,abundant surface active sites,and excellent chemical stability,which makes it show great application potential in environmental remediation.In this paper,the preparation process of MXene and its composites was briefly reviewed,and the research progress of MXene-based composites in the treatment of heavy metals,dyes,radioactive substances and antibiotics in water was introduced.The advantages and disadvantages of MXene composites in the application of water treatment were summarized,and the limitations and prospects of its application were pointed out.
[1] Naguib M,Kurtoglu M,Presser V,et al.Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2[J].Advanced Materials,2011,23(37):4248-4253.
[2] 李凯凯.自组装MXene复合材料的制备及吸附催化性能研究[D].秦皇岛:燕山大学,2018.
[3] 陈平平.高通量二维层状膜通道的可控构建[D].郑州:郑州大学,2018.
[4] Naguib M,Mochalin V N,Barsoum M W,et al.25th anniversary article:MXenes:a new family of two-dimensional materials[J].Advanced Materials,2014,26(7):992-1005.
[5] Ghidiu M,Naguib M,Shi C,et al.Synthesis and characterization of two-dimensional Nb4C3 (MXene)[J].Chemical Communications,2014,50(67):9517-9520.
[6] Natu V,Clites M,Pomerantseva E,et al.Mesoporous MXene powders synthesized by acid induced crumpling and their use as Na-ion battery anodes[J].Materials Research Letters,2018,6(4):230-235.
[7] Chia Xinyi,Pumera Martin.Characteristics and performance of two-dimensional materials for electrocatalysis[J].Nature Catalysis,2018,1(12):909-921.
[8] Huang K,Li Z,Lin J,et al.Two-dimensional transition metal carbides and nitrides (MXenes) for biomedical applications[J].Chemical Society Reviews,2018,47(17):6889.
[9] Ren C E,Hatzell K B,Alhabeb M,et al.Charge- and size-selective ion sieving through Ti3C2Tx MXene membranes[J].Journal Of Physical Chemistry Letters,2015,6(20):4026-4031.
[10] 吴昕昱,张好斌.聚合物基纳米复合材料结构设计与电磁屏蔽性能研究[J].高分子学报,2020,51(6):573-585.
[11] 叶善成,张小珍,姜硕,等.面向水处理应用的二维MXene膜研究进展[J].当代化工研究,2024(1):22-25.
[12] 何艳,王李波,王晓龙,等.二维晶体材料MXenes的合成、性能和应用研究进展[J].人工晶体学报,2019,48(5):787-793,808.
[13] 朱石林.高性能MXene基分离膜的制备及其在印染废水处理中的研究应用[D].西安:西安工业大学,2023.
[14] 郑会奇,陈晋,李延军.二维晶体MXene的制备及催化领域的应用研究进展[J].硅酸盐通报,2018,37(6):1908-1913.
[15] 姚送送,李诺,叶红齐,等.二维MXene材料的制备与电化学储能应用[J].化学进展,2018,30(7):932-946.
[16] 曾广勇,王彬,张俊,等.二维MXene膜的构筑及在水处理应用中的研究进展[J].复合材料学报,2021,38(7):2078-2091.
[17] 刘洁,白圆,马睿,等.MXene吸附法去除水中污染物的研究进展[J].工业水处理,2024,44(6):40-52.
[18] Zhao Q Y,Yang L,Ma Y Z,et al.Highly sensitive,reliable and flexible pressure sensor based on piezoelectric PVDF hybrid film using MXene nanosheet reinforcement[J].Journal of Alloys and Compounds,2021,886:161069.
[19] 薛禹,谭妍妍,徐余欢,等.MXene/PVDF复合膜的制备、性能调控及其应用研究进展[J].精细化工,2024,41(2):292-301.
[20] Pandey R P,Rasool K,Madhavan V E,et al.Ultrahigh-flux and fouling-resistant membranes based on layered silver/MXene (Ti3C2Tx) nanosheets[J].Journal of Materials Chemistry A,2018,6(8):3522-3533.
[21] Kang K M,Kim D W,Ren C E,et al.Selective molecular separation on Ti3C2Tx-graphene oxide membranes during pressure-driven filtration:comparison with graphene oxide and MXenes[J].ACS Applied Materials & Interfaces,2017,9(51):44687-44694.
[22] Ma X Y,Wang A Q,Miao J L,et al.2D lamellar membrane with MXene hetero-intercalated small sized graphene oxide for harsh environmental wastewater treatment[J].Separation and Purification Technology,2023,311.
[23] Chen L H,Yin M,Xiao C H,et al.MXene-based PCC-IS/M@TiO2 ternary integrated heterogeneous conjunctiva for efficient interfacial evaporation and photocatalytic degradation[J].Desalination,2024,575:117312.
[24] Yang X J,Liu Y C,Hu S X,et al.Construction of Fe3O4@MXene composite nanofiltration membrane for heavy metal ions removal from wastewater[J].Polymers for Advanced Technologies,2021,32(3):1000-1010.
[25] Jang J,Kang Y,Jang K,et al.Ti3C2Tx-ethylenediamine nanofiltration membrane for high rejection of heavy metals[J].Chemical Engineering Journal,2022,437:135297.
[26] Zhang T Q,Hao S,Zhao J K,et al.Exfoliated MXene/poly-melamine-formaldehyde composite membranes for removal of heavy metals and organics from aqueous solutions[J].Journal of Hazardous Materials,2024,463:132866.
[27] Huang Z Y,Liu J H,Liu Y H,et al.Enhanced permeability and antifouling performance of polyether sulfone (PES) membrane via elevating magnetic Ni@MXene nanoparticles to upper layer in phase inversion process[J].Journal of Membrane Science,2021,623:119080.
[28] Imsong R,Purkayastha D D.A synergistically enhanced photocatalytic 2D MXene nanofibrous composite membrane for wastewater treatment[J].Applied Surface Science,2024,654:159402.
[29] Zhang T,Zhang L Z.A self-healing PVDF-ZnO/MXene membrane with universal fouling resistance for real seawater desalination[J].Water Research,2022,216:118349.
[30] 孙世操,刘彦洋,王力,等.吸附材料处理染料废水的研究进展[J].山东化工,2018,47(16):73-74,76.
[31] 朱晓泉.Ti3C2Tx MXene基复合物的制备及其性能研究[D].天津:天津大学,2020.
[32] 张诗洋.二维层状复合材料的制备及其在水处理中的应用研究[D].广东:广东工业大学,2020.
[33] Ding L,Wei Y Y,Wang Y J,et al.A two-dimensional lamellar membrane:MXene nanosheet stacks[J].Angewandte Chemie-international Edition,2017,56(7):1825-1829.
[34] Wang Q H,Pan X F,Lin C M,et al.Modified Ti3C2Tx (MXene) nanosheet-catalyzed self-assembled,anti-aggregated,ultra-stretchable,conductive hydrogels for wearable bioelectronics[J].Chemical Engineering Journal,2020,401(1):126129.
[35] Xie T T,Wang Y Y,Zhang Q,et al.Ti3C2Tx MXene-derived hydroxyl-rich titanate based hybrid membrane with cellulose as structural regulator for highly-efficient disposition of heavy metal ions[J].Desalination,2024,572:117115.
[36] Tang R,Jiang L Y,Yan J Y,et al.Fast-thermoresponsive carboxylated cellulose nanofibers/Ti3C2/exfoliated montmorillonite-poly(N-isopropylacrylamide) with switchable wettability for oil-water separation[J].Separation and Purification Technology,2024,339:26580.
[37] Kalaei M R N,Heydarinasab A,Rashidi A,et al.Facile fabrication of Mxene coated metal mesh-based material for oil/water emulsion separation[J].Ecotoxicology and Environmental Safety,2023,255:114824.
[38] Wang J L,Wang X,Shao K J,et al.Spongy porous CuFe prussian blue deposited MXene nanosheets for quick removal of cesium ions from wastewater and seawater[J].Separation and Purification Technology,2023,327:124863.
[39] Yang S A,Shi C,Qu K Q,et al.Electrostatic self-assembly cellulose nanofibers/MXene/nickel chains for highly stable and efficient seawater evaporation and purification[J].Carbon Letters,2023,33(7):2063-2074.
[40] Zhang M,Sun K,Zheng Z H,et al.Development of MXene-decorated sodium alginate/SiO2@n-docosane hierarchical phase-change microcapsules for solar-driven sustainable seawater desalination[J].Desalination,2023,550:116380.
[41] Cao Y,Fang Y,Lei X Y,et al.Fabrication of novel CuFe2O4/MXene hierarchical heterostructures for enhanced photocatalytic degradation of sulfonamides under visible light[J].Journal of Hazardous Materials,2020,387:122021.
[42] Yin J J,Ge B C,Jiao T F,et al.Self-assembled sandwich-like MXene-derived composites as highly efficient and sustainable catalysts for wastewater treatment[J].Langmuir,2021,37(3):1267-1278.
[43] Vigneshwaran S,Jun B M,Prabhu S M,et al.Enhanced sonophotocatalytic degradation of bisphenol A using bimetal sulfide-intercalated MXenes,2D/2D nanocomposite[J].Separation and Purification Technology,2020,250:117178.
[44] 张佳琪.Cu-Fe双金属化合物/MXene异质结的制备及光催化性能研究[D].扬州:扬州大学,2023.
PDF
