难降解有机废水是环境领域中的难题,若处理不当会对人类健康和生态环境造成严重危害,但目前常用的处理方法难以完全去除难降解有机物。薄膜型催化剂可同时实现物理分离和化学催化,且该技术具有废水处理效率高、无二次污染等特点,在环保领域备受关注。基于此,介绍了薄膜型催化剂的反应机理,综述了薄膜型催化剂的制备方法,包括共混法、表面涂层法和自下而上法;举例了薄膜型催化剂在几种难降解废水中的应用。最后,提出了当前薄膜型催化剂存在的问题并对未来的研究方向做出展望,为后续的技术研究提供启发与参考,以期制备出更加高效、廉价的薄膜型催化剂,提高难降解废水处理效果、减少环境污染。
The treatment of refractory organic wastewater is a difficult problem in the environmental field,and improper treatment of refractory organic wastewater can seriously affect the ecological environment and human health.However,the currently commonly treatment methods are unable to completely remove refractory organic matter.Thin-film catalysts can simultaneously achieve physical separation and chemical catalysis.Due to its high efficiency and no secondary pollution,this technology has attracted much attention in the field of environmental protection.This paper introduced the reaction mechanisms of thin-film catalyst.Then,the preparation methods of thin-film catalysts,including blending method,surface coating method and bottom-up method,were reviewed.The applications of thin-film catalysts in several refractory organic wastewater were summarized.Finally,this paper put forward the existing problems of thin-film catalyst,made an outlook on the future research direction,and provided inspiration and reference for subsequent technical research,with a view to prepare more efficient and inexpensive thin-film catalysts,improve the treatment effect of refractory wastewater and reduce environmental pollution.
[1] 孙小雯,高鑫,张伟.染料废水处理技术的现状和分析[J].辽宁化工,2023,52(10):1510-1513.
[2] 许从峰,郭芳杏,胡春,等.制浆造纸废水处理技术研究进展及思考[J].中国造纸,2024(4):177-188.
[3] 李彬,张晨阳,陶伟伟.制药废水处理技术研究进展[J].工业水处理,2022,42(11):7-17.
[4] 李海华,李青,宋伟,等.农药废水的综合治理研究[J].山东化工,2024,53(5):263-266.
[5] 王磊.石油化工废水处理技术的研究与实践[J].当代化工研究,2024(3):89-91.
[6] 王琼杰,张勇,汪金晓雪,等.吸附法深度处理焦化废水研究进展[J].水处理技术,2020,46(1):7-11.
[7] 周张花.城市生活污水深度处理中膜法水处理技术的应用[J].城市建设理论研究(电子版),2024(19):98-100.
[8] 邹小玲,余江涛,张本凯.厌氧生物法处理高盐废水研究进展[J].现代化工,2020,40(3):44-47.
[9] 沈万峰.有机废水的好氧生物处理技术进展研究[J].城市道桥与防洪,2017(9):105-106,130.
[10] 冯雪梅,卫新来,陈俊,等.高级氧化技术在废水处理中的应用进展[J].应用化工,2020,49(4):993-996,1001.
[11] 郎明娇,杨朝美,曾广勇.光催化膜的构筑及其在废水处理中的研究进展[J].工业水处理,2024,44(7):47-56.
[12] 王建宇,陈榕汶,方传杰,等.电催化膜技术工艺处理含酚废水的研究进展[J].膜科学与技术,2024,44(4):190-201.
[13] 于子函,纪玉祺,闫良国,等.催化膜活化过硫酸盐降解水中有机污染物研究进展[J].济南大学学报(自然科学版),2024,38(4):422-428.
[14] 赵晓勇,曾一鸣,施艳荞,等.相转化法制备超滤和微滤膜的孔结构控制[J].功能高分子学报,2002,15(4):487-495.
[15] Huang Z H,Zhang X,Wang Y X,et al.Fe3O4/PVDF catalytic membrane treatment organic wastewater with simultaneously improved permeability,catalytic property and anti-fouling[J].Environmental Research,2020,187:109617.
[16] 井希明,盛永刚.溶胶-凝胶法制备SiO2减反膜研究[J].日用化学工业(中英文),2023,53(2):210-219.
[17] Chakraborty S,Loutatidou S,Palmisano G,et al.Photocatalytic hollow fiber membranes for the degradation of pharmaceutical compounds in wastewater[J].Journal of Environmental Chemical Engineering,2017,5(5):5014-5024.
[18] 梁幸幸,杨颖,许德平.静电纺丝法制备空气过滤膜及应用[J].化学工业与工程,2015,32(3):59-67.
[19] Song J,Wang X Q,Yan J H,et al.Soft Zr-doped TiO2 Nanofibrous membranes with enhanced photocatalytic activity for water purification[J].Scientific Reports,2017,7(1):1-12.
[20] Lin H B,Fang Q L,Wang W,et al.Prussian blue/PVDF catalytic membrane with exceptional and stable Fenton oxidation performance for organic pollutants removal[J].Applied Catalysis b-Environmental,2020,273:119047.
[21] 余海丽,张卜生,谷龙艳,等.旋涂法制备掺杂BiOX薄膜及光催化性能研究[J].人工晶体学报,2018,47(11):2270-2276,2287.
[22] Gai S,Fan R Q,Xing K,et al.Preparation of composite filters based on porous coordination polymers by using a vacuum filtration method for highly efficient removal of particulate matters[J].Chemistry-An Asian Journal,2019,14(13):2291-2301.
[23] 王振宇,刘燕才,陈琨,等.等离子喷涂-化学气相沉积制备α/β-Bi2O3薄膜的相结构调控和光催化降解性能[J].硅酸盐学报,2023,51(7):1800-1810.
[24] Meng Y X,Jiang W,Qing Y W.Nanofiltration membranes via layer-by-layer assembly and cross-linking of polyethyleneimine/sodium lignosulfonate for heavy metal removal[J].Chinese Journal of Polymer Science,2020,38(9):965-972.
[25] Yang H S,Liu Y,Xu B Y,et al.Rational design of a super anti-fouling PVDF-PC-TBT@X membrane for emulsion/dye wastewater separation[J].Journal of Environmental Chemical Engineering,2023,11(6):111256.
[26] Hou X Y,Wang J Z,Zhang R X,et al.Preparation of PVDF-nSiO2/PVSQ high-flux composite membrane by chemical grafting and separation of composite brine by membrane distillation[J].Journal of Environmental Chemical Engineering,2024,12(5):113257.
[27] Morillo M D,Faccini M,Garcia M A,et al.Highly efficient removal of heavy metal ions from polluted water using ion selective polyacrylonitrile nanofibers[J].Journal of Environmental Chemical Engineering,2018,6(1):236-245.
[28] Sadek O,Touhtouh S,Dahbi A,et al.Photocatalytic degradation of methylene blue on multilayer TiO2 coatings elaborated by the sol-gel spin-coating method[J].Water Air And Soil Pollution,2023,234(11):1-11.
[29] 钱怡帆,周堂,张礼颖,等.聚丙烯腈/醋酸纤维素/TiO2复合纳米纤维膜的制备及其光催化降解性能[J].纺织学报,2020,41(5):8-14.
[30] Topaloglu A K,Kahraman B F.Textile dye removal in wastewater by peroxymonosulfate (PMS) activation on a zero-valent iron nanoparticle-modified ultrafiltration catalytic membrane (nZVI@PES)[J].Environmental Science And Pollution Research,2023,30(41):94779-94789.
[31] Wang T,Wang Z Y,Wang P L,et al.An integration of photo-Fenton and membrane process for water treatment by a PVDF@CuFe2O4 catalytic membrane[J].Journal of Membrane Science,2019,572:419-427.
[32] Nieto S J,Torres P A,Pedrosa M,et al.Application of g-C3N4-PVDF membrane for the photocatalytic degradation of micropollutants in continuous flow mode:impact of water matrix[J].Journal of Environmental Chemical Engineering,2023,11(5):110586.
[33] Zhu D Y,Xue S K,Yang S F,et al.Layered bimetallic oxide composite film:a highly efficient and reusable photocatalytic film for removal of tetracycline antibiotics[J].Chemical Engineering Journal,2023,476:146681.
[34] Wu S,Cui Y L,Liang L,et al.Mn-Cu bimetallic electro-spun catalytic membrane coupled Fenton-like scheme for sulfamethoxazole destruction under ambient pH[J].Separation and Purification Technology,2024,337:126432.
[35] Leichtweis J,Carissimi E,Hagemann U,et al.NiFe2O4/biochar decorated porous polymer membranes for the flow-through photo-Fenton degradation of tetracycline[J].Chemical Engineering Journal,2023,477:147203.
[36] Ma T G,Ren H J,Liu M J,et al.Nanoconfined catalytic membrane assembled by nitrogen-doped carbon encapsulating Fe-based nanoparticles for rapid removal of 2,4-dichloro-phenol in wastewater by peroxymonosulfate activation[J].Journal of Hazardous Materials,2024,466:133523.
[37] 张新奇,朱孟府,邓橙,等.PTFE/Bi-SnO2-CNT电催化膜的结构及性能表征[J].膜科学与技术,2019,39(1):34-40.
[38] Liu Y T,Lin Q,Guo Y Q,et al.The nitrogen-doped multi-walled carbon nanotubes modified membrane activated peroxymonosulfate for enhanced degradation of organics and membrane fouling mitigation in natural waters treatment[J].Water Research,2022,209:117960.
[39] Zhang S,Hedtk E T,Zhu Q H,et al.Membrane-confined iron oxychloride nanocatalysts for highly efficient heterogeneous Fenton water treatment[J].Environmental Science & Technology,2021,55(13):9266-9275.