金属有机骨架(MOFs)具有独特的多孔结构、大的比表面积和丰富的活性位点,在光催化产氢研究中常作为高效助催化剂的载体和分散平台,也成为设计新颖结构的模板牺牲剂。近年来,出现了一些具有窄带隙的MOFs,其自身就可以实现高效产氢,显示出在光催化产氢中的巨大应用潜力。综述了近十年MOFs基材料在光催化产氢方面的研究进展,在总结前人工作的基础上进一步展现了MOFs基材料在光催化产氢应用的潜力,并为未来的研究方向提出建议。
Due to its unique porous structure,large specific surface area and rich active sites,the metal-organic frameworks (MOFs) are often used as carriers and dispersion platforms for efficient co-catalysts in the studies of photocatalytic hydrogen production.They have also become template sacrificial agents for designing novel structures.In recent years,some MOFs with narrow band gaps have emerged,which can achieve efficient hydrogen production by themselves,showing the great potential of MOFs in photocatalytic hydrogen production.The research progress of MOFs-based materials in photocatalytic hydrogen production in the past decade was reviewed.On the basis of summarizing the previous works,the potential of MOFs-based materials in photocatalytic hydrogen production was further demonstrated,and suggestions for future research directions were put forward.
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基金资助
国家自然科学基金(51772099,51572069)
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