过渡金属碳化钼被认为是可替代贵金属的潜在催化材料之一,其性能主要依赖于制备策略,尤其是钼前驱体的设计和合成直接影响纳米碳化钼的粒径、分散性及纳米碳载体的结构和形貌。综述了近年来制备纳米碳化钼前驱体的设计策略及主要优缺点,介绍了纳米碳化钼在电催化、储能、传感和吸波领域的应用进展。
Transition metal molybdenum carbide is considered to be one of the potential catalytic materials that can replace precious metals.Its performance mainly depends on the preparation strategy,especially the design and synthesis of molybdenum precursors affect directly the size and dispersion of nanometer molybdenum carbide,and the structure and morphology of nanocarbon carrier.In this paper,the design strategies and main advantages and disadvantages of the precursor preparations of molybdenum carbide in recent years were reviewed.The application progress of nano molybdenum carbide in the fields of electrocatalysis,energy storage,sensing and wave-absorption was introduced.
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基金资助
国家自然科学基金(51572185;22378286);山西省基础研究计划项目(20210302123173);山西省重点研发计划国际合作项目(201903D421079);中央引导地方科技发展资金(YDZJSX2021A014)