锂离子电池在消费电子、储能和新能源汽车等领域得到广泛应用,但仍存在一些问题,导致其使用寿命和续航里程不能满足日益增长的需求,如何提升电池的循环性能非常重要,研究自修复材料在锂离子电池中的应用是近年来的热点方向。主要介绍了本征型和外援型两种自修复材料的结构和作用机理,综述了其在锂离子电池中的应用进展,总结了该领域近几年的研究成果及存在的问题,并展望了未来研究发展方向。
Lithium-ion batteries are widely used in the fields of consumer electronics,energy storage and new energy vehicles,but there are still some problems,resulting in their service life and cruising range cannot meet the growing demand.How to improve the cycle performance of the battery is very important.The application of self-healing materials in lithium-ion batteries is a hot topic in recent years.In this paper,the structures and mechanisms of two kinds of self-healing materials,i.e.intrinsic type and extrinsic type,were mainly introduced.The application progress of self-healing materials in lithium-ion batteries was reviewed.The research achievements and existing challenges in this field in recent years were summarized,and the future research and development direction was prospected.
[1] Cheng Y,Wang C,Kang F,et al.Self-healable lithium-ion batteries:a review[J].Nanomaterials,2022,12(20):3656.
[2] Chen D,Wang D,Yang Y,et al.Self-healing materials for next-generation energy harvesting and storage devices[J].Advanced Energy Materials,2017,7(23):1700890.
[3] 王敏慧.功能性自修复材料的制备及其性能研究[D].广州:华南理工大学,2022.
[4] Li C,Bhandary R,Marinow A,et al.Synthesis and characterization of quadrupolar-hydrogen-bonded polymeric ionic liquids for potential self-healing electrolytes[J].Polymers,2022,14(19):4090.
[5] Li J,Yang L,Zhang H,et al.Self-healing composite solid electrolytes with enhanced Li+ transport and mechanical properties for safe lithium metal batteries[J].Chemical Engineering Journal,2022,438:135418.
[6] Cui X,Chu Y,Wang X,et al.Stabilizing lithium metal anodes by a self-healable and Li-regulating interlayer[J].ACS Applied Materials & Interfaces,2021,13(37):44983-44990.
[7] Deng K,Zhou S,Xu Z,et al.A high ion-conducting,self-healing and nonflammable polymer electrolyte with dynamic imine bonds for dendrite-free lithium metal batteries[J].Chemical Engineering Journal,2022,428:131224.
[8] 谢坤池,施连旭,刘军.锂离子电池自修复聚合物电解质的研究进展[J].分子科学学报,2022,38(3):203-215.
[9] Qin Y,Wang H,Zhou J,et al.Binding FSI- to construct a self-healing SEI film for Li-metal batteries by in situ crosslinking vinyl ionic liquid[J].Angewandte Chemie International Edition,2024,63(19):e202402456.
[10] Wu Y,Han T,Huang X,et al.A Ga-Sn liquid alloy-encapsulated self-healing microcapsule as high-performance Li-ion battery anode[J].Journal of Electroanalytical Chemistry,2022,922:116789.
[11] Jiang M,Mu P,Zhang H,et al.An endotenon sheath-inspired double-network binder enables superior cycling performance of silicon electrodes[J].Nano-Micro Letters,2022,14(1):87.
[12] Peng X,Chen X,Tang C,et al.Self-healing binder for high-voltage batteries[J].ACS Applied Materials & Interfaces,2023,15(17):21517-21525.
[13] Gupta A,Badam R,Matsumi N.Heavy-duty performance from silicon anodes using poly(BIAN)/poly(acrylic acid)-based self-Healing composite binder in lithium-ion secondary batteries[J].ACS Applied Energy Materials,2022,5(7):7977-7987.
[14] Ma W,Wan S,Cui X,et al.Exploration and application of self-healing strategies in lithium batteries[J].Advanced Functional Materials,2023,33(15):2212821.
[15] 朱传晖,郭磊,胡涛,等.液态合金/二硫化钼自修复负极材料的制备及其电化学性能[J].硅酸盐学报,2024,52(6):2024-2031.
[16] Qi Y,Shen C,Hou Q,et al.A self-healing liquid metal anode for lithium-ion batteries[J].Journal of Energy Chemistry,2022,72:522-531.
[17] Guo C,Cao Y,Li J,et al.Solvent-free green synthesis of nonflammable and self-healing polymer film electrolytes for lithium metal batteries[J].Applied Energy,2022,323:119571.
[18] Gu W,Li F,Liu T,et al.Recyclable,self-healing solid polymer electrolytes by soy protein-based dynamic network[J].Advanced Science,2022,9(11):2103623.
[19] 陈心怡,李瑀,封伟.基于两性离子的自修复准固态聚合物电解质[J].高分子学报,2022,53(11):1349-1357.
[20] Ren Y,Cui Z,Bhargav A,et al.A self-healable sulfide/polymer composite electrolyte for long-life,low-lithium-excess lithium-metal batteries[J].Advanced Functional Materials,2022,32(2):2106680.
[21] Zhou S,Deng K,Xu Z,et al.Highly conductive self-healing polymer electrolytes based on synergetic dynamic bonds for highly safe lithium metal batteries[J].Chemical Engineering Journal,2022,442:136083.
[22] Davino S,Callegari D,Pasini D,et al.Cross-linked gel electrolytes with self-healing functionalities for smart lithium batteries[J].ACS Applied Materials & Interfaces,2022,14(46):51941-51953.
[23] Chen X,Yi L,Zou C,et al.Boosting the performances of lithium metal batteries through in-situ construction of dual-network self-healing gel polymer electrolytes[J].Electrochimica Acta,2023,446:142084.
[24] Wan L,Cao X,Xue X,et al.Self-healing and flexible ionic gel polymer electrolyte based on reversible bond for high-performance lithium metal batteries[J].Energy Technology,2022,10(2):2100749.
[25] 丁赵波,罗英,刘雯,等.自修复材料在储能器件中的研究现状[J].电池,2021,51(6):619-623.
[26] Wei Y,Cheng J,Li D,et al.A structure self-healing Li-rich cathode achieved by lithium supplement of Li-rich LLZO coating[J].Advanced Functional Materials,2023,33(22):2214775.
基金资助
珠海市产学研合作项目(2220004002572)