金属-生物质框架(Bio-MOFs)既保有传统MOFs的可调节孔径和结构、高比表面和高密度的活性位点,又因为生物质分子取代传统有机配体具有环保、低成本的特点,并且在一定程度上能提升本征活性,在电催化方面引起关注。综述了当前Bio-MOFs的常用生物质配体,对其在电催化领域的应用进展进行了介绍,并提出存在的问题及未来领域的发展方向。
The metal-biomass frameworks (Bio-MOFs) not only retain the adjustable pore size and structure,high specific surface and high density of active sites of traditional MOFs,but also have the characteristics of environmental friendliness and low cost due to biomass molecules replacing traditional organic ligands,and can improve the intrinsic activity to a certain extent,attracting growing attention in the field of electrocatalysis.In this paper,the commonly used biomass ligands for current Bio-MOFs were summarized,and the application progress of Bio-MOFs in electrocatalysis was reviewed.The existing problems were analyzed,and the future development directions of Bio-MOFs were put forward.
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基金资助
湖南省自然科学基金项目(2023JJ31009);国家重点研发计划项目(2019YFB1503804)
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