建筑领域是能源消耗和二氧化碳排放大户,研究建筑被动节能技术是有效解决方式之一。其中矿物基相变材料因其良好的热性能、储能效果和成本优势被广泛研究。介绍了相变材料的分类、热性能、选择、封装及矿物特点,阐述了多种矿物基相变材料在围护结构中的应用进展。应用表明,使用矿物作为载体提高了相变材料热稳定性、导热性,有效解决了相变材料泄露问题。将矿物基相变材料应用于围护结构可以维持室温相对稳定,减少供暖空调负荷,降低能源消耗。
There is large energy consumption and carbon dioxide emission in building field,and research on building passive energy conservation technology is one of the effective solutions.Among them,mineral-based phase change materials (PCMs) have been widely studied because of their good thermal properties,energy storage effect and cost advantages.The classification,thermal performance,selection,encapsulation and mineral characteristics of phase change materials were introduced.The application progress of many kinds of mineral-based phase change materials in building enclosures was described.The application analysis showed that the use of mineral as carrier could improve the thermal stability and thermal conductivity of PCMs,and effectively solve the problem of leakage of PCMs.The application of mineral-based PCMs to building enclosure could stabilize room temperature relatively,reduce heating and air conditioning load,and lower energy consumption.
[1] 张源,魏燕丽,许锦峰.相变材料物性与轻质相变围护结构节能研究进展[J].江苏大学学报(自然科学版),2021,42(3):354-360.
[2] 肖力光,李赫.相变储能材料在建筑围护结构领域的应用及研究进展[J].化工新型材料,2024,52(4):228-232.
[3] 蒋聪,蒋达华,陈璞,等.相变材料在围护结构中的应用及热工性能研究进展[J].化工新型材料,2024,52(2):282-287,293.
[4] Guo Z J,Qiao J X,Liu X J,et al.Advances in mineral-based composite phase change materials for energy storage:a review[J].Green and Smart Mining Engineering,2024,1(4):447-473.
[5] 陈璞,蒋达华,徐玉珍,等.相变材料选用及储能墙体节能研究进展[J].化工新型材料,2023,51(2):207-212.
[6] 陶文博,谢如鹤.有机相变蓄冷材料的研究进展[J].制冷学报,2016,37(1):52-59.
[7] 李昭,李宝让,陈豪志,等.相变储热技术研究进展[J].化工进展,2020,39(12):5066-5085.
[8] 王成君,苏琼,段志英,等.基于多孔支撑体的形状稳定复合相变储能材料的研究进展[J].化工进展,2021,40(3):1483-1494.
[9] 李兴会,陈敏智,周晓燕.复合定形相变材料的封装及应用研究新进展[J].工程科学学报,2020,42(11):1422-1432.
[10] 成鑫磊,穆锐,孙涛,等.固液相变材料的封装制备及在建筑领域的研究进展[J].材料导报,2024,38(5):73-87.
[11] 伏舜宇,沈仲华,杨英英,等.相变材料应用于建筑围护结构中定型封装方法研究进展[J].化工新型材料,2021,49(11):222-228.
[12] 吴晅,户澳文,徐芳强,等.相变储热材料应用于建筑围护结构的研究现状和发展趋势[J].化工新型材料,2023,51(3):25-30.
[13] 崔艳琦.相变材料热性能及其在室内被动式储能系统的简易计算[J].储能科学与技术,2017,6(2):302-306.
[14] 陈贡.提高相变材料热导率的研究进展[J].化工新型材料,2024,52(S2):11-15.
[15] 朱思倩,赵春腾,张倩茹.围护结构传热系数检测方法的实验研究[J].中国测试,2023,49(S1):252-256.
[16] Katish M,Allen S,Squires A,et al.Thermal stability of organic phase change materials (PCMs) by accelerated thermal cycling technique[J].Thermochimica Acta,2024,737:179771.
[17] 李传常,罗杰,江杰云,等.基于矿物特性的太阳能储热材料研究进展[J].中国材料进展,2012,31(9):51-56.
[18] 叶志林,魏婷,易红玲,等.癸酸-棕榈酸/膨胀珍珠岩定型相变材料的制备与热性能[J].华东理工大学学报(自然科学版),2017,43(4):495-500.
[19] 廖立兵.矿物材料的定义与分类[J].硅酸盐通报,2010,29(5):1067-1071.
[20] 彭同江.我国矿物材料的研究现状与发展趋势[J].中国矿业,2005(1):21-24.
[21] 李琳,王宇,李东旭,等.硅藻土基定形相变材料的制备及应用进展[J].化工新型材料,2024,52(4):238-243.
[22] Zhang P,Cui Y,Zhang K,et al.Enhanced thermal storage capacity of paraffin/diatomite composite using oleophobic modification[J].Journal of Cleaner Production,2021,279:123211.
[23] Li C,Wang M,Xie B,et al.Carbon-decorated diatomite stabilized lauric acid-stearic acid as composite phase change materials for photo-to-thermal conversion and storage[J].Renewable Energy,2024,229:120731.
[24] Fu W,Lao J,Chen L,et al.Design of Na2HPO4·12H2O/diatomite composite phase change materials with low supercooling degree,excellent thermal properties and corrosion resistance for building energy conservation[J].Journal of Energy Storage,2024,84:110922.
[25] 刘景滔,蒋达华,杨昊天,等.海泡石基复合相变调温调湿材料研究进展[J].化工新型材料,2021,49(5):11-15.
[26] 钟益.十二水合磷酸氢二钠/海泡石复合相变材料的制备及蓄热性能研究[D].广州:华南理工大学,2021.
[27] Topçu İlker Bekir,Bayram Muhammed,Ustao ğlu Abid,et al.Innovative cementitious mortar incorporated with sepiolite based shape-stable phase change material for thermal controlling of buildings[J].Construction and Building Materials,2024,426:136124.
[28] Jiang Jinyang,Ju Siyi,Wang Fengjuan,et al.Cement-based materials incorporated with polyethylene glycol/sepiolite composite phase change materials:hydration,mechanical,and thermal properties[J].Journal of Sustainable Cement-Based Materials,2024,13(2):311-323.
[29] 刘猛,封金鹏,符林总,等.蛭石功能化应用研究新进展[J].矿产综合利用,2021(1):14-22.
[30] 李向辉,刘松阳,白瑞雪,等.建筑节能用癸酸-月桂酸/膨胀蛭石复合相变储热材料的制备及性能[J].辽宁石油化工大学学报,2023,43(3):34-40.
[31] 刘凤利,胡国峰,刘俊华,等.癸酸-硬脂酸/有机膨胀蛭石相变蓄热砂浆的制备与性能研究[J].功能材料,2020,51(5):5007-5012.
[32] Wang Mengqing,Liu Songyang,Gao Wei,et al.Synthesis and characterization of Capric acid-Lauric acid/expanded vermiculite as a phase change composite for thermal energy storage[J].Journal of Energy Storage,2024,78:110091.
[33] 格桑尼玛,刘鹏,王雅静,等.膨胀珍珠岩基复合相变材料研究进展[J].化工新型材料,2023,51(12):15-19,26.
[34] 杨华,陈万河,孔祥飞,等.建筑中应用基于十四醇-十四酸二元共融混合物/膨胀珍珠岩和膨胀蛭石复合相变板材的制备、性能表征及热性能[J].中南大学学报(英文版),2019,26(9):2578-2595.
[35] Li Runjie,Zhao Yajing,Xia Boyang,et al.Enhanced thermal conductivity of composite phase change materials based on carbon modified expanded perlite[J].Materials Chemistry and Physics,2021,261:124226.
[36] Alkhazaleh Awni H,Almanaseer Waref,Alkhazali Atif.Experimental investigation on thermal properties and fire performance of lauric acid/diphenyl phosphate/expanded perlite as a flame retardant phase change material for latent heat storage applications[J].Sustainable Energy Technologies and Assessments,2023,56:103059.
[37] Chen Z,Qin M,Yang J.Synthesis and characteristics of hygroscopic phase change material:composite microencapsulated phase change material (MPCM) and diatomite[J].Energy & Buildings,2015,106:175-182.
[38] 贾亚可.有机/海泡石纤维相变蓄热材料的研究[D].天津:河北工业大学,2011.
[39] Xie N,Niu J,Zhong Y,et al.Development of polyurethane acrylate coated salt hydrate/diatomite form-stable phase change material with enhanced thermal stability for building energy storage[J].Construction and Building Materials,2020,259:119714.
[40] 刘洁,杨英英,李爱征,等.用于地板辐射采暖的多元水合盐复合相变砂浆的制备及性能研究[J].储能科学与技术,2023,12(12):3655-3662.
[41] Zhang Henghua,Dong Qianbin,Lu Juetian,et al.Modified sodium acetate trihydrate/expanded perlite composite phase change material encapsulated by epoxy resin for radiant floor heating[J].Journal of Energy Storage,2023,65:107374.
[42] Xie Ning,Gao Xuenong,Zhong Yi,et al.Enhanced thermal performance of Na2HPO4·12H2O composite phase change material supported by sepiolite fiber for floor radiant heating system[J].Journal of Building Engineering,2022,56:104747.
[43] 陈万河.复合相变通风屋顶的热特性及参数优化研究[D].天津:河北工业大学,2018.
[44] 谢尚群,孔祥飞,何金棋,等.复合相变蓄能屋顶的制备及性能研究[J].墙材革新与建筑节能,2017(7):47-52.
[45] Fu L,Wang Q,Ye R,et al.A calcium chloride hexahydrate/expanded perlite composite with good heat storage and insulation properties for building energy conservation[J].Renewable Energy,2017,114:733-743.
基金资助
江西省自然科学基金项目(20192BAB206040);江西省教育厅科学技术研究项目(GJJ180459)