面向二氧化碳电化学还原的阴离子交换膜研究进展

李沛1, 周诗宇1, 汪洋1, 胡婧婷1, 张春波1, 李雪峰2*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (8) : 6 -9.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (8) : 6-9. DOI: 10.19817/j.cnki.issn1006-3536.2025.08.044
综述与专论

面向二氧化碳电化学还原的阴离子交换膜研究进展

    李沛1, 周诗宇1, 汪洋1, 胡婧婷1, 张春波1, 李雪峰2*
作者信息 +

Research progress on anion exchange membranes for electrochemical CO2 reduction

  • Li Pei1, Zhou Shiyu1, Wang Yang1, Hu Jingting1, Zhang Chunbo1, Li Xuefeng2
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摘要

CO2电化学还原技术(ECO2RR)是一项在常温常压、绿色条件下将CO2直接转化、增值的重要技术。而阴离子交换膜作为CO2电化学还原器件中的核心部件,其性能决定着整个膜电极的能量转换效率。理想的阴离子交换膜(AEM)应拥有高的离子传导率、机械性能与化学稳定性,并且能够有效地阻止产物和反应物的交叉渗透,减少ECO2RR系统的能量损失。但阴离子交换膜在ECO2RR中的应用还存在着诸多的障碍需要克服。总结了面向ECO2RR应用的阴离子交换膜的设计、制备与性能,讨论了阴离子交换膜的各项性能对ECO2RR性能的影响,并展望未来面向ECO2RR应用的阴离子交换膜的研究方向。

Abstract

Electrochemical CO2 reduction technology (ECO2RR) is a crucial method for directly converting and increasing the value of carbon dioxide at ambient temperature and pressure in an eco-friendly way.Anion exchange membrane (AEM),as a key component in ECO2RR device,plays a vital role in determining its overall energy conversion efficiency.The ideal AEM should exhibit high ion conductivity,mechanical properties and chemical stability.It is also required to effectively prevent the crossover permeation of products and reactants,thereby reducing energy losses in ECO2RR system.However,the utilization of AEMs in ECO2RR devices still encounters various challenges that must be addressed.In this context,the design,preparation and properties of AEMs utilized in ECO2RR were outlined.Furthermore,the influence of properties of these AEMs on the ECO2RR performance was discussed,and the future research directions of AEM for ECO2RR applications were envisioned.

关键词

二氧化碳 / 电化学还原 / 阴离子交换膜 / 离子传导率 / 化学稳定性

Key words

carbon dioxide / electrochemical reduction / anion exchange membrane / ionic conductivity / chemical stability

引用本文

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面向二氧化碳电化学还原的阴离子交换膜研究进展[J]. 化工新型材料, 2025, 53(8): 6-9 DOI:10.19817/j.cnki.issn1006-3536.2025.08.044

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基金资助

国家电网吉林省电力有限公司科技项目(合同号:2023-39)

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