紫磷是最近几年发展起来的一种具有层状结构的新型单质磷,在催化、生物医药、传感等领域具有很好的应用前景。结合国内外相关文献,综述了目前开发的紫磷制备方法,包括等离子体辅助法、铋融化法、铅融化法、化学气相传输法和催化法。分析讨论了各种制备方法的优缺点,提出催化法具有工业化发展前景。但催化法制备紫磷的机制尚不完全明确,深入研究催化法制备紫磷的机理,简化其工艺流程,扩大制备规模,实现紫磷的低成本规模化制备是紫磷制备的发展趋势。
Violet phosphorus is a new type of elemental phosphorus with a layered structure developed in recent years,which has good application prospects in catalysis,biomedicine,sensing and other fields.Combined with the relevant literature at home and abroad,the currently developed violet phosphorus preparation methods were summarized,including plasma-assisted method,bismuth melting method,lead melting method,chemical gas phase transport method and catalytic method.The advantages and disadvantages of the various preparation methods were analyzed and discussed,and the catalytic method had the prospect of industrialization.However,the mechanism of violet phosphorus preparation by catalysis was not completely clear.The development trend of violet phosphorus preparation should deeply study the mechanism of preparation of violet phosphorus by catalysis,simplify its process,expand the preparation scale,and realize the low-cost large-scale preparation of violet phosphorus.
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基金资助
国家自然科学基金(22168021)
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