铁基化合物负极(阳极)材料是一种新兴的锂离子电池负极材料,具有比容量大,电导率高,环境污染小,制备成本低等特点。介绍了以铁硫和铁氧两种铁基化合物为主的负极材料的制备方法和结构设计,归纳了铁基化合物作为锂离子电池负极材料的应用,并分析了铁基化合物作为锂离子电池负极材料存在的问题,指出了如何通过合理的结构设计获得电化学性能优异的铁基化合物负极材料。
Iron-based compound anode material is an emerging anode material for lithium-ion batteries,featuring large specific capacity,high conductivity,low environmental pollution and low preparation cost.The preparation method and structural design of anode materials mainly composed of iron-based compounds,iron sulfur and iron oxide,were introduced.The application of iron-based compounds as anode materials for lithium-ion batteries was summarized,and the existing problems of iron-based compounds as anode materials for lithium-ion batteries were analyzed.How to obtain iron-based compound anode materials with excellent electrochemical properties through reasonable structural design was pointed out.
[1] 孙赛,邓洁,王晓晨.负极材料:突破锂离子电池能量密度天花板的关键[J].中国石化,2023(11):41-45.
[2] 陈红,沙宇晴.锂离子电池负极材料的研究现状[J].化工设计通讯,2023,49(4):148-150.
[3] Wu H B,Chen J S,Hng H H,et al.Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries[J].Nanoscale,2012,4(8):2526-2542.
[4] Aravindan V,Lee Y S,Madhavi S.Research progress on negative electrodes for practical Li-ion batteries:beyond carbonaceous anodes[J].Advanced Energy Materials,2015,5(13):1402225.
[5] Ma F,Guan S,Wang Y J,et al.Lithium gallium oxide (LiGaO2):high-performance anode material for lithium-ion batteries[J].Journal of Alloys and Compounds,2024,976:173197.
[6] Chaudhari S,Srinivasan M.1D hollow α-Fe2O3 electrospun nanofibers as high performance anode material for lithium ion batteries[J].Journal of Materials Chemistry,2012,22(43):23049-23056.
[7] Chen Y,Liu F,Zhao Y,et al.Lychee-like TiO2@Fe2O3 core-shell nanostructures with improved lithium storage properties as anode materials for lithium-ion batteries[J].Materials,2023,16(5):1945.
[8] Hang B T,Van Dang T,Van Quy N.Fe2O3/C nanomaterials synthesized by microwave for energy storage applications[J].Advances in Natural Sciences:Nanoscience and Nanotechnology,2023,14(4):045016.
[9] Liu G,Cai B,Hu Z,et al.Fe2O3@FeSe2 heterostructure as high-performance supercapacitor negative electrode material[J].Journal of Energy Storage,2024,88:111544.
[10] Xu Q T,Xue H G,Guo S P.FeS2 walnut-like microspheres wrapped with rGO as anode material for high-capacity and long-cycle lithium-ion batteries[J].Electrochimica Acta,2018,292:1-9.
[11] Huang T,Xue X,Zhang Y,et al.A review of metal sulfide cathode materials for non-aqueous multivalent ion (Mg2+,Ca2+,Al3+) batteries[J].Journal of Energy Storage,2024,79:110172.
[12] Xu Q T,Li J C,Xue H G,et al.Binary iron sulfides as anode materials for rechargeable batteries:crystal structures,syntheses,and electrochemical performance[J].Journal of Power Sources,2018,379:41-52.
[13] Li W,Huang C.Transition metal oxides and transition metal sulfides as cathodes for magnesium-ion batteries:current status and modification strategies[J].Materials Today Energy,2024,40:101510.
[14] Wang L,Ding K,Wei B,et al.Leaf-like α-Fe2O3 micron-particle:preparation and its usage as anode materials for lithium ion batteries[J].Materials Chemistry and Physics,2018,207:58-66.
[15] Wang G,Liu T,Luo Y,et al.Preparation of Fe2O3/graphene composite and its electrochemical performance as an anode material for lithium ion batteries[J].Journal of Alloys and Compounds,2011,509(24):L216-L220.
[16] Sadaqat Afifa,Ali Ghulam,ul Hasan Mahmood,et al.Laminar-protuberant like p-FeS2 rooted in mesoporous carbon sheets as high capacity anode for Na-ion batteries[J].Electrochimica Acta,2023,439:141650.
[17] Hu Zhongliang,Cui Houquan,ZhuYirong,et al.Holey reduced graphene oxide nanosheets wrapped hollow FeS2@C spheres as a high-performance anode material for sodium-ion batteries[J].Journal of Power Sources,2022,536:231438.
[18] Warjri M,Narayan J.Synthesis of α-Fe2O3 nano-rod/sheet:volumetric and electrical conductivity properties of their nanofluids[J].Journal of Molecular Liquids,2023,377:121539.
[19] Liang H,Wang X,Shi J,et al.Design of heterostructured hydrangea-like FeS2/MoS2 encapsulated in nitrogen-doped carbon as high-performance anode for potassium-ion capacitors[J].Journal of Colloid and Interface Science,2024,664:96-106.
[20] He C,Li X,Zheng J,et al.A variety of carbon-coated FeS2 anodes:FeS2@CNT with excellent lithium-ion storage performance[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,637:128226.
[21] Wang Y,Liu M,Liu H,et al.Synthesis of FeS/Fe2O3 hollow fibers derived from Fe-alginate fibers as anodes for high performance sodium-ion batteries[J].Journal of Alloys and Compounds,2023,952:169908.
[22] Gan Y,Xu F,Luo J,et al.One-pot biotemplate synthesis of FeS2 decorated sulfur-doped carbon fiber as high capacity anode for lithium-ion batteries[J].Electrochimica Acta,2016,209:201-209.
[23] Lu Z,Zhai Y,Wang N,et al.FeS2 nanoparticles embedded in N/S co-doped porous carbon fibers as anode for sodium-ion batteries[J].Chemical Engineering Journal,2020,380:122455.
[24] Hang B T,Egashira M,Watanabe I,et al.Electrochemical properties of Fe2O3-nano-loaded carbon and Fe2O3-nano/carbon mixed composites for iron-air battery anodes[J].Kyushu University Graduate School of Electric System Engineering Report,2005,27(1):1-8.
[25] Peng P,Zhao Q,Zhu P,et al.Amorphous Fe2O3 film-coated mesoporous Fe2O3 core-shell nanosphere prepared by quenching as a high-performance anode material for lithium-ion batteries[J].Journal of Electroanalytical Chemistry,2021,898:115633.
[26] Nath S,Kaittanis C,Ramachandran V,et al.Synthesis,magnetic characterization,and sensing applications of novel dextran-coated iron oxide nanorods[J].Chemistry of Materials,2009,21(8):1761-1767.
[27] Liu Y,Zhou X,Chen P,et al.Properties of hollow yolk-shell NiS2/FeS2@NC@NiFe LDH/FeO(OH) nanoflower microspheres as anode materials for lithium-ion batteries[J].Journal of Electroanalytical Chemistry,2023,943:117606.
[28] Wu X,Chen W,Key J,et al.One-pot solvothermal synthesis of fern leaf-like α-Fe2O3@C/graphene from ferrocene with enhanced lithium and sodium storage properties[J].Powder Technology,2018,323:424-432.
[29] He J,Li Q,Chen Y,et al.Self-assembled cauliflower-like FeS2 anchored into graphene foam as free-standing anode for high-performance lithium-ion batteries[J].Carbon,2017,114:111-116.
[30] Wang F,Zhang W,Zhou H,et al.Preparation of porous FeS2-C/RG composite for sodium ion batteries[J].Chemical Engineering Journal,2020,380:122549.
[31] Liu Y,Li W,Xia Y.Recent progress in polyanionic anode materials for Li(Na)-ion batteries[J].Electrochemical Energy Reviews,2021,4(3):447-472.
[32] Li D,Zhang M,Zhang L,et al.Constructing three-dimensional N-doped carbon coating silicon/iron silicide nanoparticles cross-linked by carbon nanotubes as advanced anode materials for lithium-ion batteries[J].Journal of Colloid and Interface Science,2023,629:908-916.
[33] Wang Z,Luo S,Zhang X,et al.Glass and glass ceramic electrodes and solid electrolyte materials for lithium ion batteries:a review[J].Journal of Non-Crystalline Solids,2023,619:122581.
基金资助
国家自然科学基金(41807235)
PDF
