制备高效、稳定和低成本的析氢反应电催化剂是目前氢能大规模利用面临的挑战之一。为了应对这些挑战,通常采用界面工程来提高催化剂的活性和稳定性。总结了酸碱性条件下析氢反应的机理,综述了NiS基异质结的构建方法及其在强化电催化析氢活性中的应用,分析了存在的问题并展望了未来NiS基异质结构催化剂的研究方向。
The preparation of efficient,stable and low-cost electrocatalysts for hydrogen precipitation reactions is one of the current challenges for the large-scale utilization of hydrogen energy.To address these challenges,interface engineering is often employed to effectively improve the activity and stability of catalysts.The mechanism of hydrogen precipitation reaction under acid-base conditions was summarized in detail,the construction methods of NiS-based heterojunctions and their applications in enhancing the electrocatalytic hydrogen precipitation activity were reviewed,the existing problems were analyzed,and the future research direction of NiS-based heterostructure catalysts was envisioned.
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基金资助
湖南省自然科学基金(2023JJ31009);国家重点研发计划项目(2019YFB1503804)
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