生物质化工逐步替代石油化工是我国实现“3060”碳中和碳达峰的必经之路,且生物质化工在包装,纺织品和塑料等领域都表现出巨大潜力,其中以聚呋喃二甲酸乙二醇酯(PEF)为代表性化学品,它已成为生物炼制与绿色化工领域研究的热点之一。与石油基产物聚对苯二甲酸乙二醇酯(PET)相比,合成PEF的原料更为绿色,机械强度与耐热性方面较PET也更为优异,尤其是在阻隔气体渗透的性能上十分突出,被认为是PET的完美替代品。然而,在研究过程中也暴露出PEF断裂伸长率过低、结晶速度缓慢,降解困难等问题,因此,在实际应用中需要对其进行改性。重点综述了PEF改性研究以及降解技术的进展,并对PEF的发展趋势和未来前景进行展望。
The gradual replacement of petrochemicals by biomass chemicals is the only way for China to achieve “3060” carbon neutrality and carbon peaking,and biomass chemicals has shown great potential in packaging,textiles and plastics and other fields.Among them,polyethylene furan diformate (PEF),as a representative chemical,has become one of the hotspots in biorefinery and green chemical research.Compared with the petroleum-based product polyethylene terephthalate (PET),the raw material for the synthetic of PEF is more environmentally friendly,and the mechanical strength and heat resistance are better than those of PET,especially in the performance of blocking gas penetration,and it is considered to be the perfect substitute for PET.However,during the research process,the problems such as low elongation at break,slow crystallization rate,and dificulty in degradation of PEF are also exposed,and it needs to be modified in practical applications.In this paper,we reviewed the research progress on the modification and degradation technology of PEF,and looked forward to the development trend and future prospects of PEF.
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