介绍了水性聚氨酯材料的阻燃机理以及添加型阻燃和反应型阻燃对水性聚氨酯改性研究的现状;对现有阻燃改性水性聚氨酯材料的阻燃性能进行了概述;并对水性聚氨酯阻燃复合材料在更广泛的领域应用进行了综述和展望。
This paper introduced the flame-retardant mechanism of waterborne polyurethane materials and reviewed the current research status of the modification of waterborne polyurethane by additive and reactive flame retardants.An overview of the flame-retardant properties of existing flame-retardant modified waterborne polyurethane materials was given,and a review and outlook was provided on the application of waterborne polyurethane flame-retardant composite materials in a wider range of fields.
[1] 朱超男,张伟,郑慧.水性聚氨酯阻燃性能研究进展[J].辽宁化工,2023,52(5):732-735.
[2] Gu Limin,Ge Zhen,Huang Muhua,et al.Halogen-free flame-retardant waterborne polyurethane with a novel cyclic structure of phosphorus nitrogen synergistic flame retardant[J].Journal of Applied Polymer Science,2015,70(3):859-869.
[3] 刘继纯,牛睿祺,井蒙蒙,等.聚合物材料燃烧性和阻燃性的实验方法[J].合成树脂及塑料,2010,58(6):74-78.
[4] Araby S,Philips B,Meng Q,et al.Recent advances in carbon-based nanomaterials for flame retardant polymers and composites[J].Composites Part B:Engineering,2021,212:108675.
[5] 欧育湘.国外阻燃剂发展动态及对发展我国阻燃剂工业之浅见[J].精细与专用化学品,2003,11(2):4-9.
[6] Laoutid F,Bonnaud L,Alexandre M,et al.New prospects in flame retardant polymer materials:from fundamentals to nanocomposites[J].Materials Science and Engineering:R:Reports,2009,63(3):100-125.
[7] Zhou C,Nih M,Zhu B,et al.Progress and outlook in the waterborne flame retardant polyurethane[J].Chemical Industry Times,2022,36(5):8-12.
[8] 杨良敏.大豆油基阻燃水性聚氨酯的制备与表征[D].武汉:湖北大学,2022.
[9] 黄燕萍,程良松,蔡绍祥.水性聚氨酯/纳米纤维素/氢氧化镁或纳米铜粒子复合材料制备及阻燃、耐磨性能研究[J].林产工业,2023,60(10):7-12,39.
[10] 蔡绍祥,刘荣贵,程良松.纳米纤维素改性水性聚氨酯材料阻燃性能研究[J].林产工业,2022,59(11):20-26.
[11] Yin S,Ren X,Lian P,et al.Synergistic effects of black phosphorus/boron nitride eanosheets on enhancing the flame-retardant properties of waterborne polyurethane and its flame-retardant mechanism[J].Polymers,2020,12(7):1487.
[12] 朱港港,黄毅萍,鲍俊杰,等.阻燃型水性聚氨酯乳液的制备及性能[J].塑料工业,2024,52(1):29-35.
[13] 安炳辉,姚伯龙,姚旭,等.含磷硅水性聚氨酯的制备及其阻燃性能的研究[J].聚氨酯工业,2022,37(5):28-31.
[14] 马晋怡,于俊荣,王彦,等.含磷阻燃改性水性聚氨酯的合成及性能研究[J].聚氨酯工业,2022,37(1):32-35.
[15] 宿倩雪,杨璐璐,吕佳帅男,等.磷硅协同阻燃改性水性聚氨酯[J].合成树脂及塑料,2020,37(5):24-27,38.
[16] Feng L,Wang W,Song B,et al.Synthesis of P,N and Si-containing waterborne polyurethane with excellent flame retardant,alkali resistance and flexibility via one-step synthetic approach[J].Progress in Organic Coatings,2023,174(10):107286.
[17] 张贝楠.阻燃水性聚氨酯涂料的制备与研究[D].上海:东华大学,2022.
[18] 黄婉莹,刘海生,周玉冰,等.棉织物的水性聚氨酯阻燃涂层整理及其性能研究[J].化纤与纺织技术,2023,52(10):13-17.
[19] Sun Y,Xin H,Wu Y,et al.Synthesis of P-N-S elemental flame-retardant waterborne polyurethane and its application in polyamide fabric[J].Progress in Organic Coatings,2024,186:10802.
[20] Zhang Cheng,He Hui,Li Qunyang,et al.Synthesis and characterization of flame-retardant polyurethane based on new chain extenders[J].Polymer Interbational,2023,71(10):1193-1200.
[21] Zhu J,Li J,Cai W,et al.Synthesis and application of a phosphorus-containing waterborne polyurethane based polymeric dye with excellent flame retardancy[J].Progress in Organic Coatings,2020,140:105525.
基金资助
国家自然科学基金(51143005);湖北省自然科学基金项目(2010CDB05805)
PDF
