生物质基聚氨酯材料的研究对实现聚氨酯材料绿色化生产有着重要的意义。围绕近五年的相关文献,针对木质素、常见植物油(蓖麻油、大豆油、棕榈油)以及多糖类(淀粉、壳聚糖)几种典型生物质资源,详细介绍了其应用于合成功能性聚氨酯材料时重要的改性特点,并讨论了改性生物质基聚氨酯材料所面临的挑战与前景展望。
The research on biomass-based polyurethane materials is of great significance for achieving the green production of polyurethane materials.Based on the relevant literature from the past five years,focusing on several typical biomass resources such as lignin,common plant oils (castor oil,soybean oil,palm oil) and polysaccharides (starch,chitosan),this review provided a detailed overview of their important modification characteristics when applied in the synthesis of functional polyurethane materials,and the challenges and prospects faced by modified biomass-based polyurethane materials were discussed.
[1] 徐培林,张淑琴.聚氨酯材料手册[M/OL].北京:化学工业出版社,2002.
[2] Sternberg J,Sequerth O,Pilla S.Green chemistry design in polymers derived from lignin:review and perspective[J].Progress in Polymer Science,2021,113:101344.
[3] 陈凤贵,涂小寒,胡茜,等.木质素增强水性聚氨酯性能研究[J].武汉大学学报(理学版),2019,65(4):377-382.
[4] 马晓振,罗清,秦冬冬,等.木质素基生物质聚氨酯[J].化学进展,2020,32(5):617-626.
[5] 陈鄞琛.乙酸木质素改性聚氨酯胶黏剂的合成和性能研究[D].广州:华南理工大学,2020.
[6] Klein S E,Alzagameem A,Rumpf J,et al.Antimicrobial activity of lignin-derived polyurethane coatings prepared from unmodified and demethylated lignins[J].Coatings,2019,9(8):494.
[7] Chen Y,Zhang H,Zhu Z,et al.High-value utilization of hydroxymethylated lignin in polyurethane adhesives[J].International Journal of Biological Macromolecules,2020,152:775-785.
[8] Vieira F R,Gama N,Magina S,et al.Polyurethane adhesives based on Oxyalkylated Kraft lignin[J].Polymers,2022,14(23):5305.
[9] 朱妮妮.木质素基聚氨酯泡沫的制备及其油水分离性能的研究[D].大庆:东北石油大学,2023.
[10] Gouveia J R,de Sousa Júnior R R,Ribeiro A O,et al.Effect of soft segment molecular weight and NCO∶OH ratio on thermomechanical properties of lignin-based thermoplastic polyurethane adhesive[J].European Polymer Journal,2020,131:109690.
[11] Wu T,Li X,Ma X,et al.Modification of lignin by hexamethylene diisocyanate to synthesize lignin-based polyurethane as an organic polymer for marine polyurethane anticorrosive coatings[J].Materials Research Express,2022,9(10):105302.
[12] Li X,Liu C,An X,et al.Bio-based alkali lignin cooperative systems for improving the flame retardant and mechanical properties of rigid oolyurethane foam[J].Polymers,2023,15(24):4709.
[13] Antonino L D,Sumerskii I,Potthast A,et al.Lignin-based polyurethanes from the blocked isocyanate approach:synthesis and characterization[J].ACS Omega,2023,8(30):27621-27633.
[14] Li Y,Chen S,Shen J,et al.Preparation and properties of biobased,cationic,waterborne polyurethanes dispersions from castor oil and poly (caprolactone) diol[J].Applied Sciences,2021,11(11):4784.
[15] 欧艺威.可降解型聚氨酯树脂的制备及其降解行为研究[D].广州:广东工业大学,2022.
[16] 金伟,杨润苗,沈鑫,等.蓖麻油的改性及其在聚氨酯电子灌封胶中的应用研究[J].江苏理工学院学报,2023,29(2):105-113.
[17] 吴振强.耐水抗菌型蓖麻油基水性聚氨酯的制备及性能研究[D].西安:陕西科技大学,2023.
[18] 关仲翔,梅子能.蓖麻油衍生物水性聚氨酯树脂的合成及性能表征[J].化工技术与开发,2021,50(6):23-25.
[19] 宋利青,石红翠,张博,等.湿固化聚氨酯胶黏剂的制备及耐水性研究[J].聚氨酯工业,2021,36(3):11-14.
[20] 吕斌,张鹤年,高党鸽.PDMS改性蓖麻油基水性聚氨酯的制备及防污性能[J].精细化工,2022,39(3):541-547.
[21] 胡继广,周登健,杨建军,等.UV固化改性蓖麻油基水性聚氨酯的制备及抗菌性能[J].精细化工,2021,38(12):2478-2484,2538.
[22] 王汝康,曾艳茹,徐长安,等.蓖麻油基聚氨酯光固化薄膜的制备及自修复性能[J].广州化学,2023,48(4):7-15,83.
[23] 陈佳琪.改性水性聚氨酯基纸质文物保护液的制备及性能研究[D].宁波:浙江理工大学,2022.
[24] Tenorio-Alfonso A,Sánchez M C,Franco J M.Synthesis and mechanical properties of bio-sourced polyurethane adhesives obtained from castor oil and MDI-modified cellulose acetate:influence of cellulose acetate modification[J].International Journal of Adhesion and Adhesives,2019,95:102404.
[25] Peres T L C,Ribeiro F V,Aramburu A B,et al.Polyurethane adhesives for wood based on a simple mixture of castor oil and crude glycerin[J].Materials,2023,16(23):7251.
[26] Kim B M,Choi J S,Jang S,et al.Sustainable strategies for synthesizing lignin-incorporated bio-based waterborne polyurethane with tunable characteristics[J].Polymers,2023,15(19):3987.
[27] 杨富凯,于浩,邓玉媛,等.不同结构的大豆油基聚氨酯泡沫的制备与性能[J].塑料,2022,51(3):93-97,121.
[28] 代注顶.植物油基水性聚氨酯的制备及其性能研究[D].无锡:江南大学,2021.
[29] 李明阳,史珺,韦代东,等.环氧大豆油合成生物基多元醇及其在聚氨酯木材胶黏剂中的应用性能[J].广州化学,2023,48(4):16-19,25,83.
[30] 张洪礼,王文君,黄毅萍,等.磷酸化环氧大豆油改性水性聚氨酯的制备[J].中国皮革,2020,49(1):41-48.
[31] 彭丽,田苏平,王念贵.羟丙基聚硅氧烷改性大豆油基水性聚氨酯的制备[J].胶体与聚合物,2021,39(3):125-127,131.
[32] 张世万,田苏平,王念贵.氨基氟硅氧烷改性大豆油基水性聚氨酯的制备[J].胶体与聚合物,2021,39(4):160-162.
[33] Dodangeh F,Dorraji M S S,Rasoulifard M H,et al.Synthesis and characterization of alkoxy silane modified polyurethane wood adhesive based on epoxidized soybean oil polyester polyol[J].Composites Part B:Engineering,2020,187:107857.
[34] 高思.棕榈油基聚氨酯的制备及其应用研究[D].武汉:湖北大学,2019.
[35] Zhang D,Chen S.The study of palm-oil-based bio-polyol on the morphological,acoustic and mechanical properties of flexible polyurethane foams[J].Polymer International,2020,69(3):257-264.
[36] Polaczek K,Kurańska M,Auguścik-Królikowska M,et al.Open-cell polyurethane foams of very low density modified with various palm oil-based bio-polyols in accordance with cleaner production[J].Journal of Cleaner Production,2021,290:125875.
[37] Javaid M A,Zia K M,Iqbal A,et al.Utilization of waxy corn starch as an efficient chain extender for the preparation of polyurethane elastomers[J].International Journal of Biological Macromolecules,2020,148:415-423.
[38] 陈东鹊.淀粉基水性聚氨酯胶黏剂的合成、性能与应用[D].广州:广州大学,2022.
[39] 黄一迅.生物质基阻燃聚醚多元醇的制备与应用[D].长春:长春工业大学,2022.
[40] 周利琴.β-环糊精及淀粉基聚合物吸附分离水中芳香类有机物[D].南宁:广西大学,2021.
[41] 董晶晶,田虹雨,石若琳,等.添加纳米TiO2改善淀粉基聚酯聚氨酯复合材料的膜层质量和养分控释特性[J].植物营养与肥料学报,2023,29(7):1367-1378.
[42] Tian H,Li Z,Lu P,et al.Starch and castor oil mutually modified,cross-linked polyurethane for improving the controlled release of urea[J].Carbohydrate Polymers,2021,251:117060.
[43] Paprota N,Szatkowski P,Szlachta M,et al.The effect of starch and magnetite on the physicochemical properties of polyurethane composites for hyperthermia treatment[J].Advances in Polymer Technology,2022,2022(1):7377895.
[44] Lei L,Buddingh J,Wang J,et al.Transparent omniphobic polyurethane coatings containing partially acetylated β-cyclodextrin as the polyol[J].Chemical Engineering Journal,2020,380:122554.
[45] Sklenickova K,Vlckova V,Abbrent S,et al.Open-cell aliphatic polyurethane foams with high content of polysaccharides:structure,degradation,and ecotoxicity[J].ACS Sustainable Chemistry & Engineering,2021,9(17):6023-6032.
[46] Javaid M A,Zia K M,Khera R A,et al.Evaluation of cytotoxicity,hemocompatibility and spectral studies of chitosan assisted polyurethanes prepared with various diisocyanates[J].International Journal of Biological Macromolecules,2019,129:116-126.
[47] Szlachta M,Ordon K,Nowicka K,et al.Thermal properties of polyurethane-based composites modified with chitosan for biomedical applications[J].Journal of Thermal Analysis and Calorimetry,2021,143:3471-3478.
[48] Wang Q,Feng Z,He C,et al.Preparation and performance study of a reactive polyurethane hot-melt adhesive/CS-Fe3O4 magnetic nanocomposite film/fabric[J].RSC Advances,2022,12(42):27463-27472.
[49] 周龙,杜国勇,邓春萍.超亲水-水下超疏油聚氨酯海绵的制备及其油水分离性能研究[J].中国塑料,2023,37(8):28-37.
[50] Strzał ka A,Lubczak R,Lubczak J.Chitosan oligomer as a raw material for obtaining polyurethane foams[J].Polymers,2023,15(14):3084.
基金资助
国家自然科学基金(51143005);湖北省自然科学基金项目(2010CDB05805)
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