能源和环境问题已成为世界面临的重大挑战,开发具有低成本和高效率特性的新材料并应用于能量转换及环境领域至关重要。许多研究表明,典型的过渡金属MOF(如镍、钴和锰)具有低成本、高孔隙和比表面积大等优点,已成功应用于储能装置和环境净化领域,有利于进一步推动能源发展和工业化生产。选择了3种环境友好且成本低廉的金属元素(镍、钴和锰)作为研究对象,总结了过渡金属Ni-Co-Mn MOFs及其衍生物的结构、形貌、制备路径及在能源和环境领域的最新实际应用(这些领域包括可充电电池、超级电容器、电催化剂、气体吸附和污染物降解等),展望了Ni-Co-Mn MOFs材料在能源和环境领域的应用前景,讨论了其所面临的机遇与挑战。
Energy and environmental issues have become major challenges facing the world,and it is important to develop new materials with low cost and high efficiency for energy conversion and environmental fields.Numerous studies have shown that typical transition metal MOFs (such as nickel,cobalt and manganese) have the advantages of low cost,high porosity and large specific surface area,and have been successfully applied in the fields of energy storage devices and environmental purification,which is conducive to further promoting energy development and industrial production.Three environmentally friendly and low-cost metal elements (nickel,cobalt and manganese) were selected as research objects.The structures,morphologies,preparation methods of transition metal Ni-Co-Mn MOFs and their derivatives,as well as their latest practical applications in the fields of energy and environment,including rechargeable batteries,supercapacitors,electrocatalysts,gas adsorption and pollutant degradation,etc.,were reviewed.The application prospects of Ni-Co-Mn MOFs materials in the fields of energy and environment were also envisioned,and the opportunities and challenges they faced were discussed.
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