天然高分子凝胶电解质具有低成本、可降解、绿色环保等优点,被认为是可持续超级电容器的关键技术之一。介绍了天然高分子基凝胶电解质的特性,综述了天然高分子凝胶电解质(包括纤维素、壳聚糖、明胶等)在超级电容器中的研究进展,并总结了其基本制备方式、优势及不足,对天然高分子基凝胶电解质的研究与应用具有一定的借鉴意义。
Natural polymer gel electrolyte is considered to be one of the key technologies for sustainable supercapacitors due to its low cost,degradability and environmental friendliness.In this paper,the characteristics of natural polymer-based gel electrolytes were introduced.The research progress of natural polymer-based gel electrolytes (including cellulose,chitosan,gelatin,etc.) in supercapacitors was reviewed.The basic preparation methods,advantages and disadvantages of natural polymer-based gel electrolytes were summarized,proving a certain reference for the research and application of natural polymer-based gel electrolytes.
[1] 张紫瑞,赵云鹏,张颖,等.超级电容器电极材料研究进展[J].化工新型材料,2019,47(12):1-5.
[2] Baig M M,Khan M A,Gul I H,et al.A review of advanced electrode materials for supercapacitors:challenges and opportunities[J].Journal of Electronic Materials,2023,52(9):5775-5794.
[3] Pacheco M,Lefort B,Pacheco J,et al.Hydrogel and carbon nanostructures based supercapacitor:initial steps toward green supercapatteries[J].Journal of Energy Storage,2023,72:108539.
[4] Lu X H,Yu M H,Wang G M,et al.Flexible solid-state supercapacitors:design,fabrication and applications[J].Energy & Environmental Science,2014,7(7):2160-2181.
[5] Wang Z,Wang L,Jiang W Y,et al.Development of flame-retardant ion-gel electrolytes for safe and flexible supercapacitors[J].Science China-Materials,2023,66(8):3129-3138.
[6] Tadesse M G,Luebben J F.Review on hydrogel-based flexible supercapacitors for wearable applications[J].Gels,2023,9:106.
[7] Bai Y,Zhao W,Bi S,et al.Preparation and application of cellulose gel in flexible supercapacitors[J].Journal of Energy Storage,2021,42:103058.
[8] Karan C K,Mallick S,Raj C R,et al.A self-healing metal-organic hydrogel for an all-solid flexible supercapacitor[J].Chemistry-a European Journal,2019,25(65):14775-14779.
[9] Wu L,Shi X Y,Wu Z S.Recent advancements and perspectives of biodegradable polymers for supercapacitors[J].Advanced Functional Materials,2023,33(16):2211454.
[10] Wang D K,Yang F S,Cong L L,et al.Lignin-containing hydrogel matrices with enhanced adhesion and toughness for all-hydrogel supercapacitors[J].Chemical Engineering Journal,2022,450:138025.
[11] Lin S Y,Wang F J,Shao Z Q.Biomass applied in supercapacitor energy storage devices[J].Journal of Materials Science,2021,56(3):1943-1979.
[12] Vijayakumar M,Sankar A B,Rohita D S,et al.Conversion of biomass waste into high performance supercapacitor electrodes for real-time supercapacitor applications[J].ACS Sustainable Chemistry & Engineering,2019,7(20):17175-17185.
[13] Wang Y,Xu T,Liu K,et al.Biomass-based materials for advanced supercapacitor:principles,progress,and perspectives[J].Aggregate,2024,5(1):e428.
[14] Selvaraj T,Perumal V,Khor S F,et al.The recent development of polysaccharides biomaterials and their performance for supercapacitor applications[J].Materials Research Bulletin,2020,126:110839.
[15] Colherinhas G,Malaspina T,Fileti E E.Storing energy in biodegradable electrochemical supercapacitors[J].ACS Omega,2018,3(10):13869-13875.
[16] 朱伟志,李雯静,贺媚,等.各向异性纤维素双交联水凝胶的制备与应用研究[J].化工新型材料,2024,52(3):226-230,235.
[17] Rana H H,Park J H,Gund G S,et al.Highly conducting,extremely durable,phosphorylated cellulose-based ionogels for renewable flexible supercapacitors[J].Energy Storage Materials,2020,25:70-75.
[18] Gupta V K,Carrott P J M,Singh R,et al.Cellulose:a review as natural,modified and activated carbon adsorbent[J].Bioresource Technology,2016,216:1066-1076.
[19] Nechyporchuk O,Yu J C,Nierstrasz V A,et al.Cellulose nanofibril-based coatings of woven cotton fabrics for improved inkjet printing with a potential in E-textile manufacturing[J].ACS Sustainable Chemistry & Engineering,2017,5(6):4793-4801.
[20] Zheng Q F,Cai Z Y,Ma Z Q,et al.Cellulose nanofibril/reduced graphene oxide/carbon nanotube hybrid aerogels for highly flexible and all-solid-state supercapacitors[J].ACS Applied Materials & Interfaces,2015,7(5):3263-3271.
[21] Wang Z H,Carlsson D O,Tammela P,et al.Surface modified nanocellulose fibers yield conducting polymer-based flexible supercapacitors with enhanced capacitances[J].ACS Nano,2015,9(7):7563-7571.
[22] Wang Y H,Wei X Y,Li J H,et al.Homogeneous isolation of nanocellulose from eucalyptus pulp by high pressure homogenization[J].Industrial Crops and Products,2017,104:237-241.
[23] Ye D D,Lei X J,Li T,et al.Ultrahigh tough,super clear,and highly anisotropic nanofiber-structured regenerated cellulose films[J].ACS Nano,2019,13(4):4843-4853.
[24] Wang H,Xie H X,Du H S,et al.Highly efficient preparation of functional and thermostable cellulose nanocrystals via H2SO4 intensified acetic acid hydrolysis[J].Carbohydrate Polymers,2020,239:116233.
[25] Zhu A T,Huang J,Xie H B,et al.Use of a superbase/DMSO/CO solvent in order to incorporate cellulose into organic ionogel electrolyte for flexible supercapacitors[J].Chemical Engineering Journal,2022,446:137032.
[26] Luan X,Zhang K,Shen W,et al.Engineering self-healing cellulose-reinforced organohydrogel electrolytes for flexible foldable capacitors with low temperature adaptability[J].Industrial Crops and Products,2024,216:118692.
[27] Zhang K F,Pang Y J,Chen C Z,et al.Stretchable and conductive cellulose hydrogel electrolytes for flexible and foldable solid-state supercapacitors[J].Carbohydrate Polymers,2022,293:119673.
[28] Durukan M B,Keskin D,Tufan Y,et al.An edible supercapacitor based on zwitterionic soy sauce-based gel electrolyte[J].Advanced Functional Materials,2023,34(6):2307051.
[29] 薛添仁,曹省慧,王硕,等.壳聚糖基生物可降解食品包装材料的研究进展[J].化工新型材料,2023,51(6):231-234,240.
[30] Jia X,Ma P,Wei C I,et al.Chitin and chitosan:pioneering sustainable substrates for next-generation soilless vertical farming[J].Trends in Food Science & Technology,2024,150:104599.
[31] Sheng H L,Zhu A T,Zhang L H,et al.Use of an [EMIM][OAc]/GVL-based organic electrolyte solvent to engineer chitosan into a nanocomposite organic ionogel electrolyte for flexible supercapacitors[J].Green Chemistry,2023,25(8):3046-3056.
[32] Xu M,Yue W,Zhang L,et al.Engineering chitosan into a recyclable and flame-resistant gel electrolyte via a dual cross-linking strategy for flexible supercapacitors[J].Green Chemistry,2024,26(2):918-926.
[33] Qu M F,Lei D,Zhang H,et al.One-pot method for in situ synthesis of triple cross-linked hydrogel electrolytes for flexible supercapacitors with high mechanical and electrochemical properties[J].Journal of Energy Storage,2023,72:108644.
[34] Peng K L,Wang W Z,Zhang J H,et al.Preparation of chitosan/sodium alginate conductive hydrogels with high salt contents and their application in flexible supercapacitors[J].Carbohydrate Polymers,2022,278:118927.
[35] Wang R T,Lei D,Zhang H,et al.An interface-integrated hydrogel for all-in-one flexible supercapacitor with excellent wide-temperature and self-healing properties[J].Composites Part B-Engineering,2024,275:111345.
[36] Etxabide A,Uranga J,Guerrero P,et al.Development of active gelatin films by means of valorisation of food processing waste:a review[J].Food Hydrocolloids,2017,68:192-198.
[37] Sarika P R,James N R.Polyelectrolyte complex nanoparticles from cationised gelatin and sodium alginate for curcumin delivery[J].Carbohydrate Polymers,2016,148:354-361.
[38] Liang Y P,Song Q W,Chen Y K,et al.Stretch-induced robust intrinsic antibacterial thermoplastic gelatin organohydrogel for a thermoenhanced supercapacitor and mono-gauge-factor sensor[J].ACS Applied Materials & Interfaces,2023,15(16):20278-20293.
[39] Zhu A T,Xu Q Q,Huang J,et al.Fabrication of gelatin-derived gel electrolyte using deep eutectic solvents through in situ derivatization and crosslinking strategy for supercapacitors and flexible sensors[J].ACS Applied Materials & Interfaces,2023,15(35):41483-41493.
[40] Gao C X,Gao Z C,Wei Y Q,et al.Flexible wood enhanced poly(acrylic acid-co-acrylamide)/quaternized gelatin hydrogel electrolytes for high-energy-density supercapacitors[J].ACS Applied Materials & Interfaces,2023,15(2):2951-2960.
基金资助
国家自然科学基金面上项目(21774028)