近年来电子设备数量飞速增长,由此导致的电磁辐射和干扰问题也愈发引起人们的重视。通过吸波材料吸收和损耗电磁波能量是一种有效降低电磁辐射的方式。聚吡咯纳米材料具有质轻、电导率可控、合成简便、界面极化强等优势,成为新一代吸波材料的理想基体。首先介绍了吸波材料吸收电磁波的电损耗和磁损耗机理,随后对单一聚吡咯和聚吡咯复合材料在电磁波吸收领域的研究进展进行了综述。最后,讨论了聚吡咯复合纳米吸波材料的发展困境和未来改进方向,希望为新一代吸波材料的设计提供参考。
With the rapid growth of the number of electronic equipment in recent years,the problems of electromagnetic radiation and interference have attracted more and more attention.Absorbing and losing electromagnetic wave energy through wave-absorbing materials is an effective way to solve this problem.Polypyrrole nanomaterials have become an ideal matrix for the new generation of wave-absorbing materials because of their advantages such as light weight,controllable electrical conductivity,simple synthesis and strong interfacial polarization.Firstly,the electric and magnetic loss mechanisms of wave-absorbing materials were introduced,and then the research progress of single polypyrrole and polypyrrole composites in the field of electromagnetic wave absorption was reviewed.Finally,the development predicament and future improvement direction of polypyrrole wave-absorbing nanomaterials were discussed in the hope of providing reference for the design of the new generation of wave-absorbing materials.
[1] 李娟.磁性复合材料的制备及其电磁波吸收性能的研究[D].长春:吉林大学,2018.
[2] Kocaman A,Altun G,Kaplan A A,et al.Genotoxic and carcinogenic effects of non-ionizing electromagnetic fields[J].Environmental Research,2018,163:71-79.
[3] 盖莉雪.聚吡咯基纳米复合材料形貌调控及吸波性能研究[D].大连:大连工业大学,2021.
[4] Hao L,Dong C,Zhang L,et al.Polypyrrole nanomaterials:structure,preparation and application[J].Polymers (Basel),2022,14(23):5139.
[5] Soares B G,Barra G M O,Indrusiak T.Conducting polymeric composites based on intrinsically conducting polymers as electromagnetic interference shielding/microwave absorbing materials—a review[J].Journal of Composites Science,2021,5(7):173.
[6] Munir A.Microwave radar absorbing properties of multiwalled carbon nanotubes polymer composites:a review[J].Advances in Polymer Technology,2017,36(3):362-370.
[7] Cao M S,Song W L,Hou Z L,et al.The effects of temperature and frequency on the dielectric properties,electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites[J].Carbon,2010,48(3):788-796.
[8] Zhu L,Zeng X,Li X,et al.Hydrothermal synthesis of magnetic Fe3O4/graphene composites with good electromagnetic microwave absorbing performances[J].Journal of Magnetism and Magnetic Materials,2017,426:114-120.
[9] 董久锋,邓星磊,牛玉娟,等.面向高温介电储能应用的聚合物基电介质材料研究进展[J].物理学报,2020,69(21):43-58.
[10] Ma J,Wang X,Cao W,et al.A facile fabrication and highly tunable microwave absorption of 3D flower-like Co3O4-rGO hybrid-architectures[J].Chemical Engineering Journal,2018,339:487-498.
[11] Yan J,Huang Y,Liu X,et al.Polypyrrole-based composite materials for electromagnetic wave absorption[J].Polymer Reviews,2021,61(3):646-687.
[12] Ali N N,Atassi Y,Salloum A,et al.Lightweight broadband microwave absorbers of core-shell (polypyrrole/NiZn ferrite) nanocomposites in the X-band:insights on interfacial polarization[J].Journal of Materials Science:Materials in Electronics,2019,30(7):6876-6887.
[13] Hao B,Li L,Wang Y,et al.Electrical and microwave absorbing properties of polypyrrole synthesized by optimum strategy[J].Journal of Applied Polymer Science,2013,127(6):4273-4279.
[14] Kulkarni G,Kandesar P,Velhal N,et al.Facile synthesis of coral cauliflower-like polypyrrole hemispheres toward screening electromagnetic interference pollution[J].Journal of Applied Polymer Science,2021,138(22):50447-50455.
[15] Ren H,Li T,Wang H,et al.Two birds with one stone:superhelical chiral polypyrrole towards high-performance electromagnetic wave absorption and corrosion protection[J].Chemical Engineering Journal,2022,427:131582-131594.
[16] 万振东.聚吡咯基材料的制备及其吸波性能研究[D].杭州:中国计量大学,2021.
[17] Wang J,Wang B,Feng A,et al.Design of morphology-controlled and excellent electromagnetic wave absorption performance of sheet-shaped ZnCo2O4 with a special arrangement[J].Journal of Alloys and Compounds,2020,834:155092-155102.
[18] Mahule T S,Das J,Srinivasu V V.Low-field microwave absorption in Zn1-x(Mn:Fe(Ni))xO(x=0.02) system:hysteresis,line shapes and powdering effects[J].Applied Physics A,2019,125(4):231-236.
[19] Wu Z,Tan D,Tian K,et al.Facile preparation of core-shell Fe3O4@polypyrrole composites with superior electromagnetic wave absorption properties[J].The Journal of Physical Chemistry C,2017,121(29):15784-15792.
[20] Hosseini S H,Asadnia A.Synthesis,characterization,and microwave-absorbing properties of polypyrrole/MnFe2O4 nanocomposite[J].Journal of Nanomaterials,2012,2012:198973-198978.
[21] 景茂祥,沈湘黔.纳米磁性金属电磁波吸收剂的研究进展及展望[J].材料导报,2005,19(12):13-16.
[22] 常传波.Ni0.5Zn0.5Fe2O4铁氧体基纳米复合材料的制备及其吸波性能研究[D].太原:中北大学,2011.
[23] Zhang N,Li J,Men X,et al.Cleaning synthesis of core-shell structured Ni@PPy composite as excellent lightweight electromagnetic wave absorber[J].Journal of Materials Science:Materials in Electronics,2020,31(2):1483-1490.
[24] Wang H C,Yan Z R,Deng L,et al.Synthesis and surface modification of cobalt nanoparticles and electromagnetic property of Co/PPy nanocomposites[J].Rare Metals,2015,34(4):223-228.
[25] Gai L,Zhao Y,Song G,et al.Construction of core-shell PPy@MoS2 with nanotube-like heterostructures for electromagnetic wave absorption:assembly and enhanced mechanism[J].Composites Part A:Applied Science and Manufacturing,2020,136:105965-105975.
[26] Zhang L,Jia J,Liang H,et al.Facile synthesis of adjustable high-entropy alloy/polypyrrole electromagnetic wave absorber[J].Journal of Materials Science:Materials in Electronics,2021,32(21):26074-26085.
[27] 翁立,闵永刚.石墨烯基吸波复合材料的研究新进展[J].功能材料,2017,48(12):12041-12049.
[28] Sun K,Yang X,Lei Y,et al.Core-shell structural design and microwave absorption enhancement of multi-dimensional graphene oxide@polypyrrole/carbonyl iron fiber nanocomposites[J].Journal of Alloys and Compounds,2023,930:167446-167455.
[29] Liu B,Li J,Wang L,et al.Ultralight graphene aerogel enhanced with transformed micro-structure led by polypyrrole nano-rods and its improved microwave absorption properties[J].Composites Part A:Applied Science and Manufacturing,2017,97:141-150.
[30] Zhang K,Xie A,Wu F,et al.Carboxyl multiwalled carbon nanotubes modified polypyrrole (PPy) aerogel for enhanced electromagnetic absorption[J].Materials Research Express,2016,3(5):055008-055018.
[31] 郭蕊.基于石墨烯和MXene制备电磁防护材料[D].上海:东华大学,2022.
[32] Liu T,Liu N,An Q,et al.Designed construction of Ti3C2Tx@PPY composites with enhanced microwave absorption performance[J].Journal of Alloys and Compounds,2019,802:445-457.
[33] 刘顺尧,朱金莲,邹紫薇,等.稀土吸波材料的研究进展[J].稀土,2020,41(5):123-136.
[34] Wei W,Liu X,Lu W,et al.Light-weight gadolinium hydroxide@polypyrrole rare-earth nanocomposites with tunable and broadband electromagnetic wave absorption[J].ACS Applied Materials & Interfaces,2019,11(13):12752-12760.
[35] Xing H,Chen W,Liu C,et al.Construction of core-shell-structured Al2O3@ppy composites with high-performance electromagnetic wave absorption performance[J].Journal of Materials Science:Materials in Electronics,2022,33(29):23196-23211.
[36] Tian C,Du Y,Xu P,et al.Constructing uniform core-shell PPy@PANI composites with tunable shell thickness toward enhancement in microwave absorption[J].ACS Applied Materials & Interfaces,2015,7(36):20090-20099.
[37] Huang J,Gu H,Li N,et al.Polypyrrole/schiff base composite as electromagnetic absorbing material with high and tunable absorption performance[J].Molecules,2022,27(19):6160.
[38] Mravčáková M,Omastová M,Pötschke P,et al.Poly(propylene)/montmorillonite/polypyrrole composites:structure and conductivity[J].Polymers for Advanced Technologies,2006,17(9-10):715-726.
[39] Boukerma K,Piquemal J Y,Chehimi M M,et al.Synthesis and interfacial properties of montmorillonite/polypyrrole nanocomposites[J].Polymer,2006,47(2):569-576.
[40] Jin J,Song J,Deng S,et al.Synthesis and microwave absorbing characteristics of flake-like polypyrrole filled composites in X-band[J].Polymer Composites,2016,37(2):532-538.
[41] 贾雪菲,常乾,曹雪芳,等.低频磁损耗型吸波材料研究进展[J].功能材料,2022,53(12):12028-12032,12038.
[42] Zhang M,Zhao L,Zhao W,et al.Boosted electromagnetic wave absorption performance from synergistic induced polarization of SiCNWs@MnO2@PPy heterostructures[J].Nano Research,2023,16(2):3558-3569.
[43] Jafarian M,Seyyed Afghahi S S,Atassi Y,et al.Promoting the microwave absorption characteristics in the X band using core-shell structures of Cu metal particles/PPy and hexaferrite/PPy[J].Journal of Magnetism and Magnetic Materials,2020,493:165680-165689.
[44] Gu Q,Jafarian M,Salman Seyyed Afghahi S,et al.Tuning the impedance matching characteristics of microwave absorbing paint in X-band using copper particles and polypyrrole coating[J].Materials Research Bulletin,2020,125:110780-110787.
[45] Liu P,Huang Y,Zhang X.Synthesis of graphene@branching-like polypyrrole@CoFe2O4 composites and their excellent electromagnetic wave absorption properties[J].Materials Letters,2014,136:298-301.
[46] Wang Q,Wu X,Huang J,et al.Enhanced microwave absorption of biomass carbon/nickel/polypyrrole (C/Ni/PPy) ternary composites through the synergistic effects[J].Journal of Alloys and Compounds,2022,890:161887-161899.
[47] Wang L,Huang L,Li Y,et al.Polypyrrole@reduced graphene oxide@Liquid metal composites for efficient electromagnetic wave absorption[J].Journal of Applied Physics,2022,132(19):194101-194116.
基金资助
陕西省国际科技合作项目(2015KW-016);陕西省科学技术厅青年项目(2022JQ-485)