Coupling agent coating method was used to optimize the performance of long-afterglow phosphor materials,and the preliminary reasons were analyzed.Four kinds of coupling agents,KH550,KH560,A151,and A171 were selected to modify the surface of self-prepared strontium aluminate long-afterglow phosphors.It was found that the ratios of coupling agents had a great influence on the luminescence performance of the powder,and the effects of different coupling agents were different.When the dosage of coupling agent was more than 5%,the luminescence performance of the powder was enhanced obviously,and the peak value appeared in 15%~25% ratio.Comparatively,A171 demonstrated the most noticeable optimization effect on luminescent performance overall.
[1] 宋兆鑫,邹吉祥,刘露露,等.长余辉发光材料及其在建筑内部氛围照明中的应用[J].光源与照明,2023(3):61-65.
[2] 王豪,宋亚坤,刘军辉,等.有机掺杂长余辉发光材料的研究进展[J].精细化工,2023,40(9):1884-1894.
[3] Wang C H,Liu Y H,Liu Y.Near-infrared phosphorescent switchof diarylethene phenylpyridinium derivative and cucurbit[8]uril for cell imaging[J].Small,2022,18(21):2201821.
[4] Zhou B,Yan D P.Color-tunable persistent luminescence in 1Dzinc-organic halide microcrystals for single-component white light and temperature-gating optical waveguides[J].Chemical Science,2022,13(25):7429-7436.
[5] 安欣,岳杨,朱楠楠,等.SrAl2O4∶Eu2+,Dy3+,Tm3+荧光材料的光激励诱导长余辉特性及其防伪应用[J].发光学报,2023,44(11):1931-1939.
[6] 金钰,符斌,杨晓龙,等.长余辉发光材料在配电网安全标志中的应用[J].电力勘测设计,2022(6):10-13,86.
[7] 陈志.香豆素类光色转换剂对夜光纤维用Sr4Al14O25∶Eu2+,Dy3+的光色红移影响研究[D].无锡:江南大学,2018.
[8] 许家友,张艳花.β-二酮包覆发光粉制备PVC发光塑料的研究[J].塑料工业,2009,37(11):66-68.
[9] 郑刘斌,朱亚楠,葛明桥.偶联剂对Sr2MgSi2O7∶Eu2+,Dy3+/光转换剂复合红色发光材料发光性能的影响[J].硅酸盐学报,2020,48(4):463-469.
[10] 杨艳华,冯小伟,马红梅.长余晖自发光路面材料包覆方法及耐水性能影响研究[J].光源与照明,2023(9):53-55.
基金资助
陆军工程大学基础学科科研基金项目(KYSZJKQTZK23003)