改性氮化硼/环氧天然橡胶/天然橡胶复合材料的制备及性能研究

边锋1, 黄舸舸2, 崔凌峰1, 熊玉竹1*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (5) : 140 -145.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (5) : 140-145. DOI: 10.19817/j.cnki.issn1006-3536.2025.05.033
科学研究

改性氮化硼/环氧天然橡胶/天然橡胶复合材料的制备及性能研究

    边锋1, 黄舸舸2, 崔凌峰1, 熊玉竹1*
作者信息 +

Preparation and properties of modified boron nitride/epoxy natural rubber/natural rubber composites

  • Bian Feng1, Huang Gege2, Cui Lingfeng1, Xiong Yuzhu1
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文章历史 +
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摘要

γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)对氮化硼进行表面改性,并将改性后的氮化硼(BN)添加到环氧天然橡胶/天然橡胶(ENR/NR)橡胶基体中制备出橡胶复合材料,并对其力学性能、抗湿滑性能、耐磨性能以及导热性能等进行分析。结果表明:改性后的氮化硼可明显提升填料与基体的相互作用,增强橡胶复合材料的耐磨性能、抗湿滑性能、导热性能等。

Abstract

In this paper,the surface modification of boron nitride with γ-glycidyl ether oxypropyl trimethoxy-silane (KH560) was carried out,and the modified boron nitride (BN) was added to the epoxy natural rubber/natural rubber (ENR/NR) rubber matrix to prepare rubber composites.The mechanical properties,wet skid resistance,wear resistance and thermal conductivity were tested and analyzed.The results showed that boron nitride modification could significantly improve the interaction between filler and matrix,and enhance the wear resistance,wet skid resistance and thermal conductivity of rubber composites.

关键词

氮化硼 / 橡胶复合材料 / 表面改性

Key words

boron nitride / rubber composite / surface modification

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引用格式 ▾
改性氮化硼/环氧天然橡胶/天然橡胶复合材料的制备及性能研究[J]. 化工新型材料, 2025, 53(5): 140-145 DOI:10.19817/j.cnki.issn1006-3536.2025.05.033

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参考文献

[1] Wu J,Ling L,Xie J,et al.Surface modification of nanosilica with 3-mercaptopropyl trimethoxysilane:experimental and theoretical study on the surface interaction[J].Chemical Physics Letters,2014,591:227-232.
[2] Nazir M T,Phung B T,Yu S,et al.Effects of thermal properties on tracking and erosion resistance of micro-ATH/AlN/BN filled silicone rubber composites[J].IEEE Transactions on Dielectrics and Electrical Insulation,2018,25(6):2076-2085.
[3] Hosseini M R K,Razzaghi-Kashani M.Vulcanization kinetics of nano-silica filled styrene butadiene rubber[J].Polymer,2014,55(24):6426-6434.
[4] Charoenchai M,Tangbunsuk S,Keawwattana W.Silica-graphene oxide nanohybrids as reinforcing filler for natural rubber[J].Journal of Polymer Research,2020,27:230.
[5] 韩冬礼,杨嘉顺,刘毅,等.新型硅烷偶联剂IMLV在绿色轮胎胎面胶中的应用[J].橡胶工业,2022,69(10):764-768.
[6] 王梓轩,宋维晓,卢咏来,等.环氧化天然橡胶用作大分子界面改性剂的研究进展[J].橡胶工业,2022,69(6):474-479.
[7] 张丽洁.含可牺牲微区丁苯橡胶的制备及其强韧化机理研究[D].广州:华南理工大学,2020.
[8] Khongprom P,Phumnok E,Ratanawilai S.Preparation of natural rubber composites with high silica contents using a wet mixing process[J].ACS Omega,2022,7(10):8364-8376.
[9] 宋维晓,罗锦标,卢咏来,等.环氧化天然橡胶新型交联体系的研究进展[J].橡胶工业,2021,68(1):73-78.
[10] Xia Lijian,Song Jianhui,Wang Hui,et al.Silica nanoparticles reinforced natural rubber latex composites:the effects of silica dimension and polydispersity on performance[J].Journal of Applied Polymer Science,2019,136(18):47449.
[11] Payne A R.The dynamic properties of carbon black-loaded natural rubber vulcanizates.part Ⅰ[J].Journal of Applied Polymer Science,2010,6(19):57-63.
[12] 王润国,孙超英,安晓鹏,等.生物基弹性体的研究进展[J].橡胶工业,2023,70(9):675-685.
[13] Cunningham A,Anderew K R,Roberts A D.Short duration sliding contacts between elastomers and smooth rigid substrates:exploratory studies with an instrumented pendulum skid tester[J].Wear,1999,232(1):122-130.
[14] 王兵辉,王魁业,熊玉竹.有机湿法改性白炭黑对天然橡胶复合材料性能的影响[J].橡胶工业,2020,67(11):803-811.
[15] Ejsmont Jerzy A,Ronowski Grzegorz,Świeczko-Żurek Beata,et al.Road texture influence on tyre rolling resistance[J].Road Materials and Pavement Design:an International Journal,2017,18(1):181-198.
[16] Yan H,Sun K,Zhang Y,et al.Effects of silane coupling agents on the vulcanization characteristics of natural rubber[J].Journal of Applied Polymer Science,2010,94(4):1511-1518.

基金资助

贵州省科技计划项目(黔科合成果[2023]重大003)

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