为了解决汽车尾气造成的污染问题,采用掺填式和涂覆式制备沥青混合料试件,探讨在沥青混合料中掺杂或涂覆电气石-二氧化钛(TATi)复合材料对碳氢化合物、一氧化碳和氮氧化物这3种尾气降解效率及耐久性的影响,并对尾气降解型沥青混合料的路用性能进行评价。结果表明:制备掺填式沥青混合料选用质量分数50%的TATi复合材料替代矿粉经济实惠;选用质量分数3%的TATi溶液喷涂(刷涂)制备的涂覆式沥青混合料尾气降解效率较高;与掺填式和涂覆式沥青混合料相比,TATi掺杂量为3%(质量分数)的含砂雾封层涂覆式沥青混合料的尾气降解效率和耐久性最好;碾压后掺填式和涂覆式沥青混合料的尾气降解效率均有所降低,与掺填式沥青混合料相比,涂覆式沥青混合料尾气降解效率明显降低;掺杂TATi后掺填式和涂覆式沥青混合料均能满足路用性能。
To address pollution issues associated with automobile exhaust,asphalt mixture specimens were prepared utilizing filling and coating methods.This study investigated the effects of incorporating or coating tourmaline-titanium dioxide (TATi) composite materials into asphalt mixtures on the degradation efficiency and durability of hydrocarbons,carbon monoxide,and nitrogen oxides.Additionally,the road performance of these exhaust-degrading asphalt mixtures was evaluated.The results indicated that employing TATi composite material with a mass fraction of 50% as a substitute for mineral powder in the formulation of blended asphalt mixtures was economically feasible.Furthermore,the exhaust degradation efficiency of coated asphalt mixtures,prepared by spraying (brushing) a TATi solution with a mass fraction of 3%,was superior.Among the various mixtures,the sand mist seal coated asphalt mixture with a TATi doping content of 3% (by mass) exhibited the highest efficiency in exhaust degradation and durability.It was observed that the exhaust degradation efficiency of both mixed and coated asphalt mixtures decreased after rolling.Notably,the coated asphalt mixture exhibited a significant reduction in exhaust gas degradation efficiency compared to the mixed asphalt mixture.However,after doping with TATi,both filled and coated asphalt mixtures could meet the required road performance standards.
[1] Jia S W,Yan G L,Shen A Z.Traffic and emissions impact of the combination scenarios of air pollution charging fee and subsidy[J].Journal of Cleaner Production,2018,197:678-689.
[2] Zhao Y B,Gao P P,Yang W D,et al.Vehicle exhaust:an overstated cause of haze in China[J].Science of the Total Environment,2018,612:490-491.
[3] Shi G,Liu J,Wang H,et al.Source apportionment for fine particulate matter in a Chinese city using an improved gas-constrained method and comparison with multiple receptor models[J].Environmental Pollution,2018,233:1058-1067.
[4] 生态环境部.中国移动源环境管理年报(2023年)[J].环境保护,2024,52(2):48-62.
[5] 魏鹏.可降解汽车尾气的沥青混合料路面研究[D].哈尔滨:哈尔滨工业大学,2011.
[6] 王文广.二氧化钛基复合光催化材料的制备及其性能研究[D].武汉:武汉理工大学,2012.
[7] 刘浪,解伟,金娇,等.纳米TiO2基催化剂在环保功能路面应用的研究进展[J].中国材料进展,2020,39(1):78-83.
[8] 李文博.TiO2封层式催化分解尾气型沥青路面材料及其路用性能研究[D].乌鲁木齐:新疆大学,2018.
[9] 钱国平,王娜,周大垚.纳米TiO2基路面功能涂层降解NO试验研究[J].交通科学与工程,2016,32(1):29-32;38.
[10] 周君林,张云霞,彩雷洲,等.负载TiO2光催化剂对大孔隙沥青路面性能的影响[J].公路交通科技,2023,40(4):46-52.
[11] 严守靖,汪峰,迟凤霞,等.玻璃微珠-纳米TiO2复合材料汽车尾气降解效能研究[J].公路交通科技,2020,37(6):138-144.
[12] 严守靖,王洋洋,迟凤霞,等.空心玻璃微珠/纳米TiO2复合材料的制备与表征[J].浙江大学学报(工学版),2021,55(4):713-719.
[13] Leng Z,Yu H,Gao Z.Study on air-purifying performance of asphalt mixture specimens coated with titanium dioxide using different methods[J].International Journal of Pavement Research and Technology,2018,11:867-874.
[14] 李威睿,彭庚,伍燕华,等.可降解汽车尾气的沥青混合料开发及工程应用[J].硅酸盐通报,2021,40(4):1405-1412.
[15] Wang D,Leng Z,Hüben M,et al.Photocatalytic pavements with epoxy-bonded TiO2-containing spreading material[J].Construction and Building Materials,2016,107:44-51.
[16] Karapati S,Giannakopoulou T,Todorova N,et al.TiO2 functionalization for efficient NOx removal in photoactive cement[J].Applied Surface Science,2014,319:29-36.
[17] 刘方园,徐鲁艺,修阳,等.非金属元素掺杂纳米二氧化钛[J].化学通报,2021,84(2):108-119.
[18] 欧玉静,石俊青,赵丹,等.金属离子掺杂TiO2光催化剂及其表征技术的研究进展[J].功能材料,2021,52(2):2018-2024.
[19] 欧小雨,沈群,黎小芳,等.N掺杂TiO2纳米纤维光催化氧化NO[J].中南民族大学学报(自然科学版),2021,40(2):117-123.
基金资助
国家自然科学基金(51508150);河北省自然科学基金(E2022402050)