化工新型材料

化工新型材料 ›› 2025, Vol. 53 ›› Issue (4) : 157-164. DOI: 10.19817/j.cnki.issn1006-3536.2025.04.044

科学研究

聚多巴胺表面改性UHMWPE纤维及其界面性能研究

蒋干兵, 李露露, 陈天欢, 颜甜甜, 俞科静

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Surface modification of UHMWPE fibers with polydopamine and their interfacial properties

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Received		Published
2024-01-11		2025-04-20
Issue Date	Revised Date
2025-04-21	2024-01-11

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摘要

受天然贻贝蛋白粘附力的启发,通过简单的溶液浸渍在超高分子量聚乙烯(UHMWPE)纤维表面聚合一层聚多巴胺(PDA)涂层,工艺绿色环保简单高效,而且不损伤纤维本身力学性能。研究乙醇介导的溶剂效应、聚合时间对多巴胺聚合的影响,及多巴胺改性对纤维性能及复合材料界面性能的影响。结果表明:改性后PDA涂层涂覆在UHMWPE纤维表面,并引入了氨基和羟基基团;在40%乙醇溶液中改性,时间为24h效果较优,UHMWPE-40%乙醇/环氧树脂(UHMWPE-40%乙醇/EP)体系的粘接强度提高了57.7%;PDA改性24h的UHMWPE/EP的界面剪切强度(IFSS)提升了146.7%;PDA改性后UHMWPE/EP层压复合材料的ILSS提高了19.40%。

Abstract

In this paper,inspired by the adhesion of natural mussel proteins,a PDA coating was polymerized on the surface of UHMWPE fibers by simple solution impregnation,which was a green,simple and efficient process,and did not damage the mechanical properties of the fibers themselves.The ethanol-mediated solvent effect,the effect of polymerization time on the polymerization of dopamine,and the effect of dopamine modification on the fiber properties and the interfacial properties of the composites were investigated.The results showed that the modified PDA coating was successfully coated on the surface of UHMWPE fibers with the introduction of amino and hydroxyl groups.The modification in 40% ethanol solution for 24h was more effective,and the adhesive strength of the UHMWPE-40% ethanol/EP system was increased by 57.7%.The IFSS of the PDA-modified UHMWPE/EP for 24h was improved by 146.7%.ILSS of UHMWPE/EP laminated composites modified by PDA was improved by 19.40%.

关键词

聚多巴胺(PDA) / 超高分子量聚乙烯 / 表面改性 / 界面增强

Key words

polydopamine (PDA) / UHMWPE / surface modification / interface enhancement

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蒋干兵, 李露露, 陈天欢, 颜甜甜, 俞科静. 聚多巴胺表面改性UHMWPE纤维及其界面性能研究[J]. 化工新型材料, 2025, 53(4): 157-164 DOI:10.19817/j.cnki.issn1006-3536.2025.04.044

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] 顾超英,赵永霞.国内外超高分子量聚乙烯纤维的生产与应用[J].纺织导报,2010(4):52-55.
[2] 戚东涛,陶继志,王秀云.电晕处理对超高分子量聚乙烯纤维表面性能的影响[J].材料科学与工艺,2006(5):535-537,542.
[3] 李志,张炜,吴向阳,等.超高分子量聚乙烯纤维表面紫外接枝聚合改性研究[J].化工新型材料,2011,39(11):46-49.
[4] 冯霞,胡俊成,阿拉东.多巴胺仿生修饰及聚乙烯亚胺二次功能化表面改性超高分子量聚乙烯纤维[J].天津工业大学学报,2016,35(6):14-19.
[5] Wang Shicheng,Ma Jinyang,Feng Xia,et al.An effective surface modification of UHMWPE fiber for improving the interfacial adhesion of epoxy resin composites[J].Polymer Composites,2020,41(4):1614-1623.
[6] Lee H,Dellatore S M,Miller W M,et al.Mussel-inspired surface chemistry for multifunctional coatings[J].Science,2007,318(5849):426-430.
[7] Fang Z H,Tu Q Z,Chen Z Y.Biomimetic surface modification of UHMWPE fibers to enhance interfacial adhesion with rubber matrix via constructing polydopamine functionalization platform and then depositing zinc oxide nanoparticles[J].Surfaces and Interfaces,2022,29:101728.
[8] Wang K,Liu M,Song C,et al.Surface-conductive UHMWPE fibres via in situ reduction and deposition of graphene oxide[J].Materials & Design,2018,148:167-176.
[9] Lee W,Lee J U,Byun JH.Catecholamine polymers as surface modifiers for enhancing interfacial strength of fiber-reinforced composites[J].Composites Science and Technology,2015,110:53-61.
[10] Wang J,Liang G,Zhao W,et al.Studies on surface modification of UHMWPE fibers via UV initiated grafting[J].Applied Surface Science,2006,253(2):668-673.
[11] Cheng K,Li M,Zhang S,et al.Study on the structure and properties of functionalized fibers with dopamine[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,582:123846-123856.
[12] Hu J,Feng X,Liu Z,et al.Surface amine-functionalization of UHMWPE fiber by bio-inspired polydopamine and grafted hexamethylene diamine[J].Surface and Interface Analysis,2017,49(7):640-646.
[13] Bashiri Rezaie A,Liebscher M,Ranjbarian M,et al.Enhancing the interfacial bonding between PE fibers and cementitious matrices through polydopamine surface modification[J].Composites Part B:Engineering,2021,217:108817-108828.