Silver phosphate,as an ideal photocatalytic material,exhibits extremely high photocatalytic activity in the degradation of ammonia nitrogen in water.Ag3PO4 semiconductor materials were prepared using three methods: egg membrane method,direct precipitation method,and hydrothermal synthesis.The crystal structure and properties of Ag3PO4 were analyzed using X-ray diffraction,scanning electron microscopy,and UV visible spectrophotometer.Photocatalytic degradation experiments were conducted on ammonia nitrogen solution and Rhodamine B dye.The results indicated that the Ag3PO4-Z crystal prepared by direct precipitation method had the best photocatalytic activity among the three methods.The exposure degree of its silver phosphate (110) crystal surface was relatively high,and the oxidation ability of photogenerated electrons generated was stronger.At the same time,the nanoparticle size was smaller,the specific surface area was larger,and it could adsorb more pollutants,which was more conducive to the photocatalytic process.Therefore,by controlling the preparation conditions,the morphology and crystal structure of Ag3PO4 photocatalysts could be regulated,providing valuable insights for promoting the application in industrial wastewater treatment.
[1] 肖力光,骆婉侠.磷酸银光催化剂改性及应用研究进展[J].化工新型材料,2024,52(8):241-246.
[2] 王鹏,申佳锟,陆银辉,等.石墨相氮化碳/MXene/磷酸银/聚丙烯腈复合纳米纤维膜的制备及其光催化性能[J].纺织学报,2023,44(12):10-16.
[3] 童设华,聂金林,林燕,等.铁氮共掺杂碳材料改性磷酸银复合光催化剂对四环素的催化降解性能与机制[J].环境科学学报,2023,44(7):57-68.
[4] 宋萃,赵丽华,戚明颖,等.水热法制备Ag3PO4/HAP复合光催化剂及其光催化性能[J].无机化学学报,2020,36(3):521-528.
[5] 黄淑云,王敏,熊望荣,等.Ag3PO4/SnO2异质结催化剂对罗丹明B的光催化降解性能研究[J].当代化工,2023,55(11):2678-2684.
[6] 樊苗苗,樊国栋,田海莹.高效磷酸银/碳球复合光催化剂的制备及可见光催化性能研究[J].现代化工,2024,44(7):205-211.
[7] 罗嘉宏,张刚,史伟.AgBr/Ag3PO4复合材料可见光催化去除无机废水中的氨氮[J].华南师范大学学报(自然科学版),2023,55(5):65-71.
[8] 李俊生,徐嘉伦,王学峰,等.光催化氧化技术处理氨氮废水的研究进展[J].应用化工,2022,51(7):2154-2159.
[9] 苏骑,王群,贾伟科,等.MIL-125(Ti)衍生的介孔圆盘状TiO2/C高效光催化降解罗丹明B研究[J].化工新型材料,2024,52(5):234-240.
[10] 樊佳炜,武海霞,陈卫刚.氨氮废水的高级氧化处理技术研究进展[J].南京工业大学学报(自然科学版),2020,42(2):142-151.
[11] 郑林,曲盛泽,黄晶晶,等.C60/Ag3PO4复合材料制备及光降解罗丹明B的研究[J].广东化工,2023,50(21):13-15.
[12] 苏琼,张博文,张平,等.新型光催化剂磷酸银的研究进展[J].环境化学,2024,43(5):1531-1544.
[13] Amirulsyafiee Amiezatul,Khan Mohammad Mansoob,Harunsani Mohammad Hilni.Ag3PO4 and Ag3PO4-based visible light active photocatalysts:recentprogress,synthesis,and photocatalytic applications[J].Catalysis Communications,2022,172:106556.
[14] 邓军阳,聂龙辉,汪杰,等.磷酸银光催化剂制备与催化性能研究进展[J].硅酸盐学报,2019,47(7):1023-1032.
[15] 汤隽祎,王宏杰,赵子龙,等.还原氧化石墨烯/磷酸银光催化剂制备及其对卡马西平的降解[J].环境工程学报,2019,13(6):1314-1321.
[16] 汤春妮石墨相氮化碳/磷酸银复合光催化剂的研究进展[J].当代化工,2020,49(6):1090-1098.
[17] 唐建可,马春蕾,薛彦峰.Ag3PO4/BiOI复合材料的制备及其光催化性能研究[J].化工新型材料,2024,52(9):195-200.
[18] 吴福礼,李兵,黄有鹏,等.Ag3PO4/MoS2复合材料的制备及其光催化性能研究[J].化工新型材料,2021,49(9):202-207.
[19] 陶萍芳,秦荣欢,岑佳龙,等.稀土离子掺杂Ag3PO4的水热合成及其催化性能研究[J].化工新型材料,2020,48(8):213-218.
[20] 张小芳,王盼,郭世巧,等.g-C3N4/Ag3PO4复合催化剂的制备及其可见光降解罗丹明B和亚甲基蓝[J].化工新型材料,2021,49(9):271-275.
[21] 马金玲,牛晓君,王杰,等.菱形十二面体磷酸银的制备及其可见光催化性能研究[J].化工新型材料,2017,45(7):104-106.
[22] Bi Yingpu,Ouyang Shuxin,Umezawa Naoto,et al.Facet effect of single-crystalline Ag3PO4 sub-microcrystals on photocatalytic properties[J].Journal of the American Chemical Society,2011,133(17):6490-6492.
[23] Zheng Binjie,Wang Xue,Liu Chang,et al.High-efficiently visible light-responsive photocatalysts:Ag3PO4 tetrahedral microcrystals with exposed {111} facets of high surface energy[J].Journal of Materials Chemistry A,2013,1(40):12635-12640.
[24] 沈阳市环境监测中心站.HJ 536—2009.水质氨氮的测定水杨酸分光光度法[S].北京:中国环境科学出版社,2010:1-4.
[25] Chai Bo,Li Jing,Xu Qian.Reduced graphene oxide grafted Ag3PO4 composites with efficient photocatalytic activity under visible-light irradiation[J].Industrial & Engineering Chemistry Research,2014,53(21):8744-8752.
[26] 林燕.磷酸银基光催化剂的活性调控及其对水中有机污染物的催化降解性能及机理研究[D].长沙:湖南大学,2021.
[27] Xu Yangsen,Zhang Weide.Morphology-controlled synthesis of Ag3PO4 microcrystals for high performance photocatalysis[J].CrystEngComm,2013,15(27):5407-5411.
[28] Zhang Weiping,Li Guiying,Wang Wanjun,et al.Enhanced photocatalytic mechanism of Ag3PO4 nano-sheets using MS2(M=Mo,W)/rGO hybrids as co-catalysts for 4-nitrophenol degradation in water[J].Applied Catalysis B:Environment and Energy,2018,232:11-18.
[29] Wang Hua,He Liang,Wang Lihua,et al.Facile synthesis of Ag3PO4 tetrapod microcrystals with an increased percentage of exposed {110} facets and highly efficient photocatalytic properties[J].CrystEngComm,2012,14(24):8342-8344.
[30] Cai Tao,Liu Yutang,Wang Longlu,et al.Silver phosphate-based Z-Scheme photocatalytic system with superior sunlight photocatalytic activities and anti-photocorrosion performance[J].Applied Catalysis B:Environment and Energy,2017,208:1-13.
[31] 段毅Ag3PO4和g-C3N4基光催化剂的制备及可见光降解典型药物的研究[D].长沙:湖南大学,2020.
[32] Zhang Mingyi,Shao Changlu,Mu Jingbo,et al.One-dimensional Bi2MoO6/TiO2 hierarchical heterostructures with enhanced photocatalytic activity[J].CrystEngComm,2011,14(2):605-612.
基金资助
2023年度中国建设教育协会教育教学科研重点课题项目(2023054);上海市职业教育协会课题项目(YB202409);上海交通职业技术学院校级科研创新团队项目(2024T01)