碳点荧光增强及重金属离子传感应用

雷晨阳1,2, 王黎1,2*, 陶强强1,2, 任壮1,2, 张爱心1,2, 郭仕超1,2

化工新型材料 ›› 2025, Vol. 53 ›› Issue (3) : 13 -16.

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化工新型材料 ›› 2025, Vol. 53 ›› Issue (3) : 13-16. DOI: 10.19817/j.cnki.issn1006-3536.2025.03.046
综述与专论

碳点荧光增强及重金属离子传感应用

    雷晨阳1,2, 王黎1,2*, 陶强强1,2, 任壮1,2, 张爱心1,2, 郭仕超1,2
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Fluorescence enhancement of carbon dots and applications of heavy metal ions sensing

  • Lei Chenyang1,2, Wang Li1,2, Tao Qiangqiang1,2, Ren Zhuang1,2, Zhang Aixin1,2, Guo Shichao1,2
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摘要

介绍了元素掺杂和表面钝化两种碳点的荧光增强途径,以改善原始碳点存在的荧光量子产率低、发光纯度低以及蓝绿区集中的发射等缺陷。同时,对碳点在重金属离子传感应用及发展进行了展望。

Abstract

Two fluorescence enhancement methods for carbon dots,elemental doping and surface passivation,were elaborated to improve the defects of pristine fluorescent dots,such as low fluorescence quantum yield,low luminescence purity,and emission concentrated in the blue-green region.By the way,the application and development of carbon dots in heavy metal ions sensing were prospected.

关键词

碳点 / 元素掺杂 / 表面钝化 / 重金属离子

Key words

carbon dots / element doping / surface passivation / heavy metal ions

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碳点荧光增强及重金属离子传感应用[J]. 化工新型材料, 2025, 53(3): 13-16 DOI:10.19817/j.cnki.issn1006-3536.2025.03.046

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参考文献

[1] 孙博思,赵丽娇,任婷,等.水环境中重金属检测方法研究进展[J].环境科学与技术,2012,35(7):157-162,174.
[2] Sohrabi H,Hemmati A,Majidi M R,et al.Recent advances on portable sensing and biosensing assays applied for detection of main chemical and biological pollutant agents in water samples:a critical review[J].Trends in Analytical Chemistry,2021,143:116344.
[3] Xu X,Ray R,Gu Y,et al.Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments[J].Journal of the American Chemistry Socciety,2004,126(40):12736-12737.
[4] Gao X,Du C,Zhuang Z,et al.Carbon quantum dot-based nanoprobes for metal ion detection[J].Journal of Materials Chemistry C,2016,4(29):6927-6945.
[5] Zhu S,Song Y,Zhao X,et al.The photoluminescence mechanism in carbon dots (graphene quantum dots,carbon nanodots,and polymer dots):current state and future perspective[J].Nano Research,2015,8(2):355-381.
[6] Đorđević L,Arcudi F,Cacioppo M,et al.A multifunctional chemical toolbox to engineer carbon dots for biomedical and energy applications[J].Nature Nanotechnology,2022,17(2):112-130.
[7] Pan L,Sun S,Zhang A,et al.Truly fluorescent excitation-dependent carbon dots and their applications in multicolor cellular imaging and multidimensional sensing[J].Advanced Materials,2015,27(47):7782-7787.
[8] Ding H,Wei J S,Zhang P,et al.Solvent-controlled synthesis of highly luminescent carbon dots with a wide color gamut and narrowed emission peak widths[J].Small,2018,14(22):1800612.
[9] Radhakrishnan K,Panneerselvam P,Marieeswaran M.A green synthetic route for the surface-passivation of carbon dots as an effective multifunctional fluorescent sensor for the recognition and detection of toxic metal ions from aqueous solution[J].Analytical Methods,2019,11(4):490-506.
[10] Zhang Q,Wang R Y,Feng B W,et al.Photoluminescence mechanism of carbon dots:triggering high-color-purity red fluorescence emission through edge amino protonation[J].Nature Communications,2021,12(1):6856.
[11] Ansari L,Hallaj S,Hallaj T,et al.Doped-carbon dots:recent advances in their biosensing,bioimaging and therapy applications[J].Colloids and Surface B-Biointerfaces,2021,203:111743.
[12] Li L,Dong T.Photoluminescence tuning in carbon dots:surface passivation or/and functionalization,heteroatom doping[J].Journal of Materials Chemistry C,2018,6(30):7944-7970.
[13] Lin Z,Yang J,Zeng Q,et al.Deep blue photoluminescence and optical gain from sodium-doped carbon dots[J].Journal of Luminescence,2022,246:118856.
[14] Anh N T N,Chowdhury A D,Doong R A.Highly sensitive and selective detection of mercury ions using N,S-codoped graphene quantum dots and its paper strip based sensing application in wastewater[J].Sensors and Actuators B:Chemical,2017,252:1169-1178.
[15] Zhang R,Chen W.Nitrogen-doped carbon quantum dots:facile synthesis and application as a “turn-off” fluorescent probe for detection of Hg2+ ions[J].Biosensors and Bioelectronics,2014,55:83-90.
[16] Sheng L,Huangfu B,Xu Q,et al.A highly selective and sensitive fluorescent probe for detecting Cr(Ⅵ) and cell imaging based on nitrogen-doped graphene quantum dots[J].Journal of Alloys and Compounds,2020,820:153191.
[17] Atchudan R,Edison T N J I,Perumal S,et al.Hydrophilic nitrogen-doped carbon dots from biowaste using dwarf banana peel for environmental and biological applications[J].Fuel,2020,275:117821.
[18] Gonzalez-gonzalez R B,Morales-murillo M B,Martinez-prado M A,et al.Carbon dots-based nanomaterials for fluorescent sensing of toxic elements in environmental samples:strategies for enhanced performance[J].Chemosphere,2022,300:134515.
[19] Kamali S R,Chen C N,Agrawal D C,et al.Sulfur-doped carbon dots synthesis under microwave irradiation as turn-off fluorescent sensor for Cr(Ⅲ)[J].Journal of Analytical Science and Technology,2021,12(1):48.
[20] Xu Q,Pu P,Zhao J,et al.Preparation of highly photoluminescent sulfur-doped carbon dots for Fe(Ⅲ) detection[J].Journal of Materials Chemistry A,2015,3(2):542-546.
[21] Kalaiyarasan G,Joseph J,Kumar P.Phosphorus-doped carbon quantum dots as fluorometric probes for iron detection[J].ACS Omega,2020,5(35):22278-22288.
[22] Lin L,Wang Y,Xiao Y,et al.Hydrothermal synthesis of carbon dots codoped with nitrogen and phosphorus as a turn-on fluorescent probe for cadmium(Ⅱ)[J].Mikrochim Acta,2019,186(3):147.
[23] Bourlinos A B,Trivizas G,Karakassides M A,et al.Green and simple route toward boron doped carbon dots with significantly enhanced non-linear optical properties[J].Carbon,2015,83:173-179.
[24] Jia M,Peng L,Yang M,et al.Carbon dots with dual emission:a versatile sensing platform for rapid assay of Cr(Ⅵ)[J].Carbon,2021,182:42-50.
[25] Ye Q,Yan F,Shi D,et al.N,B-doped carbon dots as a sensitive fluorescence probe for Hg2+ ions and 2,4,6-trinitrophenol detection for bioimaging[J].Journal of Photochemistry and Photobiology B:Biology,2016,162:1-13.
[26] Bandi R,Dadigala R,Gangapuram B R,et al.Green synthesis of highly fluorescent nitrogen-doped carbon dots from lantana camara berries for effective detection of lead(Ⅱ) and bioimaging[J].Journal of Photochemistry and Photobiology B:Biology,2018,178:330-338.
[27] Gupta A,Chaudhary A,Mehta P,et al.Nitrogen-doped,thiol-functionalized carbon dots for ultrasensitive Hg(Ⅱ) detection[J].Chemistry Communications,2015,51(53):10750-10753.
[28] Shen J,Zhu Y,Chen C,et al.Facile preparation and upconversion luminescence of graphene quantum dots[J].Chemical Communications,2011,47(9):2580-2582.
[29] Teng X,Ma C,Ge C,et al.Green synthesis of nitrogen-doped carbon dots from konjac flour with “off-on” fluorescence by Fe3+ and l-lysine for bioimaging[J].Journal of Materials Chemistry B,2014,2(29):4631-4639.
[30] Guan L,Wang W,Zhang X,et al.Functionalized green carbon dots for specific detection of copper in human serum samples and living cells[J].Journal of Fluorescence,2024,DOI:10.1007/s10895-024-03586-z.
[31] Pappalardo J S,Macairan J R,Macina A,et al.Effects of polydopamine-passivation on the optical properties of carbon dots and its potential use in vivo[J].Physical Chemistry Chemical Physics,2020,22(29):16595-16605.
[32] Perikala M,Bhardwaj A.Engineering photo-luminescent centers of carbon dots to achieve higher quantum yields[J].ACS Applied Electronic Materials,2020,2(8):2470-2478.
[33] Wang H,Yang L,Chu S,et al.Semiquantitative visual detection of lead ions with a smartphone via a colorimetric paper-based analytical device[J].Analytical Chemistry,2019,91(14):9292-9299.
[34] Zhai X,Zhang P,Liu C,et al.Highly luminescent carbon nanodots by microwave-assisted pyrolysis[J].Chemistry Communications,2012,48(64):7955-7957.
[35] Liu C,Zhang P,Tian F,et al.One-step synthesis of surface passivated carbon nanodots by microwave assisted pyrolysis for enhanced multicolor photoluminescence and bioimaging[J].Journal of Materials Chemistry,2011,21(35):13163-13167.
[36] Huang G,Luo X,Lin W,et al.Carbon dots based multicolor fluorescence sensor for ratiometric and colorimetric dual-model detection of Cu2+[J].Dyes and Pigments,2022,203:110381.

基金资助

湖北省重点研发计划项目(2021BCD002);湖北省重大技术创新项目(2019ACA152)

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