植物基磁性复合材料是将磁性纳米粒子与植物基原料相结合的复合材料,具有可持续性、经济性、环境友好性、能够与污染物相互作用的表面活性位点的多功能性,以及易于从水介质中磁分离的优势。综述了植物基磁性复合材料的种类、制备方法及对染料的吸附性能;概述了植物基磁性复合材料对于染料的吸附等温线模型、吸附动力学模型的分析结果;阐述了植物基磁性复合材料对染料的吸附机理。在合成工艺、系统评估环境风险和工业化应用需解决的问题等方面提出了进一步深入研究的建议。
Plant-based magnetic materials are composite materials that combine magnetic nanoparticles with plant-based raw materials.They have the advantages of sustainability,economy,environmental friendliness,multifunctionality of surface active sites capable of interacting with pollutants,and easy magnetic separation from aqueous media.The types,preparation methods,and adsorption properties of plant-based magnetic materials for dyes were reviewed.The adsorption isotherm model,adsorption kinetics model and adsorption mechanisms of plant-based magnetic materials for dyes were summarized.Recommendations for further research were proposed in the synthesis process,the systematic assessment of environmental risks,and the challenges that need to be solved in industrial applications.
[1] Yadav S,Yadav A,Bagotia,et al.Adsorptive potential of mo-dified plant-based adsorbents for sequestration of dyes and heavy metals from wastewater-a review[J].Journal of Water Process Engineering,2021,42:102148.
[2] Sharma A,Mangla D,Shehnaz,et al.Recent advances in magnetic composites as adsorbents for wastewater remediation[J].Journal of Environmental Management,2022,306:114483.
[3] Tee G T,Gok X Y,Yong W F.Adsorption of pollutants in wastewater via biosorbents,nanoparticles and magnetic biosorbents:a review[J].Environmental Researchm,2022,212:113248.
[4] Safarik I,Baldikova E,Prochazkova J,et al.Magnetically mo-dified agricultural and food waste:preparation and application[J].Journal of Agricultural and Food Chemistry,2018,66:2538-2552.
[5] 郑君里,罗相萍,陈凯伟,等.农林材料及其改性材料对水中重金属和染料吸附研究进展[J].水处理技术,2022,4(4):6-10.
[6] Osman A I,El-Monaem E M A,Elgarahy A,et al.Methods to prepare biosorbents and magnetic sorbents for water treatment:a review[J].Environmental Chemistry Letters,2023,21:2337-2398.
[7] Hassan N A,Wong S,Ngadi N,et al.Surface functionalization of cellulose with polyethyleneimine and magnetic nanoparticles for efficient removal of anionic dye in wastewater[J].Journal of Environmental Chemical Engineering,2020,9(1):104639.
[8] Toledo-Jaldin H P,Sanchsz-Mendieta V,Blanco-Flores A,et al.Low-cost sugarcane bagasse and peanut shell magnetic-composites applied in the removal of carbofuran and iprodione pesticides[J].Environmental Science and Pollution Research,2020,27(6):7872-7885.
[9] 甘文涛.仿生构建木基磁性材料[D].哈尔滨:东北林业大学,2019.
[10] Safarik I,Prochazkov J,Baldikova E,et al.Modification of diamagnetic materials using magnetic fluids[J].Ukrainian Journal of Physics,2020,65(9):655-661.
[11] Buthiyappan A,Gopalan J,Raman A A A.Synthesis of iron oxides impregnated green adsorbent from sugarcane bagasse:characterization and evaluation of adsorption efficiency[J].Journal of Environmental Management,2019,249:109323.
[12] Çatlioğlu F,Akay S,Turunç E,et al.Preparation and application of Fe-modified banana peel in the adsorption of methy-lene blue:process optimization using response surface methodology[J].Environmental Nanotechnology,Monitoring & Management,2021,16:100517.
[13] Pooladi H,Foroutan R,Esmaeili H,et al.Synthesis of wheat bran sawdust/Fe3O4 composite for the removal of methylene blue and methyl violet[J].Environmental Monitoring Assessment,2021,193:276.
[14] 龚新怀,辛梅华,李明春,等.磁性响应茶渣制备及其对水溶液中亚甲基蓝的吸附[J].化工进展,2019,38(2):1113-1121.
[15] 邵俊,郭丰艳,桑蓉栎,等.Fe3O4@CG磁性吸附材料对水中染料的吸附特性研究[J].化学试剂,2020,42(11):1287-1293.
[16] Mashkoor F,Nasar A.Magnetized tectona grandis sawdust as a novel adsorbent:preparation,characterization,and utilization for the removal of methylene blue from aqueous solution[J].Cellulose,2020,7(5):2613-2635.
[17] 任希华,贾悦,陈华艳,等.磁性荷叶吸附剂的制备及其对亚甲基蓝的吸附[J].应用化工,2022,51(10):2849-2854.
[18] 廖云开,李林璇,范世锁.秸秆及磁性秸秆吸附剂对废水中亚甲基蓝的去除行为及机理[J].环境科学学报,2019,9(2):359-370.
[19] Munagapati V S,Wen H Y,Gollakota A R K,et al.Magnetic Fe3O4 nanoparticles loaded papaya (Carica papaya L.) seed powder as an effective and recyclable adsorbent material for the separation of anionic azo dye (Congo Red) from liquid phase:evaluation of adsorption properties[J].Journal of Molecular Liquids,2022,345:118255.
[20] Zafar L,Khan A,Kamran U,et al.Eucalyptus (camaldulensis) bark-based composites for efficient basic blue 41 dye biosorption from aqueous stream:kinetics,isothermal,and thermodynamic studies[J].Surfaces and Interfaces,2022,31:101897.
[21] Choudhry A,Sharma A,Khan T A,et al.Flax seeds based magnetic hybrid nanocomposite:an advance and sustainable material for water cleansing[J].Journal of Water Process Engineering,2021,42:102150.
[22] Kumbhar P,Narale D,Bhosale R,et al.Synthesis of tea waste/Fe3O4 magnetic composite (TWMC) for efficient adsorption of crystal violet dye:isotherm,kinetic and thermodynamic studies[J].Journal of Environmental Chemical Engineering,2022,10:107893.
[23] 袁丹.苦草废弃生物质基磁性颗粒/成型多孔炭球的制备及吸附性能研究[D].南宁:广西大学,2018.
[24] Khan M A,Otero M,Kazi M,et al.Unary and binary adsorption studies of lead and malachite green onto a nanomagnetic copper ferrite/drumstick pod biomass composite[J].Journal of Hazardous Materials,2019,365:759-770.
[25] Phouthavong V,Yan R,Nijpanich S,et al.Magnetic adsorbents for wastewater treatment:advancements in their synthesis methods[J].Materials,2022,15:1053.
[26] Maksoud I A A,Elgahy A M,Farrell C,et al.Insight on water remediation application using magnetic nanomaterials and biosorbents[J].Coordination Chemistry Reviews,2020,403:213096.
[27] Zheng H,Qi J,Jiang R,et al.Adsorption of malachite green by magnetic litchi pericarps:a response surface methodology investigation[J].Journal of Environmental Management,2015,162:232-239.
[28] Tara N,Abomuti M A,Alahareef F M,et al.Nigella sativa-manganese ferrite-reduced graphene oxide-based nanomaterial:a novel adsorbent for water treatment[J].Molecules,2023,28:5007.
[29] Aryee A A,Dovi E,Li Q,et al.Magnetic biocomposite based on peanut husk for adsorption of hexavalent chromium,congo red and phosphate from solution:characterization,kinetics,equilibrium,mechanism and antibacterial studies[J].Chemosphere,2022,87:132030.
[30] Aryee A A,Dovi E,Han R,et al.One novel composite based on functionalized magnetic peanut husk as adsorbent for efficient sequestration of phosphate and congo red from solution:characterization,equilibrium,kinetic and mechanism studies[J].Journal of Colloid and Interface Science,2021,598:69-82.
[31] 龚新怀,李明春,杨坤,等.纳米Fe3O4@茶渣/海藻酸钙磁性复合材料制备及其对亚甲基蓝的吸附性能与吸附机制[J].复合材料学报,2021,38(2):424-438.
[32] 王通,龚琪纪,米鹏东,等.聚多巴胺改性磁性悬铃木果毛纤维吸附染料废水性能研究[J].化工新型材料,2023,51(11):190-196;200.
[33] Mallakpour S,Sitous F,Dinari M,et al.Bio-sorbent alginate/citric acid-sawdust/Fe3O4 nanocomposite beads for highly efficient removal of malachite green from water[J].International Journal of Biological Macromolecules,2022,22:2683-2696.
[34] Jabeen A,Bhatti H N.Adsorptive removal of reactive green 5 (RG-5) and direct yellow 50 (DY-50) from simulated wastewater by Mangifera indica seed shell and its magnetic composite:Batch and column study[J].Environmental Technology & Innovation,2021,23:101685.
[35] Khan T A,Nazir M.Enhanced adsorptive removal of a model acid dye bromothymol blue-magnetic chitosan-bamboo sawdust composite:batch and column studie[J].Environmental Progress & Sustainable Energy,2015,34(5):1444-1454.
[36] Liu S,Ge H,Cheng S,et al.Green synthesis of magnetic 3D bio-adsorbent by corn straw core and chitosan for methylene blue removal[J].Environmental Technology,2020,41(16):2109-2121.
[37] Idowu A A,Asamu A J,Abidemi I M,et al.Magnetic tuned sorghum husk biosorbent for effective removal of cationic dyes from aqueous solution:isotherm,kinetics,thermodyna-mics and optimization studies[J].Applied Water Science,2019,9(7):160-176.
[38] Ge H,Wang C,Liu S,et al.Synthesis of citric acid functiona-lized magnetic graphene oxide coated corn straw for methylene blue adsorption[J].Bioresource Technology,2016,221:419-429.
[39] Siddiqui S L,Zohra F,Chaudhry S A.Nigella sativa seed based nanohybrid composite-Fe2O3-SnO2/BC:a novel material for enhanced adsorptive removal of methylene blue from water[J].Environmental Research,2019,178:108667.
[40] 何佩霖.磁性油菜籽荚对水中孔雀石绿与亚甲基蓝的吸附作用及机理[D].成都:成都医学院,2022.
基金资助
黑龙江省省属本科高校基本科研业务费科研项目(145209140)