在化石燃料日益枯竭,环境问题日趋严峻的背景下,环境和能源问题已成为人类社会未来发展的重要聚焦点,储能问题成为了战略性问题。水系锌离子电池(ZIBs)具有比容量高、成本低、安全性高、环境友好等优点,但存在枝晶生长、腐蚀钝化、析氢反应等问题,因而限制了ZIBs的实际应用与大规模商业化发展。简要介绍了ZIBs的发展历程和储能机理,总结归纳了锌负极存在的问题与形成原因,综述了锌负极的改性方法并展望了其未来研究发展方向。
In the context of the increasingly depleting fossil fuels and increasingly severe environmental problems,environmental and energy issues have become important focus areas for the future development of human society,and energy storage has emerged as a strategic issue.Aqueous zinc-ion batteries(ZIBs) have the advantages of high specific capacity,low cost,high safety and environmental friendliness,but there are some problems such as dendrite growth,corrosion and passivation,hydrogen evolution reaction,thus limiting the practical application and large-scale commercial development of ZIBs.The development history and energy storage mechanism of ZIBs were briefly introduced,the existing problems and reasons of zinc anodes were summarized,the modification methods of zinc anodes were reviewed,and the future research direction was prospected.
[1] Xiong Y,Li Q,Luo K ,et al.Low cost carboxymethyl cellulose additive toward stable zinc anodes in aqueous zinc ion battery[J].Journal of Energy Storage,2023,68:107655.
[2] Guo N,Huo W,Dong X,et al.A review on 3D zinc anodes for zinc ion batteries[J].Small Methods,2022,6(9):2200597.
[3] Yuksel R,Buyukcakir O,Seong W K,et al.Metal-organic framework integrated anodes for aqueous zinc-ion batteries[J].Advanced Energy Materials,2020,10(16):1904215.
[4] 黄彬,周锦林,顾洪旭,等.MOF-5衍生碳作为水系锌离子复合电容器正极储能性能研究[J].齐鲁工业大学学报,2020,34(4):9-12.
[5] 衡永丽,谷振一,郭晋芝,等.水系锌离子电池用钒基正极材料的研究进展[J].物理化学学报,2021,37(3):200501.
[6] Zhang X,Hu J P,Fu N,et al.Comprehensive review on zinc-ion battery anode:challenges and strategies[J].InfoMat,2022,4(7):12306.
[7] Zhao Z,Jing Z,Guo X,et al.Trace amounts of fluorinated surfactant additives enable high performance zinc-ion batteries[J].Energy Storage Materials,2022,53:638-645.
[8] Li C,Jin S,Archer L A,et al.Toward practical aqueous zinc-ion batteries for electrochemical energy storage[J].Joule,2022,6(8):1733-1738.
[9] Wang Z,Dong L,Huang W,et al.Simultaneously regulating uniform Zn2+ flux and electron conduction by MOF/rGO interlayers for high-performance Zn anodes[J].Nano-Micro Letters,2021,13:73.
[10] Hao Y,Feng D,Hou L,et al.Gel electrolyte constructing Zn (002) deposition crystal plane toward highly stable Zn anode[J].Advanced Science,2022,9(7):2104832.
[11] Tang B,Shan L,Liang S,et al.Issues and opportunities facing aqueous zinc-ion batteries[J].Energy & Environmental Science,2019,12(11):3288-3304.
[12] Chen H,Dai C,Xiao F,et al.Reunderstanding the reaction mechanism of aqueous Zn-Mn batteries with sulfate electrolytes:role of the zinc sulfate hydroxide[J].Advanced Materials,2022,34(15):2109092.
[13] Liang X,Zou X,Ren X,et al.Ultrathin nickel manganese nanosheets with rich oxygen-vacancy as a durability electrode for aqueous Ni//Zn batteries[J].Journal of Colloid and Interface Science,2020,578:677-684.
[14] 姬慧敏,谢春霖,张旗,等.水系锌离子电池负极集流体关键问题及设计策略[J].化学学报,2023,81(1):29-41.
[15] 吴凯.水系锌离子电池锌负极/电解液界面的稳定性调控及机理研究[D].上海:上海大学,2022.
[16] 王心怡,李维杰,韩朝,等.水系锌离子电池金属负极的挑战与优化策略[J].储能科学与技术,2022,11(4):1211-1225.
[17] Wang D,Li Q,Zhao Y,et al.Insight on organic molecules in aqueous Zn-ion batteries with an emphasis on the Zn anode regulation[J].Advanced Energy Materials,2022,12(9):2102707.
[18] Liu Y,Hu J,Lu Q,et al.Highly enhanced reversibility of a Zn anode by in-situ texturing[J].Energy Storage Materials,2022,47:98-104.
[19] Zhou J,Zhang R,Xu R,et al.Super-assembled hierarchical cellulose aerogel-gelatin solid electrolyte for implantable and biodegradable zinc ion battery[J].Advanced Functional Materials,2022,32(21):2111406.
[20] Wang J,Zhang B,Cai Z,et al.Stable interphase chemistry of textured Zn anode for rechargeable aqueous batteries[J].Science Bulletin,2022,67(7):716-724.
[21] Wen L,Qiwen Z,Huaming Y,et al.Metallic particles-induced surface reconstruction enabling highly durable zinc metal anode[J].Advanced Functional Materials,2023,33(38):2302661.
[22] Kim Y,Park Y,Kim M,et al.Corrosion as the origin of limi-ted lifetime of vanadium oxide-based aqueous zinc ion batteries[J].Nature Communication,2022,13(1):2371.
[23] Zhou W,Chen M,Tian Q,et al.Cotton-derived cellulose film as a dendrite-inhibiting separator to stabilize the zinc metal anode of aqueous zinc ion batteries[J].Energy Storage Materials,2022,44:57-65.
[24] Li H,Guo C,Zhang T,et al.Hierarchical confinement effect with zincophilic and spatial traps stabilized Zn-based aqueous battery[J].Nano Letters,2022,22(10):4223-4231.
[25] Wang T,Yao K,Li K,et al.Influence of MXene-assisted multifunctional interface on zinc deposition toward highly reversible dendrite-free zinc anodes[J].Energy Storage Materials,2023,62:102921.
[26] Li Z,Liao Y,Wang Y,et al.A co-solvent in aqueous electrolyte towards ultralong-life rechargeable zinc-ion batteries[J].Energy Storage Materials,2023,56:174-182.
[27] Zhang Y,Zheng X,Wang N,et al.Anode optimization strategies for aqueous zinc-ion batteries[J].Chemical Science,2022,13:14246-14263.
[28] Bayaguud A,Fu Y,Zhu C.Interfacial parasitic reactions of zinc anodes in zinc ion batteries:underestimated corrosion and hydrogen evolution reactions and their suppression strategies[J].Journal of Energy Chemistry,2022,64:246-262.
[29] So S,Ahn Y N,Jaewook K,et al.Uniform and oriented zinc deposition induced by artificial Nb2O5 layer for highly reversible Zn anode in aqueous zinc ion batteries[J].Energy Storage Materials,2022,52:40-51.
[30] Guo W,Cong Z,Guo Z,et al.Dendrite-free Zn anode with dual channel 3D porous frameworks for rechargeable Zn batteries[J].Energy Storage Materials,2020,30:104-112.
[31] Kang Z,Wu C,Dong L,et al.3D porous copper skeleton supported zinc anode toward high capacity and long cycle life zinc ion batteries[J].ACS Sustainable Chemistry & Engineering,2019,3:3364-3371.
[32] Qi Z,Xiong T,Chen T,et al.Dendrite-free anodes enabled by a composite of a ZnAl alloy with a copper mesh for high-performing aqueous zinc-ion batteries[J].ACS Applied Materials & Interfaces,2021,13(24):28129-28139.
[33] Zhang Y,Yang X,Hu Y,et al.Highly strengthened and toughened Zn-Li-Mn alloys as long-cycling life and dendrite-free Zn anode for aqueous zinc-ion batteries[J].Small,2022,18(17):2200787.
[34] Tao H,Tong X,Gan L,et al.Effect of adding various carbon additives to porous zinc anode in rechargeable hybrid aqueous battery[J].Journal of Alloys and Compounds,2016,658:119-124.
[35] Kang L,Cui M,Jiang F,et al.Nanoporous CaCO3 coatings enabled uniform Zn stripping/plating for long-life zinc rechargeable aqueous batteries[J].Advanced Energy Materials,2018,8(25):1801090.
[36] Deng C,Xie X,Han J,et al.A sieve-functional and uniform-porous kaolin layer toward stable zinc metal anode[J].Advanced Functional Materials,2020,30(21):2000599.
[37] Yan H,Li S,Nan Y,et al.Ultrafast zinc-ion-conductor interface toward high-rate and stable zinc metal batteries[J].Advanced Energy Materials,2021,11(18):2100186.
[38] Shin J,Lee J,Kim Y,et al.Highly reversible,grain-directed zinc deposition in aqueous zinc ion batteries[J].Advanced Energy Materials,2021,11(39):2100676.
[39] Xu Y,Zhu J,Feng J,et al.A rechargeable aqueous zinc/sodium manganese oxides battery with robust performance enabled by Na2SO4 electrolyte additive[J].Energy Storage Materials,2021,38:299-308.
[40] Cao J,Zhang D,Chanajaree R,et al.Stabilizing zinc anode via a chelation and desolvation electrolyte additive[J].Advanced Powder Materials,2022,1(1):100007.
基金资助
国家自然科学基金面上项目(51472166)
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