双电层电容器以碳材料为电极材料,具有功率密度高、循环性能好、充放电速度快等优点,但也存在能量密度低的问题。金属硫化物因具有独特的电子结构和丰富的氧化还原反应活性位点,被用于与碳材料复合构建复合电极以改善碳材料的电化学性能。主要介绍了通过水热硫化、高温硫化等方法实现金属硫化物对生物质炭、碳纳米管、石墨烯、碳气凝胶和碳纤维的改性,研究了复合电极的电化学性能,对比了超级电容器器件的储能性能,并展望了金属硫化物改性碳材料面临的挑战与发展趋势。
Using carbon materials as electrode materials,electric double-layer capacitors have the advantages of high power density,good cycling performance,and fast charging and discharging rates,but the low energy density limits their application.Due to the unique electronic structure and abundant redox reaction active sites,metal sulfides are used for the modification of carbon materials to construct composite electrodes,improving the electrochemical performance of carbon materials.The modification of biomass carbon,carbon nanotube,graphene,carbon aerogel,and carbon fiber by metal sulfides through hydrothermal vulcanization and high temperature vulcanization were introduced.The electrochemical performance of composite electrodes was investigated,and the energy storage performance of corresponding supercapacitor devices were compared.Furthermore,the challenges and development trends of the metal sulfide-modified carbon materials were discussed.
[1] Jrondi A,Buvat G,De La Pena F,et al.Major improvement in the cycling ability of pseudocapacitive vanadium nitride films for micro-supercapacitor[J].Advanced Energy Materials,2023,13(9):2203462.
[2] Chernysheva D,Smirnova N,Ananikov V P.Recent trends in supercapacitor research:sustainability in energy and materials[J].ChemSusChem,2023,17(5):e202301367.
[3] Yi S,Abbasi K R,Hussain K,et al.Environmental concerns in the United States:can renewable energy,fossil fuel energy,and natural resources depletion help？[J].Gondwana Res,2023,117:41-55.
[4] Meda U S,Rajyaguru Y V,Pandey A.Generation of green hydrogen using self-sustained regenerative fuel cells:opportunities and challenges[J].International Journal of Hydrogen Energy,2023,48(73):28289-28314.
[5] Ravi S S,Aziz M.Clean hydrogen for mobility-quo vadis？[J].International Journal of Hydrogen Energy,2022,47(47):20632-20661.
[6] Bennear L S.Energy justice,decarbonization,and the clean energy transformation[J].Annual Review of Resource Economics,2022,14:647-668.
[7] Chen B X,Lu Z X,Feng S Y,et al.Redox-active nitroxide radicals grafted onto MXene:boosting energy storage via improved charge transfer and surface capacitance[J].ACS Energy Letters,2023:1096-1106.
[8] Huang J,Xie Y P,You Y,et al.Rational design of electrode materials for advanced supercapacitors:from lab research to commercialization[J].Advanced Functional Materials,2023,33(14):2213095.
[9] 翟冬梅,郭鹏卓,黄宏斌,等.超级电容器电极材料及电解液的研究进展[J].化工新型材料,2024,52(1):47-53.
[10] Zhong M Z,Zhang M,Li X F.Carbon nanomaterials and their composites for supercapacitors[J].Carbon Energy,2022,4(5):950-985.
[11] Ahmad F,Zahid M,Jamil H,et al.Advances in graphene-based electrode materials for high-performance supercapacitors:a review[J].Journal of Energy Storage,2023,72:108731.
[12] Kim H,Cheong J Y,Hwang B.Mini review of technological trends of flexible supercapacitors using carbon nanotubes[J].Journal of Natural Fibers,2023,20(2):2204455.
[13] Ren H J,Huang C D.Progress in electrode modification of fibrous supercapacitors[J].Journal of Energy Storage,2022,56:106032.
[14] Khot M,Kiani A.A review on the advances in electrochemical capacitive charge storage in transition metal oxide electrodes for pseudocapacitors[J].International Journal of Energy Research,2022,46(15):21757-21796.
[15] Shao Q G,Liu X H,Dong J X,et al.Vulcanization conditions of bimetallic sulfides under different sulfur sources for supercapacitors:a review[J].Journal of Electronic Materials,2023,52(3):1769-1784.
[16] Tang G L,Liang J,Wu W.Transition metal selenides for supercapacitors[J].Advanced Functional Materials,2023:2310399.
[17] Zhu Y,Su P,Wang J M,et al.Research progress on metal-organic framework-based electrode materials for supercapacitors[J].Crystals,2023,13(11):1593.
[18] Chu X,Yang W Q,Li H.Recent advances in polyaniline-based micro-supercapacitors[J].Materials Horizons,2023,10(3):670-697.
[19] Etman A E,Ibrahim A M,Darwish F A M,et al.A 10 years-developmental study on conducting polymers composites for supercapacitors electrodes:a review for extensive data interpretation[J].Journal of Industrial and Engineering Chemistry,2023,125:421-421.
[20] Wang Z D,Hong P,Zhao H P,et al.Recent developments and future prospects of transition metal compounds as electrode materials for potassium-ion hybrid capacitors[J].Advanced Materials Technologies,2023,8(3):2200515.
[21] 姜海艳,王旭,洪晓东.生物质衍生碳/MnO2复合材料在超级电容器中的应用进展[J].化工新型材料,2023,51(8):17-22.
[22] Iqbal M F,Ashiq M N,Zhang M.Design of metals sulfides with carbon materials for supercapacitor applications:a review[J].Energy Technology-Ger,2021,9(4):2000987.
[23] Liang K,Chen Y L,Wang D,et al.Post-modified biomass derived carbon materials for energy storage supercapacitors:a review[J].Sustainable Energy & Fuels,2023,7(15):3541-3559.
[24] Li J J,Yang J Y,Wang P R,et al.NiCo2S4 combined 3D hierarchical porous carbon derived from lignin for high-performance supercapacitors[J].International Journal of Biological Macromolecules,2023,232:123344.
[25] Chen Z Y,Xue R Z,Hou X,et al.Multifunctional material integrated from walnut shell-derived porous carbon and Co/Zn-S for high-performance supercapacitors and adsorbents[J].Industrial Crops and Products,2023,205:117415.
[26] Li Y F,Qiu Z Z,Qu M,et al.Mo-doped ZIF-67 derived Ni,Co,Mo trimetallic sulfide/carbon nanotubes for supercapacitors[J].Journal of Energy Storage,2023,73:108997.
[27] Zhao J H,Wang M,Wang S,et al.MOF-derived NiS2@carbon microspheres wrapped with carbon nanotubes for high cycle performance supercapacitors[J].Electrochimica Acta,2023,464:142920.
[28] Ye Y,Luo Y Z,Lou J T,et al.Hollow spherical NiCoS@N-CNT composites with high energy density for all-solid-state supercapacitors[J].ACS Applied Energy Materials Journal,2023,6:6742-6751.
[29] Cui Y H,Zhao L J,Pan H,et al.ZIF-9 derived rGO/NiCoS composite as the electrode materials for high performance asymmetric supercapacitor[J].Microchemical Journal,2023,190:108718.
[30] Li X A,Zhang W Y,Kang H W,et al.Self-assembled CoS2/NiCo2S4/RGO nanohybrids as advanced electrode for hybrid supercapacitor with enhanced energy density and ultra-long durability[J].Journal of Energy Storage,2023,67:107528.
[31] Zardkhoshoui A M,Ameri B,Davarani S S H.A hybrid supercapacitor assembled by reduced graphene oxide encapsulated lollipop-like FeNi2S4@Co9S8 nanoarrays[J].Chemical Engineering Journal,2023,470:144132.
[32] Xiong C Y,Zhang Y K,Ni Y H.Recent progress on development of electrolyte and aerogel electrodes applied in supercapacitors[J].Journal of Power Sources,2023,560:232698.
[33] Guo H W,Zhang A T,Fu H C,et al.In situ generation of CeCoSx bimetallic sulfide derived from “egg-box” seaweed biomass on S/N co-doped graphene aerogels for flexible all solid-state supercapacitors[J].Chemical Engineering Journal,2023,453:139633.
[34] Sun H D,Zheng L L,Xi Y R,et al.Nickel-iron sulfide nanoparticles supported on biomass-derived N-doped hierarchical porous carbon as a robust electrode for supercapacitors[J].Electrochimica Acta,2023,466:143053.
[35] Gai L X,Song G L,Li Y Y,et al.Versatile bimetal sulfides nanoparticles-embedded N-doped hierarchical carbonaceous aerogels (N-NiS/CoS@C) for excellent supercapacitors and microwave absorption[J].Carbon,2021,179:111-124.
[36] 裴勇勇,魏枫,高聪,等.碳纤维复合材料结构超级电容器的研究及展望[J].化工新型材料,2023,51(2):1-5.
[37] Zhang Q,Pan S J,Wang Z P,et al.MOF-derived porous NiS/CoS nanosheet arrays for flexible supercapacitor electrode[J].Ionics,2023,DOI:10.1007/s11581-023-05267-6.
[38] Zhang J,Liu X X,Yin Q,et al.CoNiS nanoplate arrays derived from hydroxide precursors for flexible fiber-shaped supercapacitors[J].ACS Omega,2019,4(7):11863-11870.
[39] Xu W N,Lu J L,Huo W C,et al.Direct growth of CuCoS nanosheets on carbon fiber textile with enhanced electrochemical pseudocapacitive properties and electrocatalytic properties towards glucose oxidation[J].Nanoscale,2018,10(29):14304-14313.
基金资助
国家自然科学基金(51503216);浙江省重点研发计划项目(2021C01004)
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