新型CVD法合成Fe3C-CNT用于高性能锂硫电池正极研究

徐开兵, 陈晓*

化工新型材料 ›› 2025, Vol. 53 ›› Issue (2) : 128 -130.

PDF
化工新型材料 ›› 2025, Vol. 53 ›› Issue (2) : 128-130. DOI: 10.19817/j.cnki.issn1006-3536.2025.02.018
新材料与新技术

新型CVD法合成Fe3C-CNT用于高性能锂硫电池正极研究

    徐开兵, 陈晓*
作者信息 +

Study on novel CVD method-synthesized Fe3C-CNT for high-performance lithium-sulfur battery cathode

  • Xu Kaibing, Chen Xiao
Author information +
文章历史 +
PDF

摘要

采用三聚腈胺作为固相碳源、氯化铁粉末作为原料,设计了一种新型的化学气相沉积方法,一步法合成了超长碳纳米管包裹的Fe3C纳米晶(Fe3C-CNT);随后用熔融法与硫粉混合,得到Fe3C-CNT/S复合材料。得益于Fe3C-CNT优异的导电性和固硫效果,该复合材料用作锂硫电池正极材料,表现出显著改善的电化学性能,在1C的电流下,循环500圈仍能保持378.4mAh/g的比容量。

Abstract

A novel chemical vapor deposition (CVD) method was used to prepare Fe3C nanocrystal coated with ultra-long carbon nanotubes (Fe3C-CNT) by one-pot method using tripolynitrylamine as solid carbon source and ferric chloride (FeCl3) powder as raw material.The Fe3C-CNT/S composite was obtained by mixing Fe3C-CNT with sulfur powder (S) by melting method.Thanks to the excellent electrical conductivity and sulfur-immobilized effects of Fe3C-CNT,the composite material,used as the cathode for lithium-sulfur batteries,exhibited significantly improved electrochemical performance,which could maintain the specific capacity of 378.4mAh/g at a current of 1C.

关键词

化学气相沉积 / Fe3C纳米晶 / 锂硫电池 / 高性能

Key words

chemical vapor deposition / Fe3C nanocrystals / lithium-sulfur batteries / high performance

引用本文

引用格式 ▾
新型CVD法合成Fe3C-CNT用于高性能锂硫电池正极研究[J]. 化工新型材料, 2025, 53(2): 128-130 DOI:10.19817/j.cnki.issn1006-3536.2025.02.018

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Dunn B,Kamath H,Tarascon J M.Electrical energy storage for the grid:a battery of choices[J].Science,2011,334(6058):928-935.
[2] Chu S,Cui Y,Liu N.The path towards sustainable energy[J].NatMater,2016,16(1):16-22.
[3] Pang Q,Liang X,Kwok C Y,et al.Advances in lithium-sulfur batteries based on multifunctional cathodes and electrolytes[J].Nat Energy,2016,1(9):16132.
[4] Liu X,Huang J Q,Zhang Q,et al.Nanostructured metal oxides and sulfides for lithium-sulfur batteries[J].AdvMater,2017,29(20):1601759.
[5] Li G,Chen Z,Lu J.Lithium-sulfur batteries for commercial applications[J].Chem,2018,4(1):3-7.
[6] Seh Z W,Sun Y,Zhang Q,et al.Designing high-energy lithium-sulfur batteries[J].ChemSocRev,2016,45(20):5605-5634.
[7] Li C,Xi Z,Guo D,et al.Chemical immobilization effect on lithium polysulfides for lithium-sulfur batteries[J].Small,2018,14(4):1701986.
[8] Liang X,Hart C,Pang Q,et al.A highly efficient polysulfide mediator for lithium-sulfur batteries[J].Nat Commun,2015,6:5682.
[9] Guo R,Su D,Chen F,et al.Hollow beaded Fe3C/N-doped carbon fibers toward broadband microwave absorption[J].ACS Appl MaterInterfaces,2022,14(2):3084-3094.
[10] Li H,Ma S,Cai H,et al.Ultra-thin Fe3C nanosheets promote the adsorption and conversion of polysulfides in lithium-sulfur batteries[J].Energy Storage Mater,2019,18:338-348.
[11] Yu B,Huang A,Chen D,et al.In situ construction of Mo2C quantum dots-decorated CNT networks as a multifunctional electrocatalyst for advanced lithium-sulfur batteries[J].Small,2021,17(23):2100460.
[12] Zhang H,Ono L K,Tong G,et al.Long-life lithium-sulfur batteries with high areal capacity based on coaxial CNTs@TiN-TiO2 sponge[J].NatCommun,2021,12(1):473.
[13] Sadezky A,Muckenhuber H,Grothe H,et al.Raman microspectroscopy of soot and related carbonaceous materials:spectral analysis and structural information[J].Carbon,2005,43(8):1731-1742.

基金资助

国家自然科学基金资助项目(51602049);高等教育规划专项课题(GJGH2023014)

AI Summary AI Mindmap
PDF

429

访问

0

被引

导航
相关文章

AI思维导图

/