具有结构化孔道的介孔碳材料是纳米颗粒物良好的载体,可以有效抑制纳米颗粒物的聚集。在介孔碳上负载纳米金颗粒物(AuNPs)合成的复合材料具备大比表面积、优异的热稳定性、可调控的孔径和孔道结构、良好的分散性以及可再生性等多重优势。综述了介孔碳负载AuNPs复合材料的合成方法,如浸渍法、离子交换法、沉积沉淀法和溶胶-凝胶法等,以及复合材料在化学传感器、能源储存和分离吸附等领域的应用,介绍了透射电子显微镜、X射线衍射和电感耦合等离子体发射光谱等表征技术在揭示复合材料组成、结构和界面特性中的作用,指出复合材料与其他活性材料结合或将人工智能应用于复合材料的设计和优化是未来的研究方向。
Mesoporous carbon materials with structured pore channels serve as excellent carriers for nanoparticles,effectively inhibiting their aggregation.Composite materials synthesized by loading gold nanoparticles (AuNPs) onto mesoporous carbons exhibit numerous advantages,including large specific surface area,excellent thermal stability,tunable pore size and structure,good dispersibility,and recyclability.This review covered the synthesis methods of mesoporous carbon-supported AuNPs composites,such as impregnation,ion exchange,deposition-precipitation,and sol-gel methods,along with their applications in chemical sensors,energy storage,and separation adsorption.The roles of characterization techniques such as transmission electron microscopy,X-ray diffraction,and inductively coupled plasma emission spectroscopy were discussed for revealing the composition,structure,and interface properties of these composites.Future research directions should include integrating composite materials with other active materials and applying artificial intelligence to the design and optimization of composite materials.
[1] Campanile R,Acunzo A,Scardapane E,et al.Multifunctional core@satellite magnetic particles for magnetoresistive biosensors[J].ACS Omega,2022,7(41):36543-36550.
[2] Gleiter H.Interfaces Ii[M].Zurich:Trans Tech Publications Ltd,1995:67-80.
[3] Liu D M,Dong C.Gold nanoparticles as colorimetric probes in food analysis:progress and challenges[J].Food Chemistry,2023,429:136887.
[4] Ma X,Li X,Luo G,et al.DNA-functionalized gold nanoparticles:modification,characterization,and biomedical applications[J].Frontiers in Chemistry,2022,10:121-139.
[5] 周耀渝,汤琳,李贞,等.有序介孔碳载金/L-赖氨酸/纳米金修饰电极的制备及其对邻苯二酚、对苯二酚的检测响应研究[J].环境科学,2013,34(3):1211-1217.
[6] Ryoo R,Joo S H,Jun S.Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation[J].J Phys Chem B,1999,103(37):7743-7746.
[7] Sun Y G,Zhang W,Wang Q,et al.Biomass-derived N,S co-doped 3D multichannel carbon supported Au@Pd@Pt catalysts for oxygen reduction[J].Environ Res,2021,202:111684.
[8] Shang Q,Dong H,Liu S H,et al.Sandwich-type electrochemical immunosensor based on nitrogen-doped porous carbon and nanoporous trimetallic nanozyme (PdAgCu) for determination of prostate specific antigen[J].Microchim Acta,2022,189(9):352-359.
[9] Jeong U,Kim H,Ramesh S,et al.Rapid access to ordered mesoporous carbons for chemical hydrogen storage[J].Angew Chem-Int Edit,2021,60(41):22478-22486.
[10] Deng C W,Pan L W,Ji F,et al.Hybrid dual-template induced nitrogen-doped hierarchically porous carbon as highly efficient oxygen reduction electrocatalyst[J].Int J Hydrog Energy,2021,46(73):36167-36175.
[11] Zhou H L,Wang D X,Fu A P,et al.Mesoporous carbon spheres with tunable porosity prepared by a template-free method for advanced lithium-sulfur batteries[J].Mater Sci Eng B-Adv Funct Solid-State Mater,2018,227:9-15.
[12] Björk E M,Atakan A,Wu P H,et al.A shelf-life study of silica and carbon-based mesoporous materials[J].Journal of Industrial and Engineering Chemistry,2021,101:205-213.
[13] Wang S,Sima G B,Cui Y,et al.Efficient hydrolysis of cellulose to glucose catalyzed by lignin-derived mesoporous carbon solid acid in water[J].Chin J Chem Eng,2020,28(7):1866-1874.
[14] Wang S,Zhu X J,Tian Y,et al.Controlled synthesis of mesoporous carbons with tailored morphologies via a “silica-assisted” strategy[J].J Mater Sci,2016,51(12):6086-6096.
[15] Liu D W,Xue N,Wei L J,et al.Surfactant assembly within pickering emulsion droplets for fabrication of interior-structured mesoporous carbon microspheres[J].Angew Chem-Int Edit,2018,57(34):10899-10904.
[16] Xiong J J,Qian Y,Jiang P,et al.Biomass-derived mesoporous and super-hydrophilic carbon manufactured by cycling-pressure-switching air activation process towards ultrahigh adsorption efficiency of tetracycline[J].Sustain Mater Technol,2022,32:121040.
[17] Zhu S,Sheng J,Jia G D,et al.Synthesis and modification of mesoporous carbon nanomaterials[J].Chin J Inorg Chem,2022,38(1):1-13.
[18] Nisa Z U,Chuan L K,Guan B H,et al.A comparative study on the crystalline and surface properties of carbonized mesoporous coconut shell chars[J].Sustainability,2023,15(8):6464.
[19] Vorokhta M,Nováková J,Dopita M,et al.Activated three-dimensionally ordered micromesoporous carbons for CO2 capture[J].Mater Today Sustain,2023,24:100509-100524.
[20] Bergna D,Hu T,Prokkola H,et al.Effect of some process parameters on the main properties of activated carbon produced from peat in a lab-scale process[J].Waste Biomass Valorization,2020,11(6):2837-2848.
[21] Castro-Gutierrez J,Canevesi R L S,Emo M,et al.CO2 outperforms KOH as an activator for high-rate supercapacitors in aqueous electrolyte[J].Renew Sust Energ Rev,2022,167:112716-112731.
[22] Yu J,Joo S,Sim T,et al.Post-KOH activation of nitrogen-containing porous carbon with ordering mesostructure synthesized through a self-assembly[J].Chem Phys Lett,2020,739:137028.
[23] Volosin A M,Chen S,Seo D K.High-surface area mesoporous carbons from gel templating and inorganic-organic hybrid gel formation[J].Journal of Solid State Chemistry,2020,281:121040-121048.
[24] Liu Y,Chen M,Hu M,et al.In-situ anchoring sulfiphilic silica nanoparticles onto macro-mesoporous carbon framework for cost-effective Li-S cathodes[J].Chemical Engineering Journal,2021,406:126781.
[25] Kuan W F,Chang F Y,Chang J J,et al.Building high-capacity mesoporous adsorbents for fluoride removal through increased surface oxygen anions using organogel-assisted synthesis[J].J Clean Prod,2023,401:136784.
[26] Samiee L,Tasharrofi S,Hassani S S,et al.Novel and economic approach for synthesis of mesoporous silica template and ordered carbon mesoporous by using cation exchange resin[J].Curr Nanosci,2017,13(6):595-603.
[27] Zhu B,Xu J Y,Xu Z H,et al.Soft-template solvent thermal method synthesis of magnetic mesoporous carbon-silica composite for adsorption of methyl orange from aqueous solution[J].Environ Sci Pollut Res,2022,29(27):40734-40744.
[28] Guo P C,Tang L,Tang J,et al.Catalytic reduction-adsorption for removal of p-nitrophenol and its conversion p-aminophenol from water by gold nanoparticles supported on oxidized mesoporous carbon[J].J Colloid Interface Sci,2016,469:78-85.
[29] Zhou M Y,Wei X R,Zhang X C,et al.Uniform mesoporous carbon hollow microspheres imparted with surface-enriched gold nanoparticles enable fast flow adsorption and catalytic reduction of nitrophenols[J].J Colloid Interface Sci,2019,537:112-122.
[30] Santos L S S,Barros S B A,Rahim A,et al.In situ synthesis of gold nanoparticles on mesoporous silica surface-functiona-lized with pyridinium ligands[J].J Nanopart Res,2020,22(2):1-14.
[31] Okumura M,Fujitani T,Huang J H,et al.A career in catalysis:masatake haruta[J].ACS Catal,2015,5(8):4699-4707.
[32] Nagpure A S,Gogoi P,Chilukuri S V.Active and recyclable gold metal nanoparticles catalyst supported on nitrogen-doped mesoporous carbon for chemoselective hydrogenation of cinnamaldehyde to cinnamyl alcohol[J].Chem-Asian J,2021,16(18):2702-2722.
[33] Li H,Shen H,Pei C,et al.A self-assembly process for the immobilization of N-modified Au nanoparticles in ordered mesoporous carbon with large pores[J].ChemCatChem,2019,11(16):3882-3891.
[34] Banerjee R,Ghosh D,Satra J,et al.One step synthesis of a gold/ordered mesoporous carbon composite using a hard template method for electrocatalytic oxidation of methanol and colorimetric determination of glutathione[J].ACS Omega,2019,4(15):16360-16371.
[35] Gu Y Y,Jiang Y T,Gong G A,et al.Detection of CYFRA21-1 in serum by electrochemical immunosensor based on nanocomposite consisting of AuNPs@CMK-3@CMWCNTs[J].Bioelectrochemistry,2022,148:108230.
[36] Rad S L,Eftekhari-Sis B,Vahdati-Khajeh S,et al.Gold nano-particles immobilized on N-doped ordered mesoporous carbon:an efficient catalyst for A3 and KA2 coupling reactions[J].Appl Organomet Chem,2023,37(4):7059-7071.
[37] Murthy P R,Selvam P.The enhanced catalytic performance and stability of ordered mesoporous carbon supported nano-gold with high structural integrity for glycerol oxidation[J].Chem Rec,2019,19(9):1913-1925.
[38] Gong C,Zhou Z W,Zhou H J,et al.Vacuum-assisted synthesis of tiny Au nanoparticles entrapped into mesoporous carbon matrix with superior catalytic activity for 4-nitrophenol reduction[J].Adv Powder Technol,2019,30(3):649-655.
[39] Sousa G P,De Oliveira C S,Neto É,et al.Au-CeO2-based nanocatalysts supported on SBA-15 for preferential oxidation of carbon monoxide (PrOx-CO)[J].New J Chem,2020,44(44):19028-19036.
[40] Mahyari M,Shaabani A,Behbahani M,et al.Thiol-functiona-lized fructose-derived nanoporous carbon as a support for gold nanoparticles and its application for aerobic oxidation of alcohols in water[J].Appl Organomet Chem,2014,28(8):576-583.
[41] Shen X,Li W,Ding S M,et al.Construction of mesoporous ceria-supported gold catalysts with rich oxygen vacancies for efficient CO oxidation[J].J Rare Earths,2022,40(3):434-442.
[42] Lei M L,Gao M Q,Yang X Y,et al.Size-controlled Au nano-particles incorporating mesoporous ZnO for sensitive ethanol sensing[J].ACS Appl Mater Interfaces,2021,13(44):51933-51944.
[43] Tan Y,Liu Y,Kong L,et al.Supercapacitor electrode of nano-Co3O4 decorated with gold nanoparticles via in-situ reduction method[J].J Power Sources,2017,363:1-8.
基金资助
江苏省双创团队[(2018)2017号]
PDF
