杂质Fe对CNFs形貌与生长机理的影响

贾晓菁, 查萌, 张璋

化工新型材料 ›› 2024, Vol. 52 ›› Issue (11) : 182 -185.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (11) : 182-185. DOI: 10.19817/j.cnki.issn1006-3536.2024.12.043
科学研究

杂质Fe对CNFs形貌与生长机理的影响

    贾晓菁, 查萌, 张璋
作者信息 +

Effect of impurity Fe on the morphology and growth mechanism of CNFs

  • Jia Xiaojing, Zha Meng, Zhang Zhang
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摘要

采用浆料浸渍法,以纳米镍粉、纳米SiO2和酚醛树脂配制催化剂浆料,在二维碳纤维布表面引入催化剂层,并通过化学气相沉积(CVD)法原位生成碳纳米纤维(CNFs)。当催化剂浆料中存在1.3%二茂铁时,观察到二维碳纤维布表面生成蕾丝状CNFs。通过扫描电镜(SEM)、透射电镜(TEM)以及拉曼光谱的表征,对比分析了杂质引入前后微结构的差异。并基于扩散和固-液-气(V-L-S)生长模型分析了蕾丝CNFs的生长机理。结果表明:Fe是影响蕾丝形成的主要因素。

Abstract

Slurry impregnation method was employed to prepare a catalyst slurry with nano-nickel powder,nano-SiO2,and phenolic resin.This catalyst layer was introduced onto the surface of a 2-D carbon fiber cloth to generate carbon nanofibers (CNFs) in situ by chemical vapor deposition (CVD).When he catalyst slurry contained 1.3wt% ferrocene,lace-like CNFs were obtained on the surface of the 2-D carbon fiber cloth.SEM,TEM and Raman Spectroscopy were used to investigate the morphology of the CNFs,and the microstructural differences before and after the introduction of impurities were analyzed and compared.In addition,the growth mechanism of lace CNFs was analyzed based on diffusion and solid-liquid-gas (V-L-S) growth models.The results showed that Fe was the key factor affecting the formation of lace.

关键词

碳纳米纤维 / 催化剂 / 化学气相沉积 / 生长机理

Key words

CNFs / catalyst / CVD / growth mechanism

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杂质Fe对CNFs形貌与生长机理的影响[J]. 化工新型材料, 2024, 52(11): 182-185 DOI:10.19817/j.cnki.issn1006-3536.2024.12.043

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参考文献

[1] 赵稼祥,王曼霞.复合材料用高性能炭纤维的发展和应用[J].新型炭材料,2000,15(1):68-75.
[2] 殷永霞,沃西源.碳纤维表面改性研究进展[J].航天返回与遥感,2004,25(1):51-54.
[3] 楚电明,董乾鹏,白文娟,等.碳纤维/碳纳米管界面增强技术研究进展[J].化工新型材料,2023,51(1):1-7.
[4] Wang C H,Du H Y,Tsai Y T,et al.High performance of low electrocatalysts loading on CNT directly grown on carbon cloth for DMFC[J].Journal of Power Sources,2007,171(1):55-62.
[5] Thostenson E T,Li W Z,Wang D Z,et al.Carbon nanotube/carbon fiber hybrid multiscale composites[J].Journal of Applied Physics,2002,91(9):6034-6037.
[6] Song Q,Li K,Li H,et al.Grafting straight carbon nanotubes radially onto carbon fibers and their effect on the mechanical properties of carbon/carbon composites[J].Carbon,2012,50(10):3949-3952.
[7] Gong Q,Li Z,Zhou X,et al.Synthesis and characterization of in situ grown carbon nanofiber/nanotube reinforced carbon/carbon composites[J].Carbon,2005,43(11):2426-2429.
[8] Zhang Q,Liu J,Sager R,et al.Hierarchical composites of carbon nanotubes on carbon fiber:influence of growth condition on fiber tensile properties[J].Composites Science and Technology,2009,69(5):594-601.
[9] Lv P,Feng Y,Zhang P,et al.Increasing the interfacial strength in carbon fiber/epoxy composites by controlling the orientation and length of carbon nanotubes grown on the fibers[J].Carbon,2011,49(14):4665-4673.
[10] Lv P,Zhang P,Li F,et al.Vertically aligned carbon nanotubes grown on carbon fabric with high rate capability for super-capacitors[J].Synthetic Metals,2012,162(13):1090-1096.
[11] 范汶鑫.碳纤维表面生长碳纳米管/碳纳米纤维及其增强复合材料的研究[D].济南:山东大学,2016.
[12] 荣怀苹.碳纤维表面纳米结构的构筑及其复合材料性能研究[D].上海:东华大学,2013.
[13] Yang S,Chen X,Motojima S,et al.Morphology and microstructure of spring-like carbon micro-coils/nano-coils prepared by catalytic pyrolysis of acetylene using Fe-containing alloy catalysts[J].Carbon,2005,43(4):827-834.
[14] Chen X,Takeuchi K,Yang S,et al.Morphology and growth mechanism of single-helix spring-like carbon nanocoils with laces prepared using Ni/molecular sieve (Fe) catalyst[J].Journal of materials science,2006,41(8):2351-2357.
[15] Rodriguez N M.A review of catalytically grown carbon nanofibers[J].Journal of Materials Research,1993,8(12):3233-3250.
[16] Dupuis A C.The catalyst in the CCVD of carbon nanotubes—a review[J].Progress in Materials Science,2005,50(8):929-961.
[17] 张志焜.纳米技术与纳米材料[M].北京:国防工业出版社,2000.
[18] Lee C J,Park J,Kim J M,et al.Low-temperature growth of carbon nanotubes by thermal chemical vapor deposition using Pd,Cr,and Pt as co-catalyst[J].Chemical Physics Letters,2000,327(5):277-283.
[19] Jourdain V,Bichara C.Current understanding of the growth of carbon nanotubes in catalytic chemical vapour deposition[J].Carbon,2013,58:2-39.
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