Hydrophilic polyethersulfone (PES) flat sheet membranes were prepared with PES,polyvinyl pyrrolidone (PVP-K90) and dimethylacetamide (DMAc) as raw materials via the nonsolvent induce phase separation technique.The effects of thermal treatment conditions on the properties of hydrophilic PES membranes were systematically investigated.The results indicated that the thermal treatment conditions significantly influenced the dissolution value of PVP.PVP dissolution value of the membrane samples decreased as increasing the temperature and processing time of thermal treatment.The treatment temperature showed little effect on the mechanical properties of the membranes.The membrane hydrophilicity gradually increased with the increase of thermal treatment time.The pure water permeance of the membranes was enhanced by thermal treatment,and the maximum value was achieved when the treatment temperature was 80℃.
[1] 林源欣,任龙飞,邵嘉慧.共涂覆法改性聚醚砜膜络合超滤除锑应用研究[J].水处理技术,2021,47(2):22-26.
[2] Huang Y,Feng X.Polymer-enhanced ultrafiltration:fundamentals,applications and recent developments[J].Journal of Membrane Science,2019,586:53-83.
[3] 樊波,涂凯,陈顺权,等.梯度海绵状结构聚醚砜(PES)平板膜的制备及其性能研究[J].化工新型材料,2016,44(4):81-84.
[4] 王薇,梁朝霞,张宇峰.磺化聚砜在聚醚砜膜亲水改性中的制备与表征[J].高分子材料科学与工程,2016,32(4):153-158.
[5] Van der Bruggen B.Chemical modification of polyethersulfone nanofiltration membranes:a review[J].Journal of Applied Polymer Science,2009,114(1):630-642.
[6] 陈可佳,史宝利.碳纳米管/聚醚砜复合纳滤膜的制备及性能研究[J].现代化工,2020,40(1):169-173.
[7] 田鹍鹏,向慧玲,李亚静,等.改性聚偏氟乙烯膜的生物相容性研究[J].生物医学工程与临床,2010,14(3):207-211.
[8] Wang H T,Yu T,Zhao C Y,et al.Improvement of hydrophilicity and blood compatibility on polyethersulfone membrane by adding polyvinylpyrrolidone[J].Fibers and Polymers,2009,10(1):1-5.
[9] Barzin J,Feng C,Khulbe K C,et al.Characterization of polyethersulfone hemodialysis membrane by ultrafiltration and atomic force microscopy[J].Journal of Membrane Science,2004,237:77-85.
[10] 张云,田立,汪效祖,等.具有完整非对称海绵状结构聚丙烯腈超滤膜的制备[J].化工新型材料,2015,43(2):56-59.
[11] Su B H,Fu P,Li Q,et al.Evaluation of polyethersulfone highflux hemodialysis membrane in vitro and in vivo[J].Journal of Materials Science:Materials in Medicine,2008,19:745-51.
[12] 邱恒,汪永辉,薛罡,等.PES/PAN膜在MBR中膜污染机理及抗污染性能[J].环境科学与技术,2010,33(9):159-163.
基金资助
广东省重点领域研发计划(2023A1111030001);深圳市科技计划可持续发展专项(KCXFZ20201221173402006);中科院科技服务网络计划项目(STS-HP-202205)