燃料油催化氧化脱硫技术具有反应条件温和、成本低及芳香族硫化合物易于脱除等优点,制备高效的氧化脱硫催化剂一直是该技术的研究难点。金属-有机骨架(MOFs)材料具有金属中心丰富、比表面积大、孔隙度高及孔隙结构多样等优点,近年来基于MOFs材料的氧化脱硫催化剂的合成及其催化性能研究受到广泛关注。综述了氧化脱硫催化剂的研究现状及负载不同金属的MOFs催化剂在燃料油催化氧化脱硫中的应用进展,并展望了其未来的发展方向。
The catalytic oxidation desulfurization technology of fuel oil has the advantages of mild reaction conditions,low cost,and easy removal of aromatic sulfur compounds.The preparation of efficient oxidation desulfurization catalysts has always been a research challenge in this technology.Metal-organic frameworks (MOFs) materials have the advantages of rich metal centers,large specific surface area,high porosity,and diverse pore structures.In recent years,the synthesis and catalytic performance of oxidation desulfurization catalysts based on MOFs materials have received widespread attention.This article reviewed the research status of oxidation desulfurization catalysts and the application progress of MOFs catalysts loaded with different metals in catalytic oxidation desulfurization of fuel oil,and looked forward to their future development directions.
[1] 周隆昌,刘汉林,李秀萍,等.直接煅烧法制备二氧化钛及其氧化脱硫性能[J].辽宁石油化工大学学报,2021,41(5):17-22.
[2] Singh D,Chopra A,Mahendra P K,et al.Sulfur compounds in the fuel range fractions from different crude oils[J].Petroleum Science and Technology,2016,34(14):1248-1254.
[3] Liu Y,Wang H,Zhao J,et al.Ultra-deep desulfurization by reactive adsorption desulfurization on copper-based catalysts[J].Journal of Energy Chemistry,2019,29:8-16.
[4] Julião D,Gomes A C,Pillinger M,et al.Desulfurization of liquid fuels by extraction and sulfoxidation using H2O2 and [CpMo(CO)3R] as catalysts[J].Applied Catalysis B:Environmental,2018,230:177-183.
[5] de Rink R,Klok J B M,Van Heeringen G J,et al.Increasing the selectivity for sulfur formation in biological gas desulfurization[J].Environmental Science & Technology,2019,53(8):4519-4527.
[6] Shi Y,Liu G,Zhang B,et al.Oxidation of refractory sulfur compounds with molecular oxygen over a Ce-Mo-O catalyst[J].Green Chemistry,2016,18(19):5273-5279.
[7] Gu Q,Wen G,Ding Y,et al.Reduced graphene oxide:a metal-free catalyst for aerobic oxidative desulfurization[J].Green Chemistry,2017,19(4):1175-1181.
[8] 商宇桐,杨丽娜,管景国,等.光催化氧化脱硫催化剂研究进展[J].石油化工高等学校学报,2020,33(2):17-22.
[9] Leng K,Sun Y,Zhang X,et al.Ti-modified hierarchical mordenite as highly active catalyst for oxidative desulfurization of dibenzothiophene[J].Fuel,2016,174:9-16.
[10] Leng K,Li X,Ye G,et al.Ti-containing hierarchical beta with highly active sites for deep desulfurization of fuels under mild conditions[J].Catalysis Science & Technology,2016,6(20):7615-7622.
[11] Piscopo C G,Granadeiro C M,Balula S S,et al.Metal-organic framework-based catalysts for oxidative desulfurization[J].ChemCatChem,2020,12(19):4721-4731.
[12] Bhadra B N,Jhung S H.Oxidative desulfurization and denitrogenation of fuels using metal-organic framework-based/derived catalysts[J].Applied Catalysis B:Environmental,2019,259:118021.
[13] Kirchon A,Feng L,Drake H F,et al.From fundamentals to applications:a toolbox for robust and multifunctional MOF materials[J].Chemical Society Reviews,2018,47(23):8611-8638.
[14] Li S W,Zhang H Y,Han T H,et al.A spinosus Fe3O4@MOF-PMoW catalyst for the highly effective oxidative desulfurization under oxygen as oxidant[J].Separation and Purification Technology,2021,264:118460.
[15] Xiao W,Dong Q,Wang Y,et al.Time modulation of defects in UiO-66 and application in oxidative desulfurization[J].CrystEngComm,2018,20(38):5658-5662.
[16] Zheng H Q,Zeng Y N,Chen J,et al.Zr-based metal-organic frameworks with intrinsic peroxidase-like activity for ultradeep oxidative desulfurization:mechanism of H2O2 decomposition[J].Inorganic Chemistry,2019,58(10):6983-6992.
[17] Granadeiro C M,Ribeiro S O,Karmaoui M,et al.Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr)[J].Chemical Communications,2015,51(72):13818-13821.
[18] Zhang X,Huang P,Liu A,et al.A metal-organic framework for oxidative desulfurization:UIO-66(Zr) as a catalyst[J].Fuel,2017,209:417-423.
[19] Viana A M,Ribeiro S O,Castro B,et al.Influence of UiO-66(Zr) preparation strategies in its catalytic efficiency for desulfurization process[J].Materials,2019,12(18):3009.
[20] Ye G,Wang H,Zeng X,et al.Defect-rich bimetallic UiO-66(Hf-Zr):solvent-free rapid synthesis and robust ambient-temperature oxidative desulfurization performance[J].Applied Catalysis B:Environmental,2021,299:120659.
[21] Fu G,Bueken B,de Vos D.Zr-metal-organic framework catalysts for oxidative desulfurization and their improvement by postsynthetic ligand exchange[J].Small Methods,2018,2(12):1800203.
[22] Jin C,Li G,Wang X,et al.Synthesis,characterization and ca-talytic performance of Ti-containing mesoporous molecular sieves assembled from titanosilicate precursors[J].Chemistry of Materials,2007,19(7):1664-1670.
[23] Kim T W,Kim M J,Kleitz F,et al.Tailor-made mesoporous Ti-SBA-15 catalysts for oxidative desulfurization of refractory aromatic sulfur compounds in transport fuel[J].ChemCatChem,2012,4(5):687-697.
[24] Luo H,Gu Y,Liu D,et al.Advances in oxidative desulfurization of fuel oils over MOFs-based heterogeneous catalysts[J].Catalysts,2021,11(12):1557.
[25] Dan-Hardi M,Serre C,Frot T,et al.A new photoactive crystalline highly porous titanium(Ⅳ) dicarboxylate[J].Journal of the American Chemical Society,2009,131(31):10857-10859.
[26] Kim S N,Kim J,Kim H Y,et al.Adsorption/catalytic properties of MIL-125 and NH2-MIL-125[J].Catalysis Today,2013,204:85-93.
[27] McNamara N D,Neumann G T,Masko E T,et al.Catalytic performance and stability of (V) MIL-47 and (Ti) MIL-125 in the oxidative desulfurization of heterocyclic aromatic sulfur compounds[J].Journal of Catalysis,2013,305:217-226.
[28] Zhang Y,Li G,Kong L,et al.Deep oxidative desulfurization catalyzed by Ti-based metal-organic frameworks[J].Fuel,2018,219:103-110.
[29] Smolders S,Willhammar T,Krajnc A,et al.A titanium(Ⅳ)-based metal-organic framework featuring defect-rich Ti-O sheets as an oxidative desulfurization catalyst[J].Angewandte Chemie,2019,131(27):9258-9263.
[30] Ye G,Sun Y,Zhang D,et al.Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization[J].Microporous and Mesoporous Materials,2018,270:241-247.
[31] Ye G,Gu Y,Zhou W,et al.Synthesis of defect-rich titanium terephthalate with the assistance of acetic acid for room-temperature oxidative desulfurization of fuel oil[J].ACS Catalysis,2020,10(3):2384-2394.
[32] Wang D,Qian E W,Amano H,et al.Oxidative desulfurization of fuel oil:part Ⅰ.Oxidation of dibenzothiophenes using tert-butyl hydroperoxide[J].Applied Catalysis A:General,2003,253(1):91-99.
[33] Otsuki S,Nonaka T,Takashima N,et al.Oxidative desulfurization of light gas oil and vacuum gas oil by oxidation and solvent extraction[J].Energy & Fuels,2000,14(6):1232-1239.
[34] Li X,Gu Y,Chu H,et al.MFM-300(V) as an active heterogeneous catalyst for deep desulfurization of fuel oil by aerobic oxidation[J].Applied Catalysis A:General,2019,584:117152.
[35] Lu Z,Godfrey H G W,Da Silva I,et al.Modulating supramolecular binding of carbon dioxide in a redox-active porous me-tal-organic framework[J].Nature Communications,2017,8(1):14212.
[36] Masoomi M Y,Bagheri M,Morsali A.Application of two cobalt-based metal-organic frameworks as oxidative desulfurization catalysts[J].Inorganic Chemistry,2015,54(23):11269-11275.
[37] Abazari R,Sanati S,Morsali A,et al.Dual-purpose 3D pillared metal-organic framework with excellent properties for catalysis of oxidative desulfurization and energy storage in asymmetric supercapacitor[J].ACS Applied materials & Interfaces,2019,11(16):14759-14773.
[38] Gómez-Paricio A,Santiago-Portillo A,Navalón S,et al.MIL-101 promotes the efficient aerobic oxidative desulfurization of dibenzothiophenes[J].Green Chemistry,2016,18(2):508-515.
[39] Vallés-García C,Santiago-Portillo A,Álvaro M,et al.MIL-101 (Cr)-NO2 as efficient catalyst for the aerobic oxidation of thiophenols and the oxidative desulfurization of dibenzothiophenes[J].Applied Catalysis A:General,2020,590:117340.
基金资助
国家自然科学基金(21702087)
PDF
