碳系电热涂料以高电热转化率、安全稳定、适用性强等特点成为电热功能性涂料主流的研究方向。其中以石墨烯为导电填料的石墨烯电热涂料深受研究人员青睐,但是影响石墨烯电热涂料性能的因素众多,为此国内外科技工作者进行了大量的研究。综述了影响石墨烯电热涂料性能的因素,着重分析了制备工艺、界面效应、分散度、粘结剂等对石墨烯电热涂料性能的影响,最后指出了石墨烯电热涂料目前存在的问题并展望了其未来发展趋势。
Carbon-based electrothermal coatings are the mainstream research direction of electrothermal functional coatings due to their high electrothermal conversion rate,safety,stability and strong applicability.Among them,graphene electrothermal coatings with graphene as conductive fillers are favored by researchers.However,there are many factors affecting the performance of graphene electrothermal coatings,and a lot of research has been carried out by scientists and technologists at home and abroad.In this paper,the influencing factors of graphene electrothermal coatings were reviewed,focusing on the effects of preparation process,interface effect,dispersion,binder and other factors on the properties of graphene electrothermal coatings.Finally,the problems of graphene thermal coatings were pointed out and the future development trend of graphene thermal coatings was expected.
[1] 孙慧君.石墨烯在涂料领域中的应用研究概况[J].无机盐工业,2019,51(2):15-18.
[2] Alexander L Ivanovskii.Graphene-based and graphene-like materials[J].Russian Chemical Reviews,2012,81(7):571-605.
[3] 吕伟奇.石墨烯的电磁与热效应基础研究[D].南京:东南大学,2019.
[4] 张娟娟,徐晓晓,何勇.生物质石墨烯电热膜在农业大棚中的应用[J].新农业,2023(9):39-42.
[5] 汪靖凯.石墨烯基电热膜室内采暖应用研究[D].西安:西安建筑科技大学,2021.
[6] 中国光学学会.全国第十六届红外加热暨红外医学发展研讨会论文及论文摘要集[C].杭州:2017.
[7] 伍健强,惠志全,陈剑明.石墨烯电热膜研究综述[J].化学工程与装备,2022(12):206-207.
[8] Cao Y,Fatemi V,Fang S,et al.Unconventional superconductivity in magic-angle graphene superlattices[J].Nature,2018,556:43-50.
[9] Housseinou Ba,Lai Truong-Phuoc,Thierry Romero,et al.Lightweight,few-layer graphene composites with improved electro-thermal properties as efficient heating devices for de-icing applications[J].Carbon,2021,182:655-668.
[10] 王基圆,房灵申,李天文.石墨烯电热膜刮膜影响因素与响应机构的研究[J].科技和产业,2022,22(12):143-147.
[11] 崔志英,杨诗慧,张妍,等.石墨烯电加热服装的服用性能研究[J].毛纺科技,2018,46(8):1-5.
[12] 魏杰,李昊,张亚男,等.石墨烯复合材料在电热防/除冰领域研究进展[J].中国材料进展,2022,41(6):487-496.
[13] 颜训刚.基于石墨烯薄膜电热效应的风机叶片防冰除冰系统研究[D].恩施:湖北民族大学,2022.
[14] 余海龙,林克辉,林创兴,等.基于石墨烯电热膜采暖系统的使用性能分析研究[J].佛山陶瓷,2022,32(10):66-67;126.
[15] Mu Jie,Gao Fangjian,Cui Gan,et al.A comprehensive review of anticorrosive graphene-composite coatings[J].Progress in Organic Coatings,2021,157:106321.
[16] 王仕东,顾宝珊,孙世清,等.石墨烯电热薄膜材料的制备及表征[J].炭素技术,2019,38(4):17-22;47.
[17] 徐晶璐,陈锦民,温绍国,等.水性石墨烯/碳纤维电热涂料的制备及性能研究[J].上海工程技术大学学报,2021,35(1):15-21.
[18] Shao C,Li X,Lin S,et al.Characterization of nanocellulose-graphene electric heating membranes prepared via ultrasonic dispersion[J].Journal of Materials Science,2019,55:421-437.
[19] Li Z,Zhen Z,Chai M,et al.Transparent electrothermal film defoggers and antiicing coatings based on wrinkled graphene[J].Small,2019,16(4):1905945.
[20] Xu Xiaozhi,Liu Chang,Sun Zhanghao,et al.Interfacial engineering in graphene bandgap[J].Chemical Society Reviews,2018,47(9):3059-3099.
[21] 郭佩.地聚物基碳系电热涂料的制备及性能研究[D].南宁:广西大学,2019.
[22] Yang Haiying,Tang Yunqing,Yang Ping.Building efficient interfacial property with graphene heterogeneous interface[J].International Journal of Mechanical Sciences,2022,273:107782.
[23] Zhang Xufeng,Li Dihui,Liu Kejian,et al.Flexible graphene-coated carbon fiber veil/polydimethylsiloxane mats as electrothermal materials with rapid responsiveness[J].International Journal of Lightweight Materials and Manufacture,2019,2:241-249.
[24] Maxime Markov,Mona Zebarjadi.Thermoelectric transport in graphene and 2D layered materials[J].Publication Cover Nanoscale and Microscale Thermophysical Engineering,2018,23(2):117-127.
[25] Khatereh Azizi,Petri Hirvonen,Fan Zheyong,at al.Kapitza thermal resistance across individual grain boundaries in graphene[J].Carbon,2017,125:384-390.
[26] Alosious S,Kannam S,Sathian K,et al.Kapitza resistance at water-graphene interfaces[J].The Journal of Chemical Phy-sics,2020,152(22):224703.
[27] Lv Cheng,Xue Qingzhong,Xia Dan,et al.Effect of chemisorption structure on the interfacial bonding characteristics of graphene-polymer composites[J].Applied Surface Science,2012,258:2077-2082.
[28] 王晨.复合炭系电热涂料的制备及性能研究[D].郑州:郑州大学,2021.
[29] 耿家钰.碳系电热涂料的制备工艺及性能研究[D].哈尔滨:哈尔滨工程大学,2017.
[30] Yang X,Su Z,Huang Q,et al.A zirconium carbide coating on graphite prepared by reactive meltin filtration[J].Journal of Central South University,2014,21:472-476.
[31] 何文龙.基于石墨烯的水性电热涂料的制备与性能研究[J].上海涂料,2019,57(3):11-14.
[32] 王千.基于石墨烯/银纳米颗粒复合薄膜的电热执行器研究[D].北京:清华大学,2018.
[33] S Syed Azim,A Satheesh K,Ramu,et al.Studies on graphite based conductive paint coatings[J].Progress in Organic Coa-tings,2005,55:1-4.
[34] Reis M,Soriano S.Electrocaloric effect on graphenes[J].Applied Physics Letters,2013,102(11):112903.
[35] 胥会,陈建,熊壮,等.石墨烯复合导电涂料的制备[J].炭素技术,2015,34(3):23-26.
[36] 夏金童,涂川俊.碳系电热涂料的制备及其自控温性能研究[J].矿冶工程,2009,29(2):80-82.
[37] 彭宇泰,陆文华,李宝磊.石墨烯在飞机电热防除冰技术的应用[J].化工设计通讯,2018,44(4):66-67.
[38] Daniel R Dreyer,Sungjin Park,Christopher W,at al.The chemistry of graphene oxide[J].Chemical Society Reviews,2015,39:228-240.
[39] 周倩楠.石墨烯/碳纳米管/环氧树脂复合材料的导热性能的实验研究[D].青岛:青岛理工大学,2018.
[40] 张春艳.石墨基电热涂料制备工艺及性能研究[D].哈尔滨:哈尔滨工程大学,2015.
基金资助
吉林省科技发展计划项目(20220203087SF,20230508042RC)