PDF
摘要
塑性嵌缝密封材料在面板接缝止水中发挥着重要的作用。为克服现有塑性嵌缝密封材料低温硬化失去塑性变形能力的缺点,基于有机硅树脂制备了有机硅塑性嵌缝密封材料,研究了增塑剂(硅油)用量对有机硅塑性嵌缝密封材料密度、拉伸粘结性能、浸泡损失率、针入度、下垂度和流动止水长度的影响。结果表明:当增塑剂用量为140份时,有机硅塑性嵌缝密封材料综合性能满足DL/T 949—2005要求;且在-40℃时该材料针入度为199.2(1/10mm)、断裂伸长率为1152%、与混凝土界面未发生破坏,表现出优异的耐低温性能。
Abstract
Plastic caulking sealing materials play an important role in panel joint sealing.In order to overcome the shortcoming that existing plastic caulking sealing materials harden under low temperature and lose their plastic deformation abilities,an organic silicone plastic caulking sealing material based on silicone resin was prepared.The effects of the plasticizer (silicone oil) dosage on the density,tensile bonding performance,weight loss rate after soaking,penetration,sagging,and flow stop length of the organic silicone plastic caulking sealing materials were studied.The results showed that the comprehensive performance of the organic silicone plastic caulking sealing material met the requirements of DL/T 949—2005,when the plasticizer dosage was 140 parts.Moreover,at -40℃,the penetration of the organic silicone plastic caulking sealing material was 199.2(1/10mm),the elongation at break was 1151%,and the interface with the concrete was not damaged,demonstrating excellent low-temperature resistance.
关键词
有机硅
/
嵌缝
/
塑性嵌缝密封材料
/
增塑剂
/
用量
Key words
organic silicone
/
caulking
/
plastic caulking sealing material
/
plasticizer
/
dosage
增塑剂用量对有机硅塑性嵌缝密封材料性能的影响[J].
化工新型材料, 2024, 52(10): 263-266 DOI:10.19817/j.cnki.issn1006-3536.2024.10.006
[1] 崔志刚,孙志恒,刘锦程,等.涂覆型止水结构在纳子峡水电站面板接缝止水破损修复中的应用[J].大坝与安全,2021(1):67-70.
[2] 孙志恒,邱祥兴,张军.面板坝接缝新型防护盖板止水结构试验[J].水力发电,2013,39(10):93-96.
[3] 徐耀,郝巨涛.混凝土面板堆石坝面板接缝止水技术的发展与展望[J].中国水利水电科学研究院学报,2018,16(5):457-465.
[4] 杨得勇.沟后水库溃坝机理现场复核试验研究[J].水力发电,2003,29(3):53-57.
[5] 贾金生,郝巨涛,陈肖蕾.混凝土面板坝止水带设计与柔性填料[J].水力发电,2002,28(4):23-26;37-71.
[6] 谭建平.SR塑性止水材料的研究和应用[J].水力发电,1992(2):31-34.
[7] 王荣芬,许临,贾金生,等.GB塑性嵌缝材料的研究和应用[J].中国建筑防水,1998(5):21-23.
[8] Bhattacharya S,Gao Y,Korampally V,et al.Mechanics of plasma exposed spin-on-glass (SOG) and polydimethyl siloxane (PDMS) surfaces and their impact on bond strength[J].Applied Surface Science,2007,253(9):4220-4225.
[9] 彭忠利,伍青,王跃林,等.羟基封端聚二甲基硅氧烷低聚物阴离子乳液聚合研究[J].中山大学学报(自然科学版),2003,42(5):47-50.
[10] 中华人民共和国国家发展和改革委员会.DL/T 949—2005水工建筑物塑性嵌缝密封材料技术标准[S].北京:中国标准出版社,2005.
[11] Liu J S,Wu S P,Mi Y X.Investigation of effect of additives on adhesive properties of silicone rubbers sealant[J].Key Engineering Materials,2009,417-418:437-440.
[12] 冯巧,丁远飞,亢建华,等.增塑剂对建筑用硅酮密封胶性能的影响[J].中国胶粘剂,2019,28(12):15-19.
[13] 贾金生,郝巨涛,谭建平,等.适应大变形的接缝止水结构和材料研究[J].水力发电,2001,27(8):44-45;53-80.
[14] 史小萌,戴海林.填料对硅酮改性聚氨酯密封胶性能影响的研究[J].石油化工,2003,32(4):294-296.