壳聚糖具有优良的生物降解性、生物相容性和可再生性,在医药、食品、化妆品、废水处理等领域拥有广阔的应用前景和独特的优势。介绍了壳聚糖的功能化改性方法,如交联改性、接枝聚合、金属螯合、分子印迹、磁化改性,对比了不同改性方法的优缺点,综述了功能化壳聚糖基材料对酚类、抗生素类、有机染料类及其他有机废水处理的研究进展。
With excellent biodegradability,biocompatibility and renewability,chitosan exhibits tremendous potential for diverse applications in the fields of medicine,food,cosmetics and wastewater treatment.This review comprehensively examined various functionalized modification techniques employed with chitosan,including cross-linking modification,graft polymerization,metal chelation,molecular imprinting,and magnetization modification.A comparative analysis of the advantages and disadvantages associated with different modification methods was provided.Furthermore,the research progress concerning chitosan-based materials for the effective treatment of phenols,antibiotics,organic dyes,and other organic wastewater was presented.
[1] Upadhyay U,Sreedhar I,Singh S A,et al.Recent advances in heavy metal removal by chitosan based adsorbents[J].Carbohydr Polym,2021,251(4):117000.
[2] Basa S,Nampally M,Honorato T,et al.The pattern of acetylation defines the priming activity of chitosan tetramers[J].J Am Chem Soc,2020,142(4):1975-1986.
[3] Jia Z Y,Zhang L,Cheng P G,et al.Process optimization of chemical precipitation for high concentration phosphorus containing wastewater treatment[J].Advanced Materials Research,2014,1010-1012:580-583.
[4] Dale C,Ekenberg M,Wenta R.Advanced biological treatment removes benzene,phenol from refinery wastewater[J].Hydrocarbon Processing,2018,12:97.
[5] Chen L,Chen B,Kang J,et al.The synthesis of a novel conjugated microporous polymer and application on photocatalytic removal of uranium(Ⅵ) from wastewater under visible light[J].Chemical Engineering Journal,2022,431(4):133222.
[6] Gan G,Fan S,Li X,et al.Adsorption and membrane separation for removal and recovery of volatile organic compounds[J].J Environ Sci (China),2023,123:96-115.
[7] 朱明新,张进雨,潘顺龙,等.磁性壳聚糖微球在有机废水处置领域的应用研究,[J].化学试剂,2022,44(11):1634-1641.
[8] 李欣.功能性壳聚糖基微球可控制备及其对放射性废水中碘离子的吸附研究,[D].武汉:武汉科技大学,2022.
[9] Duan C,Meng X,Meng J,et al.Chitosan as a preservative for fruits and vegetables:a review on chemistry and antimicrobial properties[J].Journal of Bioresources and Bioproducts,2019,4(1):11-21.
[10] 张金生,田中禾,李丽华,等.壳聚糖及其衍生物在水处理中的应用,[J].化工新型材料,2019,47(2):51-55.
[11] 鲁秀国,官伟,陈晶.壳聚糖化学改性吸附水中重金属的研究进展,[J].化工新型材料,2022,50(12):7.
[12] Perez-Calderon J,Marin-Silva D A,Zaritzky N,et al.Eco-friendly PVA-chitosan adsorbent films for the removal of azo dye acid orange 7:physical cross-linking,adsorption process,and reuse of the material[J].Advanced Industrial and Engineering Polymer Research,2023,6(3):239-254.
[13] 杨勤桃,解庆林,陈南春.壳聚糖改性硅藻土对水中As(Ⅴ)的吸附特性,[J].非金属矿,2021,44(5):103-106.
[14] 许令国,万梦,李诗瑶,等.壳聚糖改性硅藻土处理含铬废水的实验研究,[J].山东化工,2019,48(14):229-231.
[15] Shahabivand S,Mortazavi S S,Mahdavinia G R,et al.Phenol biodegradation by immobilized rhodococcus qingshengii isolated from coking effluent on Na-alginate and magnetic chitosan-alginate nanocomposite[J].J Environ Manage,2022,307(2):114586.
[16] 蒲生彦,肖雨婷,马慧,等.CS-EGDE/Fe3O4凝胶微球对水中重金属离子的吸附性能及机理研究[J].环境科学学报,2019,39(7):2172-2181.
[17] Jiang M,Han T,Wang J,et al.Removal of heavy metal chromium using cross-linked chitosan composite nanofiber mats[J].Int J Biol Macromol,2018,120:213-221.
[18] Castro-Riquelme C L,López-Maldonado E A,Ochoa-Terán A,et al.Chitosan-carbamoylcarboxylic acid grafted polymers for removal of metal ions in wastewater[J].Chemical Engineering Journal,2023,456:141034.
[19] Huang Y,Shen Y,Zhang G,et al.Highly effective and selective removal of lead ions by polymer-grafted silica-coated acid-resistant magnetic chitosan composites[J].Separation and Purification Technology,2023,314:123561.
[20] Kyzas G Z,Siafaka P I,Lambropoulou D A,et al.Poly(itaconic acid)-grafted chitosan adsorbents with different cross-linking for Pb(Ⅱ) and Cd(Ⅱ) uptake[J].Langmuir,2014,30(1):120-31.
[21] Musarurwa H,Tavengwa N T.Advances in the application of chitosan-based metal organic frameworks as adsorbents for environmental remediation[J].Carbohydr Polym,2022,283(1):119153.
[22] Zahedi S M,Hosseini M S,Karimi M,et al.Chitosan-based schiff base-metal (Fe,Cu,and Zn) complexes mitigate the negative consequences of drought stress on pomegranate fruits[J].Plant Physiol Biochem,2023,196(2):952-964.
[23] 聂雪,蒋金芝,孙雅庆.2-吡啶甲醛改性壳聚糖的合成及螯合性能的研究Ⅰ.溶剂和pH值对合成及螯合性能的影响[J].功能高分子学报,2005(3):493-498.
[24] 许龙,黄运安,朱秋劲,等.基于壳聚糖的分子印迹聚合物的制备和应用[J].化工进展,2016,35(3):847-855.
[25] Mabrouk M,Hammad S F,Abdella A A,et al.Chitosan-based molecular imprinted polymer for extraction and spectrophotometric determination of ketorolac in human plasma[J].Spectrochim Acta A Mol Biomol Spectrosc,2020,241:118668.
[26] Hossein Beyki M,Shemirani F,Shirkhodaie M.Aqueous Co(Ⅱ) adsorption using 8-hydroxyquinoline anchored gamma-Fe2O3@chitosan with Co(Ⅱ) as imprinted ions[J].Int J Biol Macromol,2016,87:375-384.
[27] Li X,Zeng D,He Z,et al.Magnetic chitosan microspheres:an efficient and recyclable adsorbent for the removal of iodide from simulated nuclear wastewater[J].Carbohydr Polym,2022,276(3):118729.
[28] Nasiri A,Rajabi S,Amiri A,et al.Adsorption of tetracycline using CuCoFe2O4@chitosan as a new and green magnetic nanohybrid adsorbent from aqueous solutions:isotherm,kinetic and thermodynamic study[J].Arabian Journal of Chemistry,2022,15(8):104014.
[29] 贾晓丽,王青青,薛添仁,等.壳聚糖基吸附材料去除水中有机染料的研究进展[J].化工新型材料,2023,51(4):72-76.
[30] Wang J,Zhuang S.Chitosan-based materials:preparation,modification and application[J].Journal of Cleaner Production,2022,355(6):131825.
[31] Liu J,Zhou B,Zhang H,et al.A novel biochar modified by chitosan-Fe/S for tetracycline adsorption and studies on site energy distribution[J].Bioresour Technol,2019,294:122152.
[32] Janani B,Okla M K,Abdel-Maksoud M A,et al.CuO loaded ZnS nanoflower entrapped on PVA-chitosan matrix for boosted visible light photocatalysis for tetracycline degradation and anti-bacterial application[J].J Environ Manage,2022,306:114396.
[33] Yang J,Li Z,Niu X,et al.Hierarchical porous N-doped carbon encapsulated CoFe2O4-CoO nanoparticles derived from layered double hydroxide/chitosan biocomposite for the enhanced degradation of tetracycline[J].Separation and Purification Technology,2022,295(51):121291.
[34] Wang F,Yang B,Wang H,et al.Removal of ciprofloxacin from aqueous solution by a magnetic chitosan grafted graphene oxide composite[J].Journal of Molecular Liquids,2016,222:188-194.
[35] Danalıoğlu S T,Bayazit Ş S,Kerkez Kuyumcu Ö,et al.Efficient removal of antibiotics by a novel magnetic adsorbent:magnetic activated carbon/chitosan (MACC) nanocomposite[J].Journal of Molecular Liquids,2017,240:589-596.
[36] Weng X,Lin S,Zhong Y,et al.Chitosan stabilized bimetallic Fe/Ni nanoparticles used to remove mixed contaminants-amoxicillin and Cd(Ⅱ) from aqueous solutions[J].Chemical Engineering Journal,2013,229(22):27-34.
[37] Kang Y G,Vu H C,Le T T,et al.Activation of persulfate by a novel Fe(Ⅱ)-immobilized chitosan/alginate composite for bisphenol A degradation[J].Chemical Engineering Journal,2018,353:736-745.
[38] Huang D,Tang Z,Peng Z,et al.Fabrication of water-compatible molecularly imprinted polymer based on β-cyclodextrin modified magnetic chitosan and its application for selective removal of bisphenol a from aqueous solution[J].Journal of the Taiwan Institute of Chemical Engineers,2017,77:113-121.
[39] Zhang B,Liu F,Nie C,et al.Photocatalytic degradation of paracetamol and bisphenol a by chitosan supported covalent organic framework thin film with visible light irradiation[J].J Hazard Mater,2022,435(13):128966.
[40] Miao M,Mu L,Cao S,et al.Dual-functional CDs@ZIF-8/chitosan luminescent film sensors for simultaneous detection and adsorption of tetracycline[J].Carbohydr Polym,2022,291(4):119587.
[41] 杨金梁,王宁,杨姗姗,等.磁性壳聚糖与混凝联合去除水体有机物的研究[J].工业水处理,2020,40(11):74-78.
[42] Wang N,Xu Z,Xu W,et al.Comparison of coagulation and magnetic chitosan nanoparticle adsorption on the removals of organic compound and coexisting humic acid:a case study with salicylic acid[J].Chemical Engineering Journal,2018,347:514-524.
[43] Sun Y,Bai L,Wang T,et al.Effective scavenging and selective adsorption of salicylic acid from wastewater using a novel deep eutectic solvents-based chitosan-acrylamide surface molecularly imprinted hydrogel[J].Applied Surface Science,2023,608(2):155102.
[44] Zhang H,Li R,Zhang Z.A versatile EDTA and chitosan bi-functionalized magnetic bamboo biochar for simultaneous removal of methyl orange and heavy metals from complex wastewater[J].Environ Pollut,2022,293:118517.
[45] Jeyaseelan C,Kaur M,Sen M.Activated carbon modified chitosan beads:an effective method for removal of congo red dye[J/OL].Materials Today:Proceedings,2023.https://doi.org/10.1016/j.matpr.2023.03.802.
[46] Zhao C,Luan J,Zhai Q,et al.Releasing SiO tetrahedron and AlO octahedron from montmorillonite to enhance the adsorption performance of carbon@chitosan@montmorillonite nanosheet for cationic dyes:coupling quantum chemistry simulations with experiments[J].Sci Total Environ,2022,851(1):158174.
[47] Cui J,Niu X,Zhang D,et al.The novel chitosan-amphoteric starch dual flocculants for enhanced removal of microcystis aeruginosa and algal organic matter[J].Carbohydr Polym,2023,304(2):120474.
[48] Al-Gharabli S,Flanc Z,Pianka K,et al.Porcupine quills-like-structures containing smart PVDF/chitosan hybrids for anti-fouling membrane applications and removal of hazardous VOCs[J].Chemical Engineering Journal,2023,452(2):139281.
[49] 王秋华.壳聚糖-甘蔗渣活性炭的制备及其处理有机农药污染物的性能研究,[D].长沙:湖南农业大学,2018.
基金资助
国家自然科学基金(52072275);湖北理工学院人才引进项目(23xjz07R)
PDF
