半导体材料光催化合成过氧化氢的研究进展

王歌兰1, 李培贺1*, 李青光1, 陈辰1, 杜超2, 刘景海1*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (8) : 89 -93.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (8) : 89-93. DOI: 10.19817/j.cnki.issn1006-3536.2024.08.050
综述与专论

半导体材料光催化合成过氧化氢的研究进展

    王歌兰1, 李培贺1*, 李青光1, 陈辰1, 杜超2, 刘景海1*
作者信息 +

Research progress on photocatalytic production of hydrogen peroxide by semiconductor materials

  • Wang Gelan1, Li Peihe1, Li Qingguang1, Chen Chen1, Du Chao2, Liu Jinghai1
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摘要

过氧化氢(H2O2)作为一种高效且绿色的氧化剂,在有机合成等领域具有广泛的应用。工业上常用蒽醌法合成H2O2,但该方法需要高温高压和贵金属催化剂,存在能耗较高和副产物较多的不足。光催化技术作为一种环境友好的绿色技术,具有催化效率高、反应条件温和等优点,将其用于H2O2的合成展现出巨大的应用潜力。基于光催化产H2O2的反应机理,系统阐述了半导体光催化材料在光催化合成H2O2领域的最新进展,为设计高效光催化合成H2O2的催化剂提供新思路,并对光催化材料的发展方向进行了展望。

Abstract

As an efficient and green oxidant,hydrogen peroxide (H2O2) has been widely used in organic synthesis and other fields.Anthraquinone method is commonly used to synthesize H2O2 in industry.However,this method requires high temperature,high pressure and noble metal catalysts,which has the disadvantages of high energy consumption and numerous by-products.As an environmentally friendly green technology,photocatalytic technology has the advantages of high catalytic efficiency and mild reaction conditions.It shows great application potential for the synthesis of H2O2.Based on the reaction mechanism of photocatalytic H2O2 production,the latest progress of semiconductor photocatalytic materials in the field of photocatalytic H2O2 production was systematically described,which provided a new idea for the design of efficient photocatalytic H2O2 production catalysts,and the development direction of photocatalytic materials was discussed.

关键词

光催化 / 过氧化氢 / 半导体材料

Key words

photocatalysis / hydrogen peroxide / semiconductor materials

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半导体材料光催化合成过氧化氢的研究进展[J]. 化工新型材料, 2024, 52(8): 89-93 DOI:10.19817/j.cnki.issn1006-3536.2024.08.050

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基金资助

国家自然科学基金(21961024和22261042);内蒙古自治区直属高校基本科研业务费项目(GXKY22063和GXKY22165);内蒙古民族大学博士科研启动基金项目(BS445);国家自然科学基金(22361035);内蒙古自治区草原英才科研专项(KYCYYC23001)

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