当前,由于高电导率和优异的赝电容特性,Mxene电极材料的研究引起了广泛关注,其纤维在储能纺织品、柔性传感器件等领域具有良好的应用前景。从Ti3C2Tx纤维的制备方法,Ti3C2Tx纤维电极材料的电化学性能方面进行了简要阐述,展望了Ti3C2Tx纤维电极材料的研究趋势。
Currently,due to its high conductivity and excellent pseudocapacitive properties,the research of Mxene electrode materials has attracted widespread attention.Their fibers have good application prospects in the fields of energy storage textiles and flexible sensor devices.In this paper,the preparation methods of Ti3C2Tx fibers and the electrochemical properties of Ti3C2Tx fiber electrode materials were briefly described.The research trends of Ti3C2Tx fiber electrode materials were prospected.
[1] Diamant V.Modern research methods of physicochemical and electrochemical proporties of electrolytes in for Li-ion batteries and hybrid suoercapacities[J].Ukrainian Chemistry Journal,2021,87(6):82-96.
[2] Sadeghi S,Mohammad Shiri H,Ehsani A,et al.Electrosynthesis of highly pure perovskite type YbMnO3 nanoparticles and its nanocomposite with conjugated polymer:surface,density of state and electrochemical investigation[J].Surfaces and Interfaces,2021,24:101130.
[3] Zhan X X,Si C,Zhou J,et al.MXene and MXene-based composites:synthesis,properties and environment-related applications[J].Nanoscale Horizons,2020,5(2):235-258.
[4] Muhammad B,Yury G.MXene-conducting polymer asymmetric pseudocapacitors[J].Advanced Energy Materials,2019,9(7):1802917.
[5] Jiang Q,Lei Y J,Liang H F,et al.Review of MXene electrochemical microsupercapacitors[J].Energy Storage Materials,2020,27:78-95.
[6] Wang H M,Zhao R,Hu H X,et al.0D/2D heterojunctions of Ti3C2 MXene QDs/SiC as an efficient and robust photocatalyst for boosting the visible photocatalytic NO pollutant removal ability[J].ACS Applied Materials & Interfaces,2020,12(36):40176-40185.
[7] Ariana L,Zhang J Z,Dion G,et al.MXene-based fibers,yarns,and fabrics for wearable energy storage devices[J].Advanced Functional Materials,2020,30(47):2000739.
[8] Zhang J Z,Kong N,Simge U,et al.Scalable manufacturing of free-standing,strong Ti3C2Tx MXene films with outstanding conductivity[J].Advanced Materials,2020,32(23):2001093.
[9] Zhang X F,Liu X D,Dong S L,et al.Template-free synthesized 3D macroporous MXene with superior performance for supercapacitors[J].Applied Materials Today,2019,16:315-321.
[10] Eom W,Shin H,Rohan B A,et al.Large-scale wet-spinning of highly electroconductive MXene fibers[J].Nature Communications,2020,11(1):2825.
[11] Jia Z X,Li Z J,Ma S F,et al.Constructing conductive titanium carbide nanosheet (MXene) network on polyurethane/polyacrylonitrile fibre framework for flexible strain sensor[J].Journal of Colloid and Interface Science,2021,584:1-10.
[12] Li Yue,Lu Zan,Xin Binjie,et al.All-solid-state flexible supercapacitor of carbonized MXene cotton fabric for wearable energy storage[J].Applied Sueface Science,2020(528):146975.
[13] Lu P,Ding B.Applications of electrospun fibers[J].Recent Patents on Nanotechnology,2008,2(3):169-182.
[14] Elisa A M,Reva M S,Riki M M,et al.Antibacterial properties of electrospun Ti3C2Tz(MXene)/chitosan nanofibers[J].RSC Advances,2018,8(62):35386-35394.
[15] Wang D Y,Zhang D Z,Li P,et al.Electrospinning of flexible poly(vinyl alcohol)/MXene nanofiber-based humidity sensor self-powered by monolayer molybdenum diselenide piezoelectric nanogenerator[J].Nano-Micro Letters,2021,13(1):57.
[16] Shao W Y,Mike T,Ifra M,et al.Polyester@MXene nanofibers-based yarn electrodes[J].Journal of Power Sources,2018,396:683-690.
[17] Fu X Y,Li L,Chen S,et al.Knitted Ti3C2Tx MXene based fiber strain sensor for human-computer interaction[J].Journal of Colloid and Interface Science,2021,604:643-649.
[18] Adel M A,Rajan J,Mazli M,et al.Ultrasensitive aptasensor using electrospun MXene/polyvinylidene fluoride nanofiber composite for Ochratoxin A detection[J].Food Chemistry,2022,390:133105.
[19] Liu L,Guo R,Gao J,et al.Mechanically and environmentally robust composite nanofibers with embedded MXene for wearable shielding of electromagnetic wave[J].Composites Communications,2022,30:101094.
[20] Elisa A M,Olga U,Riki M M,et al.Preparation and characterization of polymer-Ti3C2Tx(MXene) composite nanofibers produced via electrospinning[J].Journal of Applied Polymer Science,2017,134(37):45295.
[21] Ariana S L,Mohamed A,Christine B H,et al.Electrospun MXene/carbon nanofibers as supercapacitor electrodes[J].Journal of Materials Chemistry A,2018,7(1):269-277.
[22] Hyewon H,Segi B,Seoyeon Y,et al.High-rate electrospun Ti3C2Tx MXene/carbon nanofiber electrodes for flexible supercapacitors[J].Applied Surface Science,2021,556:149710.
[23] Tao X,Zhang L L,He X D,et al.Nitrogen-doped porous MXene (Ti3C2) for flexible supercapacitors with enhanced storage performance[J].Molecules,2022,27(15):4890.
[24] Ariana L,Shayan S,Zhang J Z,et al.Bath electrospinning of continuous and scalable multifunctional MXene-infiltrated nanoyarns[J].Small (Weinheim an der Bergstrasse,Germany),2020,16(26):e2002158.
[25] Bilen A,Kathleen M,Babak A,et al.Rheological characteristics of 2D titanium carbide (MXene) dispersions:a guide for processing MXene s[J].ACS Nano,2018,12(3):2685-2694.
[26] Zhang J Z,Simge U,Shayan S,et al.Additive-free MXene liquid crystals and fibers[J].ACS Central Science,2020,6(2):254-265.
[27] Shin H,Eom W,Lee K H,et al.Highly electroconductive and mechanically strong Ti3C2Tx MXene fibers using a deformable MXene gel[J].ACS Nano,2021,15(2):3320-3329.
[28] Chen X,Jiang J J,Yang G Y,et al.Bioinspired wood-like coaxial fibers based on MXene@graphene oxide with superior mechanical and electrical properties[J].Nanoscale,2020,12(41):21325-21333.
[29] Shayan S,Simge U,Ariana L,et al.MXene composite and coaxial fibers with high stretchability and conductivity for wearable strain sensing textiles[J].Advanced Functional Materials,2020,30(12):1910504.
[30] Jong W P,Lee D Y,Kim H,et al.Highly loaded MXene/carbon nanotube yarn electrodes for improved asymmetric supercapacitor performance[J].MRS Communications,2019,9(1):114-121.
[31] 翁雪琪,郭子娇,陆赞,等.PANI/MXene复合纤维柔性电极的制备及性能[J].电池,2021,51(5):460-464.
[32] Shayan S,Elliard R S Y,Joselito M R.Knittable energy storing fiber with high volumetric performance made from predominantly MXene nanosheets[J].Journal of Materials Chemistry A,2017,5(46):24076-24082.
[33] Li C,He Y L,Chai S G,et al.Toward high performance graphene fibers[J].Nanoscale,2013,5(13):5809-5815.
[34] Zhou T Z,Yu Y Z,He B,et al.Ultra-compact MXene fibers by continuous and controllable synergy of interfacial interactions and thermal drawing-induced stresses[J].Nature Communications,2022,13:4564.
[35] Liu Q,Zhao A,He X X,et al.Ti3C2Tx/RGO//PANI/RGO all-solid-state asymmetrical fiber supercapacitor with high energy density and superior flexibility[J].Journal of Alloys and Compounds,2021,861:157950.
[36] Yang Q Y,Xu Z,Fang B,et al.MXene/graphene hybrid fibers for high performance flexible supercapacitors[J].Journal of Materials Chemistry A,2017,5(42):22113-22119.
[37] Zhao X,Zhang J Z,Lv K,et al.Carbon nanotubes boosts the toughness and conductivity of wet-spun MXene fibers for fiber-shaped super capacitors[J].Carbon,2022,200:38-46.
[38] Guo Z J,Li Y,Lu Z,et al.High-performance MnO2@MXene/carbon nanotube fiber electrodes with internal and external construction for supercapacitors[J].Journal of Materials Science,2022,57(5):3613-3628.
[39] Liu Q,Zhao A R,He X X,et al.Full-temperature all-solid-state Ti3C2Tx/aramid fiber supercapacitor with optimal balance of capacitive performance and flexibility[J].Advanced Functional Materials,2021,31(22):2010944.
[40] Zhang J Z,Shayan S,Qin S,et al.Highly conductive Ti3C2Tx MXene hybrid fibers for flexible and elastic fiber-shaped supercapacitors[J].Small,2019,15(8):1804732.
基金资助
青海省应用基础研究计划项目(2024-ZJ-761)
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