二氧化硅空心微球的制备及应用研究进展

马傲雪, 曾丹林*, 黄刚, 魏梦呈, 赵晓玲, 陈阳

化工新型材料 ›› 2024, Vol. 52 ›› Issue (8) : 46 -50.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (8) : 46-50. DOI: 10.19817/j.cnki.issn1006-3536.2024.08.023
综述与专论

二氧化硅空心微球的制备及应用研究进展

    马傲雪, 曾丹林*, 黄刚, 魏梦呈, 赵晓玲, 陈阳
作者信息 +

Progress in preparation and application of silica hollow microspheres

  • Ma Aoxue, Zeng Danlin, Huang Gang, Wei Mengcheng, Zhao Xiaoling, Chen Yang
Author information +
文章历史 +
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摘要

综述了二氧化硅(SiO2)空心微球的制备方法,包括模板法、斯托伯法(stöber)制备法、微乳法、高温溶解法、喷雾反应法、超声波法等,对比了不同制备方法的优缺点。介绍了SiO2空心微球在磁性材料、催化、生物医学、光电材料等多个领域的应用及发展前景。

Abstract

This paper reviewed the preparation methods of SiO2 hollow microspheres,including template method,Stöber method,microemulsion method,high temperature dissolving method,spray reaction method,ultrasonic method,etc.The advantages and disadvantages of different preparation methods were also discussed.The applications and development prospects of SiO2 hollow microspheres in various fields such as magnetic materials,catalysis,biomedicine,photoelectric materials were introduced.

关键词

二氧化硅 / 空心微球 / 制备 / 应用

Key words

SiO2 / hollow microspheres / preparation / application

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引用格式 ▾
二氧化硅空心微球的制备及应用研究进展[J]. 化工新型材料, 2024, 52(8): 46-50 DOI:10.19817/j.cnki.issn1006-3536.2024.08.023

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参考文献

[1] Caruso F.Hollow capsule processing through colloidal templating and self-assembly[J].Chemistry J,2000,6(3):413-419.
[2] Caruso F.Nanoengineering of particle surfaces[J].Advanced Materials,2001,13(1):11-15.
[3] Wang D G,Zhang Y H,Dong A G,et al.Conversion of fly ash cenosphere to hollow microspheres with zeolite/mollite composite shells[J].Advanced Functional Material,2003,13(7):563-565.
[4] Crotts G,Park T G.Preparation of porous and nonporous biodegradable polymeric hollow microspheres[J].Controlled Release,1995,35:91-93.
[5] Ren T Z,Yuan Z Y,Su B L.Surfactant-assisted preparation of hollow microspheres of mesoporous TiO2[J].Chemical Physics Letter,2003,374:170-172.
[6] Kato T,ushijima H,katsumata M.Fabrication of hollow alumina microspheres via core/shell structure of polymethyl methacrylate/alumina prepared by mechanofusion[J].Material Science,2002,37:2317-2320.
[7] Jiang Y J,Zhao J Z.Synthesis of stable hollow spheres of Si/Al composite oxide with controlled pore size in the shell wall[J].Materials Letter,2004,58:2401-2403.
[8] Zhang D B,Qi L M,Ma J N,et al.Synthesis of submicrometer-sized hollow silver spheres in mixed polymer-surfactant solutions[J].Advanced Material,2002,14(20):1499-1502.
[9] Liu S,Wei M,Rao J,et al.A controlled formation of cage-like nanoporous hollow silica microspheres[J].Materials Letters,2011,65(13):2083-2085.
[10] Chen J,Chen J,Zhang X,et al.Efficient and stable PS-SO3H/SiO2 hollow nanospheres with tunable surface properties for acid catalyzed reactions[J].Applied Catalysis A:General,2016,516:1-8.
[11] Hu H,Zhou H,Liang J,et al.Facile synthesis of amino-functionalized hollow silica microspheres and their potential application for ultrasound imaging[J].Journal of Colloid & Interface Science,2011,358(2):392-398.
[12] Shen S L,Wei W,Guo K,et al.A novel process to synthesize magnetic hollow silica microspheres[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2007,311(1-3):99-105.
[13] Wei M,Oers C,Hao X,et al.Influence of silica forming media on the synthesis of hollow silica microspheres[J].Microporous & Mesoporous Materials,2011,138(1-3):17-21.
[14] Biradar A V,Biradar A A,Asefa T.Silica-dendrimer core-shell microspheres with encapsulated ultrasmall palladium nanoparticles:efficient and easily recyclable heterogeneous nanocatalysts[J].Langmuir the ACS Journal of Surfaces & Colloids,2011,27(23):14408-14418.
[15] Guo X,Liu X,Xu B,et al.Synthesis and characterization of carbon sphere-silica core-shell structure and hollow silica spheres[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2009,345(1-3):141-146.
[16] Jiang Y,Ding X,Zhao J.A facile route to synthesis of hollow SiO2/Al2O3 spheres with uniform mesopores in the shell wall[J].Materials Letters,2005,59(23):2893-289759.
[17] Tingquanlei Y.Morphology and phase compositions of hydroxyapatite powder particles plasma-sprayed into water[J].Journal of Materials Science and Technology Shenyang,2002,18(4):381-382.
[18] Kim K D,Choi K Y,Yang J W.Formation of spherical hollow silica particles from sodium silicate solution by ultrasonic spray pyrolysis method[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2005,254(1-3):193-198.
[19] 申晓毅,翟玉春,刘岩.超声水热法制备单分散球形二氧化硅及因素分析[J].化工学报,2008,59(9):2407-2411.
[20] Caruso R A,SushaA,Caruso F.Multilayered titania,silica,andlaponite nanoparticle coatins on polystyrene colloidal templates and resulting inorganichollow spheres[J].Chemical Material,2001,13:400-409.
[21] 杨晓玲,朱以华.核-壳式聚苯乙烯/二氧化硅复合微球及空腔硅球的制备[J].无机材料学报,2003,6:1293-1296.
[22] 孙新枝,杜芳林.双金属催化剂Ni-Co/SiO2空心球的可控制备及催化性能[J].无机材料学报,2016,31(9):923-928.
[23] 马雪慧,王乐善,赵彦保.中空纳米二氧化硅微球的制备及表征[J].无机化学学报,2009,25(6):1091-1096.
[24] 谢丹丹,曲晓飞,杜芳林.形貌和尺寸可控的二氧化硅/硅酸镍锰空心微球的制备[J].材料导报,2014,28(10):86-88.
[25] 赖可欣.铈、钴掺杂的空心介孔二氧化硅球在肿瘤治疗中的应用研究[D].上海:上海师范大学,2022.
[26] 程金瑜,刘朋威,何铠君,等.纳米多孔二氧化硅微球在染料罗丹明B吸附中的应用[J].染整技术,2021,43(8):36-41.
[27] 王志琰.纳米磁性二氧化硅空心球的制备及其在载药方面的应用[D].北京:北京化工大学,2010.
[28] Sang-wook K,Minsuk K,Wha Y L,et al.Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for suzuki coupling reactions[J].Journal of the American Chemical Society,2002,124(26):7642-7643.
[29] Huang S,Yu X,Dong Y,et al.Spherical polyelectrolyte brushes:ideal templates for preparing pH-sensitive core-shell and hollow silica nanoparticles[J].Colloids & Surfaces A Physicochemical & Engineering Aspects,2012,415:22-30.
[30] 罗静,颜明飞,李振坤,等.空心介孔二氧化硅纳米粒子的制备及其作为催化剂载体在水处理中的应用[J].化工技术与开发,2018,47(6):19-21,34.
[31] 吴兴萍.中空结构MFe2O4(M=Fe、Cu)/SiO2复合材料的Fenton催化性能研究[D].扬州:扬州大学,2019.
[32] 付庆涛,何婷婷,于濂清,等.磁性核壳介孔氧化硅微球的制备与应用[J].化学进展,2010,22(6):1116-1124.
[33] Zhao W R,Gu J L,Zhang L X,etal.Fabricaiton of uniform magnetic nanocomposite spheres with a magnetic core/mesoporous Silica shell structure[J].J Am Chem Soc,2005,127(25):8916-8917.
[34] Chen Y,Chen H R,Zhang S J,et al.Multifunctional mesoporous nanoellipsoids for biological bimodal imaging and magnetically targeted delivery of anticancer drugs[J].Advanced Functional Materials,2010,21(2):270-278.
[35] Deng Y,Qi D,Deng C,et al.Superparamagnetic high-magnetization microspheres with an Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins[J].Journal of the American Chemical Society,2008,130(1):28-29.
[36] Liu Z,Li M,Yang X J,et al.The use of multifunctional magnetic mesoporous core/shell heteronanostructures in a biomolecule separation system[J].Biomaterials,2011,32(21):4683-4690.
[37] Du Y,Luna L E,Tan W S,et al.Hollow silica nanoparticles in UV-visible antireflection coatings for poly (methyl methacrylate) substrates[J].ACS Nano,2010,4(7):4308-4316.
[38] 杜涵,郑育英,窦正杰,等.广东材料发展论坛——新材料与先进制造大会论文集[C].广州:材料研究与应用编辑部,2015:133-134.
[39] 李洁,张佳,付明琴,等.介孔SiO2负载有机基二元定型复合相变储能材料的性能研究[J].材料导报,2021,35(z2):483-487.
[40] Najafi M,Yousefi Y,Rafati A A.Synthesis,characterization and adsorption studies of several heavy metal ions on amino-functionalized silica nano hollow sphere and silica gel[J].Separation & Purification Technology,2012,85(none):193-205.

基金资助

国家自然科学基金(21473126);武汉科技大学煤转化与新型碳材料湖北省重点实验室开放基金(WKDM202306)

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