Conjugated microporous polymers (CMPs) are a sub-class of amorphous porous organic polymers.The π-conjugated skeleton and permanent nanoporous structure of CMPs increase their affinity with carbon dioxide.Therefore,CMPs show a good application prospect in the adsorption of carbon dioxide.By introducing the preparation methods of CMPs and the capture methods of CO2,the development status and research progress of CMPs in the adsorption of CO2 were reviewed.Various factors affecting the adsorption effect were summarized,optimization suggestions for enhancing the adsorption effect were put forward,and the future development prospect of carbon dioxide adsorption by CMPs was also presented.
[1] Baker H S,Millar R J,Karoly D J,et al.Higher CO2 concentrations increase extreme event risk in a 1.5℃ world[J].Nature Climate Change,2018,8(7):604-608.
[2] Midgley G F,Bond W J.Future of African terrestrial biodiversity and ecosystems under anthropogenic climate change[J].Nature Climate Change,2015,5(9):823-829.
[3] 汤茂玥,李宜真.“双碳”愿景提出的时代背景与价值意义[J].佳木斯职业学院学报,2022,38(4):38-40.
[4] Paltsev S,Morris J,Kheshgi H,et al.Hard-to-abate sectors:the role of industrial carbon capture and storage (CCS) in emission mitigation[J].Applied Energy,2021,300:117322.
[5] Guo J X,Huang C.Feasible roadmap for CCS retrofit of coal-based power plants to reduce Chinese carbon emissions by 2050[J].Applied Energy,2020,259:114112.
[6] 金灿,郑璐康,陈琦,等.二氧化碳吸附材料研究新进展[J].物理化学进展,2017,6(3):121-127
[7] Serafin J,Ouzzine M,Cruz O F,et al.Conversion of fruit waste-derived biomass to highly microporous activated carbon for enhanced CO2 capture[J].Waste Management,2021,136:273-282.
[8] Ko D.Comparison of carbon molecular sieve and zeolite 5A for CO2 sequestration from CH4/CO2 mixture gas using vacuum pressure swing adsorption[J].Korean Journal of Chemical Engineering,2021,38(5):1043-1051.
[9] Zu Y,Li J,Li X,et al.Imine-linked porous aromatic frameworks based on spirobifluorene building blocks for CO2 separation[J].Microporous and Mesoporous Materials,2022,334:111779.
[10] Guo Z,Wu H,Chen Y,et al.Missing-linker defects in covalent organic framework membranes for efficient CO2 separation[J].Angewandte Chemie-International Edition,2022,61(41):e202210466.
[11] Knebel A,Caro J.Metal-organic frameworks and covalent organic frameworks as disruptive membrane materials for energy-efficient gas separation[J].Nature Nanotechnology,2022,17(9):911-923.
[12] Dai J,Xie D,Liu Y,et al.Supramolecular metal-organic framework for CO2/CH4 and CO2/N2 separation[J].Industrial & Engineering Chemistry Research,2020,59(16):7866-7874.
[13] Wang L,Zhang Y S,Jiang H R,et al.Carbonyl-incorporated aromatic hyper-cross-linked polymers with microporous structure and their functional materials for CO2 adsorption[J].Industrial & Engineering Chemistry Research,2020,59(36):15955-15966.
[14] Wang T,Yao H,Song N,et al.Microporous polymer networks constructed from cross-linkable linear polyimides for CO2 adsorption[J].Microporous and Mesoporous Materials,2021,311:110708.
[15] Weng Y,Ji W,Ye C,et al.Simultaneously enhanced CO2 permeability and CO2/N2 selectivity at sub-ambient temperature from two novel functionalized intrinsic microporous polymers[J].Journal of Membrane Science,2022,644:120086.
[16] Wang S,Liu Y,Yu Y,et al.Conjugated microporous polymers based on biphenylene for CO2 adsorption and luminescence detection of nitroaromatic compounds[J].New Journal of Chemistry,2018,42(12):9482-9487.
[17] Wang W,Zhang Y,Chen L,et al.Tricycloquinazoline-containing 3D conjugated microporous polymers and 2D covalent quinazoline networks:microstructure and conductivity[J].Polymer Chemistry,2021,12(5):650-659.
[18] Lee J M,Cooper A I.Advances in conjugated microporous polymers[J].Chemical Reviews,2020,120(4):2171-2214.
[19] Teng D G,Wei X Y,Li J H,et al.One-pot facile synthesis of multifunctional conjugated microporous polymers via Suzuki-Miyaura coupling reaction[J].ChemistrySelect,2020,5(4):1410-1415.
[20] Wang S,Meng X,Luo H,et al.Post-synthetic modification of conjugated microporous polymer with imidazolium for highly efficient anionic dyes removal from water[J].Separation and Purification Technology,2022,284:120245.
[21] Tian Z,Lei Y,Ye X,et al.Efficient capture of airborne PM by nanotubular conjugated microporous polymers based filters under harsh conditions[J].Journal of Hazardous Materials,2022,423:127047.
[22] Jiang J X,Trewin A,Adams D J,et al.Band gap engineering in fluorescent conjugated microporous polymers[J].Chemical Science,2011,2(9):1777-1781.
[23] Xu Y,Chen L,Guo Z,et al.Light-emitting conjugated polymers with microporous network architecture:interweaving scaffold promotes electronic conjugation,facilitates exciton migration,and improves luminescence[J].Journal of the American Chemical Society,2011,133(44):17622-17625.
[24] Sun L,Liang Z,Yu J,et al.Luminescent microporous organic polymers containing the 1,3,5-tri(4-ethenylphenyl)benzene unit constructed by Heck coupling reaction[J].Polymer Chemistry,2013,4(6):1932-1938.
[25] Chen Q,Liu D P,Zhu J H,et al.Mesoporous conjugated polycarbazole with high porosity via structure tuning[J].Macromolecules,2014,47(17):5926-5931.
[26] Xiang L,Zhu Y,Gu S,et al.A luminescent hypercrosslinked conjugated microporous polymer for efficient removal and detection of mercury ions[J].Macromolecular Rapid Communications,2015,36(17):1566-1571.
[27] Bhunia A,Vasylyeva V,Janiak C.From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities[J].Chemical Communications,2013,49(38):3961-3963.
[28] Ren S,Bojdys M J,Dawson R,et al.Porous,fluorescent,covalent triazine-based frameworks via room-temperature and microwave-assisted synthesis[J].Advanced Materials,2012,24(17):2357-2361.
[29] Li Y X,Zhang W,Sun Z Y,et al.Light-induced synthesis of cross-linked polymers and their application in explosive detection[J].European Polymer Journal,2015,63:149-155.
[30] Zhang H,Zhang Y,Gu C,et al.Electropolymerized conjugated microporous poly(zinc-porphyrin) films as potential electrode materials in supercapacitors[J].Advanced Energy Materials,2015,5(10):1402175.
[31] Fu L,Ren Z,Si W,et al.Research progress on CO2 capture and utilization technology[J].Journal of CO2 Utilization,2022,66:102260.
[32] 王芃,胡云峰.CO2分离方法的研究进展[J].化工科技,2019,27(2):62-65
[33] 杨支秀,鲁博,郭丁丁,等.CO2捕集及分离方法研究现状与进展[J].山东化工,2020,49(18):62-64.
[34] 杜振宇.氮掺杂碳材料的制备及其CO2吸附性能研究[D].青岛:中国石油大学(华东),2014.
[35] Warmuzinski K,Tanczyk M,Jaschik M.Experimental study on the capture of CO2 from flue gas using adsorption combined with membrane separation[J].International Journal of Greenhouse Gas Control,2015,37:182-190.
[36] Indira V,Abhitha K.A review on polymer based adsorbents for CO2 capture[J].IOP Conference Series:Materials Science and Engineering,2021,1114(1):012081.
[37] 王玉冰,陈杰,延卫,等.共轭微孔聚合物的制备与应用[J].化学进展,2021,33(5):838-854.
[38] Dai D,Yang J,Zou Y C,et al.Macrocyclic arenes-based conjugated macrocycle polymers for highly selective CO2 capture and iodine adsorption[J].Angewandte Chemie-International Edition,2021,60(16):8967-8975.
[39] Li Z,Wang W B,Xu Y S,et al.Truxene/triazatruxene-based conjugated microporous polymers with flexible@rigid mutualistic symbiosis for efficient CO2 storage[J].Journal of CO2 Utilization,2021,49:101550.
[40] Liu Y,Wang S,Meng X,et al.Increasing the surface area and CO2 uptake of conjugated microporous polymers via a post-knitting method[J].Materials Chemistry Frontiers,2021,5(14):5319-5327.
[41] Zhang C,Yang X,Zhao Y,et al.Bifunctionalized conjugated microporous polymers for carbon dioxide capture[J].Polymer,2015,61:36-41.
[42] Zhao Y,Yao K X,Teng B,et al.A perfluorinated covalent triazine-based framework for highly selective and water-tolerant CO2 capture[J].Energy & Environmental Science,2013,6(12):3684-3692.
[43] Xu Y,Cui D,Zhang S,et al.Facile synthesis of conjugated microporous polymer-based porphyrin units for adsorption of CO2 and organic vapors[J].Polymer Chemistry,2019,10(7):819-822.
[44] Xie Y,Wang T T,Liu X H,et al.Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer[J].Nature Communications,2013,4:1960.
[45] Samy M M,Sharma S U,Mohamed M G,et al.Conjugated microporous polymers containing ferrocene units for high carbon dioxide uptake and energy storage[J].Materials Chemistry and Physics,2022,287:126177.
[46] Chen Y F,Sun H X,Yang R X,et al.Synthesis of conjugated microporous polymer nanotubes with large surface areas as absorbents for iodine and CO2 uptake[J].Journal of Materials Chemistry A,2015,3(1):87-91.
基金资助
甘肃省高校青年博士支持项目(2023QB-042);兰州交通大学青年科学基金项目(2021009);兰州交通大学-天津大学联合创新基金项目(2022067)
PDF
