反硫化聚合物材料研究进展

于游, 张丁尹, 范文杰*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 58 -62.

PDF
化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 58-62. DOI: 10.19817/j.cnki.issn1006-3536.2024.07.058
综述与专论

反硫化聚合物材料研究进展

    于游, 张丁尹, 范文杰*
作者信息 +

Research progress of inverse-vulcanized polymer materials

  • Yu You, Zhang Dingyin, Fan Wenjie
Author information +
文章历史 +
PDF

摘要

反硫化是以单质硫为反应原料,以小分子不饱和烯烃为交联剂合成高含硫聚合物的一种有效方法。反硫化聚合物作为一种有机无机杂化高分子材料具有很多碳基材料没有的特性。具体介绍了反硫化聚合物的特点、实验合成和材料在锂硫电池、重金属吸附剂、光学、自我修复材料、抗菌剂、溢油吸附材料等方向的应用,并对反硫化聚合物材料的未来发展前景进行了展望。

Abstract

Inverse vulcanization is an effective method for synthesizing high-sulfur polymers using elemental sulfur as the reactant and small molecule unsaturated olefins as cross-linking agents.As a type of organic-inorganic hybrid polymer material,inverse-vulcanized polymers exhibit characteristics that are distinct from carbon-based materials.This article provided a detailed introduction to the features and experimental synthesis of inverse-vulcanized polymers,along with their applications in areas such as lithium-sulfur batteries,heavy metal adsorbents,optics,self-healing materials,antibacterial agents,and oil spill adsorbents.The study also offered a prospective outlook on the future development of inverse-vulcanized polymer materials.

关键词

反硫化 / 聚合物 / 电极材料 / 吸附剂 / 抑菌 / 光学

Key words

inverse vulcanization / polymer / electrode materials / adsorbents / antibacterial / optics

引用本文

引用格式 ▾
反硫化聚合物材料研究进展[J]. 化工新型材料, 2024, 52(7): 58-62 DOI:10.19817/j.cnki.issn1006-3536.2024.07.058

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Griebel J J,Glass R S,Char K,et al.Polymerizations with elemental sulfur:a novel route to high sulfur content polymers for sustainability,energy and defense[J].Progress in Polymer Science,2016,58:90-125.
[2] Lee T,Dirlam P T,Njardarson J T,et al.Polymerizations with elemental sulfur:from petroleum refining to polymeric materials[J].Journal of the American Chemical Society,2022,144(1):5-22.
[3] Zhang Y,Glass R S,Char K,et al.Recent advances in the polymerization of elemental sulphur,inverse vulcanization and methods to obtain functional chalcogenide hybrid inorganic/organic polymers (CHIPs)[J].Polymer Chemistry,2019,10(30):4078-4105.
[4] Chalker J M,Worthington M J H,Lundquist N A,et al.Synthesis and applications of polymers made by inverse vulcanization[J].Topics in Current Chemistry,2019,377(3):16.
[5] Arslan M,Kiskan B,Cengiz E C,et al.One step-inverse vulcanization of bismaleimide and divinylbenzene by elemental sulfur for lithium sulfur batteries[J].European Polymer Journal,2016,80(5):70-77.
[6] Gomez I,Mecerreyes D,Blazquez J A,et al.Inverse vulcanization of sulfur with divinylbenzene:stable and easy processable cathode material for lithium-sulfur batteries[J].Journal of Power Sources 2016,329:72-78.
[7] Orme K,Fistrovich A H,Jenkins C L.Tailoring polysulfide properties through variations of inverse vulcanization[J].Macromolecules,2020,53(21):9353-9361.
[8] Wu X,Smith J A,Petcher S,et al.Catalytic inverse vulcanization[J].Nature Communications,2019,10(1):647.
[9] Zhang Y,Pavlopoulos N G,Kleine T S,et al.Nucleophilic activation of elemental sulfur for inverse vulcanization and dynamic covalent polymerizations[J].Journal of Polymer Science Part A:Polymer Chemistry,2019,57(1):7-12.
[10] Yan P,Zhao W,McBride F,Cai D,et al.Mechanochemical synthesis of inverse vulcanized polymers[J].Nature Communications,2022,13(1):4824.
[11] Jia J,Liu J,Wang Z Q,et al.Photoinduced inverse vulcanization[J].Nature Chemistry,2022,14(11):1249-1257.
[12] Cherumukkil S,Agrawal S,Jasra R V.Sulfur polymer as emerging advanced materials:synthesis and applications[J].Chemistry Select,2023,8(10):e202204428.
[13] Alex A,Singha N K,Choudhury S,et al.Exploring inverse vulcanization in lithium-sulfur batteries[J].Current Opinion in Electrochemistry,2023,39:101271.
[14] Chung W J,Griebel J J,Kim E T,et al.The use of elemental sulfur as an alternative feedstock for polymeric materials[J].Nature Chemistry,2013,5(6):518-524.
[15] Fu C,Li G,Zhang J,et al.Electrochemical lithiation of covalently bonded sulfur in vulcanized polyisoprene[J].ACS Energy Letters,2016,1(1):115-120.
[16] Zeng S,Li L,Zhao D,et al.Polymer-capped sulfur copolymers as lithium-sulfur battery cathode:enhanced performance by combined contributions of physical and chemical confinements[J].Journal of Physical Chemistry C,2017,121(5):2495-2503.
[17] Müller F G,Lisboa L S,J.Chalker J M.Inverse vulcanized polymers for sustainable metal remediation[J].Advanced Sustainable Systems,2023,7(5):2300010.
[18] Crockett M P,Evans A M,Worthington M J H,et al.Sulfur-limonene polysulfide:a material synthesized entirely from industrial by-products and its use in removing toxic metals from water and soil[J].Angewandte Chemie International Edition,2016,55(5):1714-1718.
[19] Parker D J,Jones H A,Petcher S,et al.Low cost and renewable sulfur-polymers by inverse vulcanisation,and their potential for mercury capture[J].Journal of Materials Chemistry A,2017,5(23):11682-11692.
[20] Sahadevan S A,Xiao X,Ma Y,et al.Sulfur-oleylamine copolymer synthesized via inverse vulcanization for the selective recovery of copper from lithium-ion battery E-waste[J].Materials Chemistry Frontiers,2023,7(7):1374-1384.
[21] Griebel J J,Namnabat S,Kim E T,et al.New infrared transmitting material via inverse vulcanization of elemental sulfur to prepare high refractive index polymers[J].Advanced Materials,2014,26(9):3014-3018.
[22] Kim D H,Jang W,Choi K,et al.One-step vapor-phase synthesis of transparent high refractive index sulfur-containing polymers[J].Science Advances,2020,6(28):eabb5320.
[23] Klene T S,Lee T,Carothers K J,et al.Infrared fingerprint engineering:a molecular-design approach to long-wave infrared transparency with polymeric materials[J].Angewandte Chemie International Edition,2019,58(49):17656-17660.
[24] Boyd D A,Nguyen V Q,McClain C C,et al.Optical properties of a sulfur-rich organically modified chalcogenide polymer synthesized via inverse vulcanization and containing an organometallic comonomer[J].ACS Macro Letters,2019,8(2):113-116.
[25] Qureshi M H,Bao J,Kleine T S,et al.Synthesis of deuterated and sulfurated polymers by inverse vulcanization:engineering infrared transparency via deuteration[J].Journal of the American Chemical Society,2023,145(50):27821-27829.
[26] Deng Z,Hoefling A,Théato P,et al.Surface properties and antimicrobial activity of poly(sulfur-co-1,3-diisopropenylbenzene) copolymers[J].Macromolecular Chemistry and Physics,2018,219(5):1700497.
[27] Smith J A,Mulhall R,Goodman S,et al.Investigating the antibacterial properties of inverse vulcanized sulfur polymers[J].ACS Omega,2020,5(10):5229-5234.
[28] Dop R A,Neill D R,Hasell T.Antibacterial activity of inverse vulcanized polymers[J].Biomacromolecules,2021,22(12):5223-5233.
[29] Griebel J J,Nguyen N A,Namnabat S,et al.Dynamic covalent polymers via inverse vulcanization of elemental sulfur for healable infrared optical materials[J].ACS Macro Letters,2015,4(9):862-866.
[30] Tonkin S J,Gibson C T,Campbell J A,et al.Chemically induced repair,adhesion,and recycling of polymers made by inverse vulcanization[J].Chemical Science,2020,11(20):5537-5546.
[31] Xin Y,Peng H,Xu J,et al.Ultrauniform embedded liquid metal in sulfur polymers for recyclable,conductive,and self-healable materials[J].Advanced Functional Materials,2019,29(17):1808989.
[32] Worthington M J H,Shearer C J,Esdaile L J,et al.Sustainable polymers:sustainable polysulfides for oil spill remediation:repurposing industrial waste for environmental benefit[J].Advanced Sustainable Systems,2018,2(6):1870034.
[33] Farioli A S,Martinez M V,Barbero C,et al.The effect of oil raw material composition in the synthesis of bio-sorbents based on inverse vulcanization on the ability to remediate hydrocarbon-contaminated water.a novel method for decontaminating water/fuel emulsions[J].Journal of Applied Polymer Science,2023,141(6):e54914.
[34] Hou K X,Zhao P C,Duan L,et al.Bitumen-like polymers prepared via inverse vulcanization with shear stiffening and self-healing abilities for multifunctional applications[J].Advanced Functional Materials,2023,33(51):2306886.
[35] Mann M,Kruger J E,Andari F,et al.Sulfur polymer composites as controlled-release fertilisers[J].Organic & Biomolecular Chemistry,2019,17(7):1929-1936.
[36] Lee J H,Kim K,Choi M,et al.Rational molecular design of polymeric materials toward efficient triboelectric energy harvesting[J].Nano Energy,2019,66:104158.
[37] Herrera C,Ysinga K J,Jenkins C L.Polysulfides synthesized from renewable garlic components and repurposed sulfur form environmentally friendly adhesives[J].ACS Applied Materials & Interfaces,2019,11(38):35312-35318.

基金资助

辽宁省教育厅基本科研项目(LJKZ0708)

AI Summary AI Mindmap
PDF

690

访问

0

被引

导航
相关文章

AI思维导图

/