碳包覆二氧化硅纳米线负极材料的制备及其储锂性能研究

兰晓艳, 周兴兰, 焦子攀, 张鹏*

化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 115 -119.

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化工新型材料 ›› 2024, Vol. 52 ›› Issue (7) : 115-119. DOI: 10.19817/j.cnki.issn1006-3536.2024.07.048
新材料与新技术

碳包覆二氧化硅纳米线负极材料的制备及其储锂性能研究

    兰晓艳, 周兴兰, 焦子攀, 张鹏*
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Preparation of carbon-coated silica nanowire anode materials and their lithium storage properties

  • Lan Xiaoyan, Zhou Xinglan, Jiao Zipan, Zhang Peng
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摘要

二氧化硅(SiO2)纳米线负极具有非常良好的电化学性能,但其商业化应用受制于其复杂且成本较高的制备工艺。纤蛇纹石棉含有天然的纳米线结构,经过简单的预处理后即可制备成二氧化硅纳米线。将纤蛇纹石棉经破壁机破碎后,预处理得到二氧化硅纳米线,再将其与多巴胺包覆,形成碳包覆的二氧化硅纳米线结构。这种结构具有非常良好的电化学性能,初始放电容量达到1186mAh/g,在1A/g的电流密度下循环100圈后仍具有600mAh/g的可逆容量。

Abstract

Silica nanowire anodes exhibit commendable electrochemical properties,but their commercial applications are limited by their complex and costly preparation processes.Conversely,serpentine asbestos harbors a natural nanowire structure,which is amenable to facile conversion into silica nanowires following uncomplicated pretreatment procedures.In this paper,serpentine asbestos was crushed by a wall breaker and pretreated to obtain silica nanowires.These nanowires were then coated with dopamine to form a carbon-coated silica nanowire structure.This structure had very good electrochemical properties,with an initial discharge capacity of 1186mAh/g and a reversible capacity of 600mAh/g even after 100 cycles at a current density of 1A/g.

关键词

二氧化硅纳米线 / 纤蛇纹石棉 / 锂离子电池

Key words

silica nanowires / serpentine asbestos / lithium-ion batteries

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碳包覆二氧化硅纳米线负极材料的制备及其储锂性能研究[J]. 化工新型材料, 2024, 52(7): 115-119 DOI:10.19817/j.cnki.issn1006-3536.2024.07.048

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基金资助

青海省自然科学基金应用基础研究项目(2023-ZJ-741)

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